Publication

2019

232. Wu, C.; Berritt, S.; Liang, X.; Walsh, P. J. Palladium-Catalyzed Enantioselective Alkenylation of Sulfenate Anions. Org. Lett. 2019,21, 960-964231.Deng, G.; Li, M.; Yu, K.; Liu, C.; Liu, Z.; Duan, S.; Chen, W.; Yang, X.; Zhang, H.; Walsh, P. J. Synthesis of Benzofuran Derivatives through Cascade Radical Cyclization/Intermolecular Coupling of 2-Azaallyls. Angew. Chem., Int. Ed.2019, 58, 2826-2830

230. Trongsiriwat, N.; Li, M.; Pascual-Escudero, A.; Yucel, B.; Walsh, P. J. Palladium-Catalyzed Allylic Alkylation of 2-Aryl-1,3-Dithianes, an Umpolung Synthesis of β,γ-Unsaturated Ketones. Adv. Syn. & Catal.2019, 361, 502-509

229.Wang, R.; Ma, M.; Gong, X.; Fan, X.; Walsh, P. J. Reductive Cross-Coupling of Aldehydes and Imines Mediated by Visible Light Photoredox Catalysis. Org. Lett.2019, 21, 27–31 (10.1021/acs.orglett.1028b03394).
•Top 10 downloaded papers in December, 2018

2018

228.Duan, S.; Li, M.; Ma, X.; Chen, W.; Li, L.; Zhang, H.; Yang, X.; Walsh, P. J. Palladium-Catalyzed Alkenylation of Azaarylmethylamines with Vinyl Halides. Adv. Syn. & Catal.2018,360, 4837-4842

227. Wang, H.; Chen, S.; Liu, G.; Guan, H.; Zhong, D.; Cai, J.; Zheng, Z.; Mao, J.; Walsh, P. J. Synthesis of Diaryl Selenides via Palladium-Catalyzed Debenzylative Cross-Coupling of Aryl Benzyl Selenides with Aryl Bromides. Organometallics2018, 37, 4086-4091226.Fan,X.; Gong,X. Ma, M.; Wang,R. Walsh, P. J. Visible Light-Promoted CO2Fixation with Imines: Synthesis of Diaryl α-Amino Acids. Nat. Commun.2018, 9, 4936

225.Shelp, R. A.; Walsh, P. J. Synthesis of BCP Benzylamines From 2-Azaallyl Anions and [1.1.1]Propellane. Angew. Chem., Int. Ed.2018, 57, 15857-15861224. Liang, X.; Wu, C.; Zheng, Z.; Walsh, P. J. Nickel-Catalyzed Oxidative Coupling Reaction of Phenyl Benzyl Sulfoxides. Organometallics2018, 37, 3132–3141223.Sha, S.-C.; Tcyrulnikov, S.; Li, M.; Hu, B.; Fu, Y.; Kozlowski, M. C.; Walsh, P. J. Cation-pInteractions in the Benzylic Arylation of Toluenes with Bimetallic Catalysts. J. Am. Chem. Soc2018,40, 12415-12423 (10.1021/jacs.8b05143).
Highlighted in JACS Spotlight (https://pubs.acs.org/doi/10.1021/jacs.8b10444).
Highlighted in Synfacts2018, 14, 1286222. Panetti, G. B.; Robinson, J. R.; Carroll, P. J.; Gau, M. R.; Manor, B. C.; Walsh, P. J.; Schelter, E. J. Synthesis of novel copper-rare earth BINOLate frameworks from a hydrogen bonding DBU-H rare earth BINOLate complex. Dalton Trans.2018, 47, 14408-14410221.Barber, V. P.; Pandit, S.; Green, A. M.; Trongsiriwat, N.; Walsh, P. J.; Klippenstein, S. J.; Lester, M. I. Four-Carbon Criegee Intermediate from Isoprene Ozonolysis: Methyl Vinyl Ketone Oxide Synthesis, Infrared Spectrum, and OH Production. J. Am. Chem. Soc.2018,140, 10866-10880

220.Wang, Q.; Poznik, M.; Li, M.; Walsh, P. J.; Chruma, J. J. 2-Azaallyl anions as light-tunable super-electron-donors: transition-metal-free coupling with aryl halides. Adv. Syn. & Catal.2018, 360, 2854-2868219. Jiang, H.; Bellomo, A.; Zhang, M.; Carroll, P. J.; Manor, B. C.; Jia, T.; Walsh, P. J. Palladium-Catalyzed Direct C–H Arylation of 3-(Methylsulfinyl)thiophenes. Org. Lett.2018, 20, 2522-2525218.Wang, R.; Ma, M.; Gong, X.; Panetti, G. B.; Fan, X.; Walsh, P. J. Visible-Light-Mediated Umpolung Reactivity of Imines: Ketimine Reductions with Cy2NMe and Water. Org. Lett.2018, 20, 2433–2436217. Liu, Z.-F.; Li, M.; Wang, B.; Deng, G.; Chen, W.; Kim, B.-S.; Zhang, H.; Yang, X.-D.; Walsh, P. Chemoselective synthesis of aryl(pyridinyl)methanol derivatives through Ni-NIXANTPHOS catalyzed a-arylation and tandem arylation/rearrangement of pyridylmethyl ethers. Org. Chem. Front.2018, 5, 1870-1876216. Zhang, S.; Hu, B.; Zheng, Z.; Walsh, P. J. Palladium-Catalyzed Triarylation of sp3C−H Bonds in Heteroarylmethanes: Synthesis of Triaryl(heteroaryl)methanes. Adv. Syn. & Catal.2018,360,1493– 1498

215.Kim, B.-S.; Gutierrez, O.; Kozlowski, M. C.; Walsh, P. J. A Simple Procedure for the Synthesis of β-Hydroxyallenamides via Homoallenylation of Aldehydes. Adv. Synth. Catal.2018, 360(7), 1426–1432.
214. Mao, J.; Zhang, J.; Zhang, S.; Walsh, P. J. NIXANTPHOS: A Highly Active Ligand for Palladium-Catalyzed Buchwald–Hartwig Amination of Unactivated Aryl Chlorides. Dalt. Trans.2018, 47(26), 8690–8696.213 Li, M.; Berritt, S.; Wang, C.; Yang, X.; Liu, Y.; Sha, S.-C.; Wang, B.; Wang, R.; Gao, X.; Li, Z.; et al. Sulfenate Anions as Organocatalysts for Benzylic Chloromethyl Coupling Polymerization via C=C Bond Formation. Nat. Commun.2018, 9(1), 1754.212.  Li, J.; Wu, C.; Zhou, B.; Walsh, P. J. Nickel-Catalyzed C(Sp3)–H Arylation of Diarylmethane Derivatives with Aryl Fluorides. J. Org. Chem.2018, 83(5), 2993–2999

 

211.  Wang, Z.; Zheng, Z.; Xu, X.; Mao, J.; Walsh, P. J. One-Pot Aminobenzylation of Aldehydes with Toluenes. Nat. Commun.2018, 9(1), 3365.

210. Lin, T.; Mi, J.; Song, L.; Gan, J.; Luo, P.; Mao, J.; Walsh, P. J. Nickel-Catalyzed Desymmetrizing Cross-Electrophile Coupling of Cyclic Meso-Anhydrides. Org. Lett.2018, 20(4), 1191–1194.

209.Liu, F.; Zhong, J.; Zhou, Y.; Gao, Z.; Walsh, P. J.; Wang, X.; Ma, S.; Hou, S.; Liu, S.; Wang, M.; et al. Cobalt-Catalyzed Enantioselective Negishi Cross-Coupling of Racemic α-Bromo Esters with Arylzincs. Chem. – A Eur. J. 2018, 24(9), 2059–2064.

2017

208.  Li, M.; Berritt, S.; Matuszewski, L.; Deng, G.; Pascual-Escudero, A.; Panetti, G. B.; Poznik, M.; Yang, X.; Chruma, J. J.; Walsh, P. J. Transition-Metal-Free Radical C (sp3)–C (sp2) and C (sp3)–C (sp3) Coupling Enabled by 2-Azaallyls as Super-Electron-Donors and Coupling-Partners. J. Am. Chem. Soc. 2017, 139 (45), 16327–16333.
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207. Li, M.; Gutierrez, O.; Berritt, S.; Pascual-Escudero, A.; Yeşilçimen, A.; Yang, X.; Adrio, J.; Huang, G.; Nakamaru-Ogiso, E.; Kozlowski, M. C. Transition-Metal-Free Chemo-and Regioselective Vinylation of Azaallyls. Nat. Chem. 2017, 9 (10), 997–1004.

 

206.Fan, X.; Walsh, P. J. Chelation-Controlled Additions to Chiral α- and β-Silyloxy, α-Halo, and β-Vinyl Carbonyl Compounds. Acc. Chem. Res. 2017, 50 (9), 2389–2400.

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205. Liu, T.; Exarhos, A. L.; Alguire, E. C.; Gao, F.; Salami-Ranjbaran, E.; Cheng, K.; Jia, T.; Subotnik, J. E.; Walsh, P. J.; Kikkawa, J. M. Birefringent Stable Glass with Predominantly Isotropic Molecular Orientation. Phys. Rev. Lett. 2017, 119 (9), 95502. 204. Gao, G.; Fu, Y.; Li, M.; Wang, B.; Zheng, B.; Hou, S.; Walsh, P. J. Arylation of Azaarylmethylamines with Aryl Chlorides and a NiBr2/NIXANTPHOS-Based Catalyst.

 

204. Gao, G.; Fu, Y.; Li, M.; Wang, B.; Zheng, B.; Hou, S.; Walsh, P. J. Arylation of Azaarylmethylamines with Aryl Chlorides and a NiBr2/NIXANTPHOS-Based Catalyst. Adv. Synth. Catal. 2017, 359 (16), 2890–2894.original image203. Jia, T.; Zhang, M.; McCollom, S. P.; Bellomo, A.; Montel, S.; Mao, J.; Dreher, S. D.; Welch, C. J.; Regalado, E. L.; Williamson, R. T.; et al. Palladium-Catalyzed Enantioselective Arylation of Aryl Sulfenate Anions: A Combined Experimental and Computational Study. J. Am. Chem. Soc. 2017, 139 (24), 8337–8345.Abstract Image202. Ablajan, K.; B Panetti, G.; Yang, X.; Kim, B.-S.; Walsh, P. J. Synthesis of Diarylated 4‐Pyridylmethyl Ethers via Palladium‐Catalyzed Cross‐Coupling Reactions. Adv. Synth. Catal. 2017.original image

201. Gao, G.; Zheng, B.; Fu, Y.; Li, M.; Wang, B.; Chen, X.-Z.; Zhang, Y.-Y.; Liu, J.-J.; Hou, S.-C.; Walsh, P. J. Palladium-Catalyzed Chemoselective α-Arylation of Methyl Sulfones with Aryl Chlorides. Asian J. Org. Chem. 2017, 6 (6), 654–657. 200. Zhang, S.; Kim, B.-S.; Wu, C.; Mao, J.; Walsh, P. J. Palladium-Catalysed Synthesis of Triaryl (Heteroaryl) Methanes. Nat. Commun. 2017, 8, 14641.199. Jiménez, J.; Kim, B.-S.; Walsh, P. J. Tandem C(sp3)−H Arylation/Oxidation and Arylation/Allylic Substitution of Isoindolinones. Adv. Synth. Catal. 2016, 358 (17), 2829–2837

.                                                                                            original image

198. Zheng, B.; Li, M.; Gao, G.; He, Y.; Walsh, P. J. Palladium-Catalyzed α-Arylation of Methyl Sulfonamides with Aryl Chlorides. Adv. Synth. Catal. 2016, 358 (13), 2156–2162.original image

 

Publications

2016

197. Li, M., Yucel, B., Jiménez, J., Rotella, M., Fu, Y., Walsh, P. J. Umpolung Synthesis of Diarylmethylamines via Palladium‐Catalyzed Arylation of N‐Benzyl Aldimines. Advanced Synthesis & Catalysis. 2016, 356 (12), pp 1910-1915.