Shitao Wang named Associate Professor at Beijing University of Chemical Technology

Congratulations to Shitao Wang for being named an Associate Professor at the Beijing University of Chemical Technology! Below is a Q&A with Associate Professor Wang.

What is your new title and when will you start your professorship?
My new position is the Associate Professor in the Beijing University of Chemical Technology, China. And I would like to start my professorship in October.
-Tell me more about your background and where you received previous education.
I obtained my bachelor’s degree at Zhengzhou University (2010) in polymer science and engineering, and master’s degree in 2013 in organic chemistry (research filed: organic optoelectronic material science) at Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences. After that, I joined professor Makoto Fujita’s lab at the University of Tokyo, Japan and obtained my Ph.D. degree in applied chemistry in 2016. During my Ph.D. study, most of my work was about the metal-organic ligand coordinated self-assembly in supramolecular chemistry and the host-guest chemistry.
-Why did you decide to do research in the Percec Group?
I decided to do research in the Percec group to broaden my research experience and to learn something different from my previous work. And also professor Percec is very famous for the self-assembly in the bulk state. His group developed the unique methodology to analyze the self-assembled structure in solid states, which is totally different from my Ph.D. study where most self-assembly was conducted in the solution state.
-What have you learned during your time in the Percec Group?
I have learned a lot after one year of study in Percec’s group such as how to synthesize Percec’s type dendrimers, how to analyze the self-assembled structures in the solid state, and much about xrd analysis.
-What are your research goals after leaving the Percec group? How has your time in the Percec group molded your future aspirations? 
After leaving this group, I would like to put my research interest in material science. Hopefully, I can combine the chemistry and material science in my research and focus on their application. My unforgettable experience in this group inspired me that we should do our own unique research and should not always follow others’.
-Do you have any advice for aspiring professors or researchers?
To do scientific research, we should work hard, think hard, and be patient and strict with our experiments. To be the group leader, we should know how to make everyone involved in the project to be more efficient and make the project progress well. Finally, cooperation in scientific research is also very important.
-William Hasley

Welcome our new group members!

We are recently hosting lots of visiting scholars and students this summer. They are:

Mr. Bilal Javed (Pakistan), Ms. Saliha Nazir (Pakistan), Ms. Hina Daud (Pakistan)

Mr. Yuqing (Robert) Luo (China), Mr. Shangda (Brooks) Li (China)

Mr. Takahiro Oh (Japan), Mr. Adriel Melendez (Puerto Rico)

Mr. William (Billy) Hasley (Penn), Mr. Alexander Zhu (Penn)

And high school students:

Matthew Liu, Shriya Agarwal, Adarsh Rao

Welcome to Percec Group!

Athina Anastasaki appointed as Tenure Track Assistant Professor at ETH Zürich!

Former group member Dr. Athina Anastasaki has been appointed as a Tenure Track Assistant Professor of Polymeric Materials at ETH Zürich. Athina visited the Percec group as a researcher on multiple occasions, during her PhD studies under Professor David Haddleton at University of Warwick, UK. She subsequently moved to the University of California Santa Barbara as a Elings Fellow with Professor Craig J. Hawker. Athina’s research focuses on polymer nanoparticles, and will be a key addition to strengthen ETH Zürich’s polymer chemistry expertise.

Many congratulations, Athina!

Three-step one-pot methodology for functionalization of sterically hindered polyacrylates

A new publication from the group in Polymer Chemistry addresses the functionalization of sterically hindered polyacrylates. Unlike poly(methyl acrylate) (PMA), the chain ends of which can be reacted quantitatively after polymerization, the chain ends of poly(butyl acrylate) (PBA) show lower reactivity due to steric encumbrance. In this work, a three step methodology involving biphasic SET-LRP, chain extension with methyl acrylate and heterogeneous esterification provides a route to acrylate-functionalized PBA. This approach, which can be simplified by applying two or even all three steps in a single pot, may provide a more general route to the funcationalization of sterically hindered polyacrylates.

This work was led in the group by Adrian Moreno with contributions from Tong Liu, as part of a collaboration with the group of Gerard Lligadas at University Rovira i Virgili, Tarragona, Spain.

Welcome to our newest group member, Xiaojing!

The group is pleased to welcome Xiaojing Feng to the group. Xiaojing is currently a PhD student at the University of Science and Technology in Beijing, China, and will be spending two years in our group as part of her doctoral studies. Her research interests include the chiral self-assembly of gold nanorods and gold nanoparticles, and functional wearable devices based on graphene-based soft electrodes.

Welcome to the group, Xiaojing!

SET-LRP Applied to Hydrophobic Biobased Menthyl Acrylate

Recent collaborative work from the group broadening the scope of SET-LRP has been published in Biomacromolecules. The new paper details the polymerization of menthyl acrylate, a monomer derived from biobased and renewable menthol. This monomer’s hydrophobicity, which might be expected to be problematic for SET-LRP, instead causes the reaction to self-generate a biphasic system, in which SET-LRP proceeds cleanly.

This work was led by the group of Gerard Lligadas at University Rovira i Virgili, Tarragona, Spain.

Recent Glycodendrimersomes Work Highlighted in PNAS Commentary

A recent paper from the group on the functional pairing between glycoconjugates and galectins has been highlighted in a Commentary in the Proceedings of the National Academy of Sciences (PNAS), written by Kamil Godula of UC San Diego. The original paper, also published in PNAS and led by Qi Xiao, unravels intricate aspects of the mechanism underlying the interactions between the cell glycan and proteins in its environment.

Feature image adapted from Kamil Godula’s Commentary.

SET-LRP’s High Chain End Functionality Exploited to Create Complex Architecture

Recent work published by the group in Polymer Chemistry utilizes one of the key features of single-electron transfer-living radical polymerization (SET-LRP): the high chain end functionality of the resulting polymers. In this work, led in our group by Adrian Moreno with contributions from Ryan L. Jezorek and Tong Liu, functional end groups of poly(methyl acrylate) (PMA) are exploited for esterification to generate PMA macromonomers and telechelics.

This work was conducted as part of a collaboration with the group of Gerard Lligadas at University Rovira i Virgili, Tarragona, Spain.

Latest Paper in PNAS Unravels the Complexity of Lectin-Carbohydrate Interactions

The group has published a new paper in Proceedings of the National Academy of Sciences. The work presents a platform for interrogating the binding interactions between lectins and carbohydrates via agglutination assays. This approach is applied to understand the complex interplay between lectin structure, glycodendrimersome surface charge, glycan density, and cross-linking.

The work was led in our group by Qi Xiao with contributions from Irene Buzzacchera and Samuel E. Sherman, as part of a multidisciplinary collaborative effort with the groups of Hans-Joachim Gabius (Ludwig-Maximilians-University, Munich, Germany), Daniel A. Hammer (Penn), Michael L. Klein (Temple University, Philadelphia) and Martin Möller (RWTH Aachen University, Aachen, Germany).

New Work Uses Cheaper TREN as Ligand for SET-LRP

The group has published a new paper in Polymer Chemistry. The work examines the replacement of Me6-TREN, a common ligand for SET-LRP, by TREN, which is 80 times cheaper. It is shown that high chain end functionality and controlled polymer growth can be achieved in a diverse range of water-organic solvent mixtures, further reducing the cost of SET-LRP for large-scale application.

The work was led in our group by Adrian Moreno and Silvia Grama, as part of a collaboration with the group of Gerard Lligadas at University Rovira i Virgili, Tarragona, Spain.