2023

Photoinduced Diastereoselective Aminoalkylation of Cubanes 

Levitre, G.; Keess, S.; and Molander, G. A. Org. Lett 2023, doi.org/10.1021/acs.orglett.3c01223

A General and Practical Route to Functionalized BCP-Heteroaryls Enabled by Photocatalytic Multicomponent Heteroarylation of [1.1.1]Propellane

 Huang, W.; Keess, S.; and Molander, G. A. Angew. Chem. Int. Ed. 2023, https://doi.org/10.1002/anie.202302223

Alkyl (Het)Arylsulfones from SuFEx Reagents via Photochemical S-F Bond Activation

Shreiber, S. T. and Molander, G. A. Org. Lett. 2023, doi.org/10.1021/acs.orglett.3c00447

A General and Modular Approach to BCP Alkylamines via Multicomponent Difunctionalization of [1.1.1]Propellane

Huang, W.; Zheng, Y.; Keess, S.; and Molander, G. A. J Am. Chem. Soc. 2023, doi.org/10.1021/jacs.2c13298

Dearomative Intermolecular [2+2] Photocycloaddition for Construction of C(sp3)-rich Heterospirocycles On-DNA

Li, L., Matsuo, B., Levitre, G., McLain, E. J., Voight, E., Crane, E. A., and Molander, G. A. Chem. Sci. 2023, doi.org/10.1039/D3SC00144J

Transition metal-free photochemical C-F activation for the preparation of difluorinated-oxindole derivatives

Matsuo, B., Majhi, J., Granados, A., Sharique, M., Martin, R. T., Gutierrez, O., and Molander, G. A. Chem. Sci.. 2023, doi.org/10.1039/D2SC06179A

Photoinduced Vicinal 1,2-Difunctionalization of Olefins for the Synthesis of Alkyl Sulfonamides

Sookezian, A. and Molander, G. A. Org. Lett. 2023, doi.org/10.1021/acs.orglett.3c00182

Photochemical Methods Applied to DNA Encoded Library (DEL) Synthesis

Matsuo, B., Granados, A., Levitre, G., and Molander, G. A. Acc. Chem. Res. 2023,doi.org/10.1021/acs.accounts.2c00778

Sustainable photo induced decarboxylative chlorination mediated by halogen atom transfer

Levitre, G., Granados, A., and Molander, G. A. Green Chem. 2023, doi.org/10.1039/D2GC04578H

Practical, scalable, and transition metal-free visible light-induced heteroarylation route to substituted oxindoles

Majhi, J., Granados, A., Matsuo, B., Ciccone, V., Dhungana, R. K., Sharique, M., and Molander, G. A. Chem. Sci. 2023, doi.org/10.1039/D2SC05918E

2022

Photochemical Intermolecular [3σ + 2σ]-Cycloaddition for the Construction of Aminobicyclo[3.1.1]heptanes

Zheng, Y., Huang, W., Dhungana, R.K., Granados, A., Keess, S., Makvandi, M.,  Molander, G.M. J. Am. Chem. Soc. 2022, doi.org/10.1021/jacs.2c11501

Trifunctionalization of Cinnamyl Alcohols Provides Access to Brominated a,a-Difluoro-y-lactones via a Photoinduced Radical-Polar-Radical Mechanism

Dhungana, R.K., Granados, A., Ciccone, V., Martin, R.T., Majhi, J., Sharique, M., Gutierrez, O., Molander, G.M. ACS Catal. 2022, doi.org/10.1021/acscatal.2c05514

Visible-Light Induced C-F Bond Activation for the Difluoroalkylation of Indoles

Shreiber, S. T., Granados, A., Matsuo, B., Majhi, J., Campbell, M. W., Pate, S., and Molander, G. A. Org. Lett. 2022, doi.org/10.1021/acs.orglett.2c03549

One Step Synthesis of Unsymmetrical 1,3-Disubstituted BCP Ketones via Nickel/Photoredox-Catalyzed [1.1.1]Propellane Multicomponent Dicarbofunctionalization

Huang, W., Keess, S., and Molander, G. A. Chem. Sci., 2022, doi: 10.1039/D2SC05100A.

Metal-Free Photochemical Imino-Alkylation of Alkenes with Bifunctional Oxime Esters

Majhi, J., Dhungana, R. K., Rentería-Gomez, A., Sharique, M., Li, L., Dong, W., Gutierrez, O., and Molander, G. A. J. Am. Chem. Soc., 2022, doi:10.1021/jacs.2c07170.

1,2-Radical Shifts in Photoinduced Synthetic Organic Transformations: A Guide to the Reactivity of Useful Radical Synthons

Matsuo, B., Granados, A., Majhi, J., Sharique, M., Levitre, G., and Molander, G. A. ACS Org. Inorg. Au , 2022, doi:10.1021/acsorginorgau.2c00032.

A Three-Component Difunctionalization of N-Alkenyl Amides via Organophotoredox Radical-Polar Crossover

Dhungana, R. K., Granados, A., Sharique, M., Majhi, J. and Molander, G. A. Chem. Comm. , 2022, doi:10.1039/D2CC04101D.

Exploiting the sp² character of bicyclo[1.1.1]pentyl radicals in the transition-metal-free multi-component difunctionalization of [1.1.1]propellane

Dong, W., Yen-Pon, E., Li, L., Bhattacharjee, A., Jolit, A. and Molander, G. A. Nature Chemistry , 2022, doi:10.1038/s41557-022-00979-0.

Solid-Phase Photochemical Peptide Homologation Cyclization

Elbaum, M. B., Elkhalifa, M. A., Molander, G. A., and Chenoweth, D. M. Org. Lett. , 2022, doi:10.1021/acs.orglett.2c02012.

Dicarbofunctionalization of [1.1.1]Propellane Enabled by Nickel/Photoredox Dual Catalysis: One-Step Multicomponent Strategy for the Synthesis of BCP-Aryl Derivatives

Huang, W., Keess, S., and Molander, G. A. J. Am. Chem. Soc. , 2022, doi:10.1021/jacs.2c05304.

From Styrenes to Fluorinated Benzyl Bromides: A Photoinduced Difunctionalization via Atom Transfer Radical Addition

Granados, A., Dhungana, R., Sharique, M., Majhi, J., and Molander, G. A. Org. Lett. , 2022, doi:10.1021/acs.orglett.2c01699.

On-DNA Hydroalkylation to Introduce Diverse Bicyclo[1.1.1]pentanes and Abundant Alkyls via Halogen Atom Transfer

Yen-Pon, E., Li, L., Levitre, G., Majhi, J., McClain, E. J., Voight, E. A., Crane, E. A., and Molander, G. A. J. Am. Chem. Soc. , 2022, doi:10.1021/jacs.2c03025 .

A practical and sustainable two-component Minisci alkylation via photo-induced EDA-complex activation

Sharique, M., Majhi, J., Dhungana, R. K., Kammer, L. M., Krumb, M., Lipp, A., Romero, E., and Molander, G. A. Chem. Sci., 2022, doi:10.1039/d2sc01363k .

Synthesis of α-Fluorinated Areneacetates through Photoredox/Copper Dual Catalysis

Levitre, G., Granados, A., Cabrera-Afonso, M.J., and Molander, G. A. Org. Lett., 2022, doi:10.1021/acs.orglett.2c00969.

Thianthrenium-enabled sulfonylation via electron donor-acceptor complex photoactivation

Granados, A., Cabrera-Afonso, M. J., Escolano, M., Badir, S. O., Molander, G. A. Chem. Catal., 2022, doi:10.1016/j.checat.2022.03.007.

Sustainable Thioetherification via Electron Donor-Acceptor Photoactivation using Thianthrenium Salts

Cabrera-Afonso, M. J., Granados, A., Molander, G.A., Angew. Chem. Int. Ed., 2022, doi:10.1002/anie.202202706.

Nickel-Mediated Synthesis of Non-Anomeric C-Acyl Glycosides through Electron Donor–Acceptor Complex Photoactivation

Escolano, M., Cabrera-Alfonso, M.J., Ribagorda, M., Badir, S.O., Molander, G.A., J. Org. Chem., 2022, doi:10.1021/acs.joc.1c0304.