2010 to 2021

“Selectivity in the Elaboration of Bicyclic Borazarenes.” Bhattacharjee, A., Davies G. H. M., Saeednia, B. , Molander, G. A.,Adv. Synth. Catal., 2020,363, 1-19. doi: 10.1002/adsc.202001384.

“Developments in Photoredox-Mediated Alkylation for DNA-Encoded Libraries.” Patel, S., Badir, S. O., Molander, G. A.,Trends Chem., 2020,, Just Accepted doi: 10.1016/j.trechm.2020.11.010.

“Stereoinduction in Metallaphotoredox Catalysis.” Lipp, A., Badir, S. O., Molander, G. A.,Angew. Chem. Int. Ed., 2020,, Just Accepted doi: 10.1002/anie.202007668.

“Developments in Photoredox/Nickel Dual-Catalyzed 1,2-Difunctionalizations.” Badir, S. O., Molander, G. A.,Chem., 2020,6, 1327-1339. doi: 10.1016/j.chempr.2020.05.013.

“On the Nature of C(sp3)–C(sp2) Bond Formation in Nickel-Catalyzed Tertiary Radical Cross-Couplings: A Case Study of Ni/Photoredox Catalytic Cross-Coupling of Alkyl Radicals and Aryl Halides.” Yuan, M., Song, Z., Badir, S. O., Molander, G. A., Gutierrez, O.J. Am. Chem. Soc., 2020,142, 7225-7234. doi: doi.org/10.1021/jacs.0c02355.

“Diastereoselective olefin amidoacylation via photoredox PCET/nickel-dual catalysis: reaction scope and mechanistic insights.” Zheng, S., Zhang, S., Saeednia, B., Zhou, J. Anna, J. M., Hong, X., Molander, G. A.Chem. Sci., 2020,11, 4131-4137. doi: doi.org/10.1039/D0SC01459A.

“Photoredox Mediated Net Neutral Radical/Polar Crossover Reactions.” Wiles, R. J., Molander, G. A.Isreal Journal of Chemistry, 2020, Review Article. doi: doi.org/10.1002/ijch.201900166.

“Multifunctional Building Blocks Compatible with Photoredox-Mediated Alkylation for DNA-Encoded Library Synthesis.” Badir, S. B.; Sim, J.; Billings, K.; Csakai, A.; Zhang, X.; Dong, W.; Molander, G. A., Org. Lett., 2020, 22, 1046. doi: doi.org/10.1021/acs.orglett.9b04568.

“Radical–Polar Crossover Annulation: A Platform for Accessing Polycyclic Cyclopropanes.” Milligan, J. A.; Burns, K.; Le, A.; Polites, V. C.; Wang, Z.-J.; Molander, G. A.; Kelly, C. B. Adv. Synth. Catal., 2020, 362 242. doi: doi.org/10.1002/adsc.201901051.

“Three-Component Olefin Dicarbofunctionalization Enabled by Nickel/Photoredox Dual Catalysis.” Campbell, M. W.; Compton, J. S.; Kelly, C. B.; Molander, G. A., J. Am. Chem. Soc., 2019, 141, 20069. doi: doi.org/10.1021/jacs.9b08282.

“Oxa- and Azabenzonorbornadienes as Electrophilic Partners under Photoredox/Nickel Dual Catalysis.” Luo, Y.; Gutiérrez-Bonet, A.; Matsui, J. K.; Rotella, M. E.; Dykstra, R.; Gutierrez, O.; Molander, G. A. ACS Catal., 2019, 9, 8835. doi: doi.org/10.1021/acscatal.9b02458.

“Regioselective Single-Electron Tsuji–Trost Reaction of Allylic Alcohols: A Photoredox/Nickel Dual Catalytic Approach.” Wang, Z.; Zheng, S.; Romero, E.; Matsui, J. K.; Molander, G. A. Org. Lett., 2019, 21, 6543. doi: 10.1021/acs.orglett.9b02473.

“Metal-Free Defluorinative Arylation of Trifluoromethyl Alkenes via Photoredox Catalysis.” Wiles, R. J.; Phelan, J. P.; Molander, G. A. Chem. Comm., 2019, 55, 7599. doi: 10.1039/C9CC04265B.

“Photoredox-Catalyzed Multicomponent Petasis Reaction with Alkyltrifluoroborates.” Yi, J.; Badir, S. O.; Alam, R.; Molander, G. A. Org. Lett., 2019, 21, 4853. doi: 10.1021/acs.orglett.9b01747.

“Deaminative Reductive Arylation Enabled by Nickel/Photoredox Dual Catalysis.” Yi, J.; Badir, S. O.; Kammer, L. M.; Ribagorda, M.; Molander, G. A. Org. Lett., 2019, 21, 3346..

“Photoredox Catalysis Enables Access to N-Functionalized 2,1-Borazaronaphthalenes.” Wang, X.; Davies, H. M.; Koschitzky, A.; Wisniewski, S. R.; Kelly, C. B.; Molander, G. A. Org. Lett., 2019, 21, 2880..

“Desulfonative Photoredox Alkylation of N-Heteroaryl Sulfones – An Acid-free Approach for Substituted Heteroarene Synthesis.” Wang, Z.; Zheng, S.; Matsui, J. K.; Lu, Z.; Molander, G. A. Chem. Sci., 2019, 10, 4389. .

“Photoredox Radical/Polar Crossover Enables Construction of Saturated Nitrogen Heterocycles.” Pantaine, L. R. E.; Milligan, J. A.; Matsui, J. K.; Kelly, C. B.; Molander, G. A. Org. Lett., 2019, 21, 2317..

“Open-Air Alkylation Reactions in Photoredox-Catalyzed DNA-Encoded Library Synthesis.” Phelan, J. P.; Lang, S. B.; Sim. J.; Berritt, S.; Peat, A. J.; Billings, K.; Fan, L.; Molander, G. A. J. Am. Chem. Soc., 2019, 141, 3723..

“Synthesis of α-Fluoro-α-amino Acid Derivatives via Photoredox-Catalyzed Carbofluorination.” Sim, J.; Campbell, M. W.; Molander, G. A. ACS Catal., 2019, 9, 1559..

“Merging Photoredox PCET with Ni-Catalyzed Cross-Coupling: Cascade Amidoarylation of Unactivated Olefins.” Zheng, S.; Gutiérrez-Boent, Á.; Molander, G. A. Chem., 2019, 5, 339..

“Radical/Polar Annulation Reactions (RPARs) Enable the Modular Construction of Cyclopropanes.” Milligan, J. A.; Phelan, J. P.; Polites, V. C.; Kelly, C. B.; Molander, G. A. Org. Lett., 2018, 20, 6840..

“Alkyl Carbon-Carbon Bond Formation by Nickel/Photoredox Cross-Coupling.” Milligan, J. A.;* Phelan, J. P.;* Badir, S.O; Molander, G. A. Angew. Chem. Int. Ed. , 2018, 58, 6152..

“Photoredox/Nickel-Catalyzed Single-Electron Tsuji-Trost Reaction: Development and Mechanistic Insight.” Matsui, J. K.; Gutiérrez-Bonet, Á; Rotella, M.; Alam, R.; Gutierrez, O.; Molander, G. A. Angew. Chem. Int. Ed. , 2018, 57, 15847..

“Redox-Neutral Photocatalytic Cyclopropanation via Radical/Polar Crossover.” Phelan, J. P.; Lang, S. B.; Compton, J. S.; Kelly, C. B.; Dykstra, R.; Gutierrez, O.; Molander, G. A. J. Am. Chem. Soc. , 2018, 140 8037..

“3-Boryl-2,1-borazaronaphthalene: Umpolung Reagents for Diversifying Naphthalene Isosteres.” Compton, J. S.; Saeednia, B.; Kelly, C. B.; Molander, G. A. J. Org. Chem., 2018, 83 9484. .

“Photoredox-Catalyzed Direct Reductive Amination of Aldehydes without External Hydrogen/Hydride Source.” 321. Alam, R.; Molander, G. A. Org. Lett. , 2018, 20 2680..

“Synthesis of Reversed C‐Acyl Glycosides through Ni/Photoredox Dual Catalysis.” Badir, S. O.; Dumoulin, A.; Matsui, J. K.; Molander, G. A. Angew. Chem. Int Ed., 2018, 57 6610..

“Synthesis of Non–Classical Arylated C–Saccharides through Nickel/Photoredox Dual Catalysis.” Dumoulin, A.; Matsui, J. K.; Gutiérrez-Bonet, A.; Molander, G. A. Angew. Chem. Int. Ed. , 2018, 57 6614..

“Rapid Access to Diverse, Trifluoromethyl-Substituted Alkenes Using Complementary Strategies.” Phelan, J. P.; Wiles, R. J.; Lang, S. B.; Kelly, C. B.; Molander, G. A. Chem. Sci., 2018, 9 3215..

“Engaging Sulfinate Salts via Ni/Photoredox Dual Catalysis Enables Facile Csp2-SO2Ar Coupling.” Cabrera-Afonso, M. J.; Lu, Z. –P.; Kelly, C. B.; Lang, S. B.; Dykstra, R.; Gutierrez, O.; Molander, G. A. Chem. Sci., 2018, 9 3186..

“Scalable thioarylation of unprotected peptides and biomolecules under Ni/photoredox catalysis.” Vara, B. A.; Li, X.; Berritt, S.; Walters, C. R.; Petersson, E. J.; Molander, G. A. Chem. Sci., 2018, 9336..

“Direct Synthesis of Secondary Benzylic Alcohols Enabled by Photoredox/Ni Dual-Catalyzed Cross-Coupling.” Alam, R.; Molander, G. A. J. Org. Chem., 2017, 82, 13728..

“Nickel/Photoredox-Catalyzed Amidation via Alkylsilicates and Isocyanates.” Zheng, S.; Primer, D. N.; Molander, G. A. ACS Catal., 2017, 7, 7957..

“Photoredox Generation of Carbon-Centered Radicals Enables the Construction of 1,1-Difluoroalkene Carbonyl Mimics.” Lang, S. B.; Wiles, R. W.; Kelly, C. B.; Molander, G. A. Angew. Chem., Int. Ed., 2017, 56, 15073..

“Late-Stage C–H Alkylation of Heterocycles and 1,4-Quinones via Oxidative Homolysis of 1,4-Dihydropyridines.” Gutiérrez-Bonet, A.; Remeur, C.; Matsui, J. K.; Molander, G. A. J. Am. Chem. Soc., 2017, 139, 12251..

“Aminomethylation of Aryl Halides Using α-Silylamines Enabled by Ni/Photoredox Dual Catalysis.” Remeur, C.; Kelly, C. B.; Patel, N. R.; Molander, G. A. ACS Catal., 2017, 7, 6065..

“Enabling the Cross-Coupling of Tertiary Organoboron Nucleophiles through Radical-Mediated Alkyl Transfer.” Primer, D. N.; Molander, G. A. J. Am. Chem. Soc., 2017, 139, 9847..

“Regioselective Diversification of 2,1-Borazaronaphthalenes: Unlocking Isosteric Space via C–H Activation.” Davies, G. H. M.; Jouffroy, M.; Sherafat, F.; Saeednia, B.; Howshall, C.; Molander, G. A. J. Org. Chem., 2017, 82, 8072..

“Haloselective Cross-Coupling via Ni/Photoredox Dual Catalysis.” Lin, K.; Wiles, R. J.; Kelly, C. B.; Davies, G. H. M.; Molander, G. A. ACS Catal., 2017, 7, 5129..

“Direct Conversion of Carboxylic Acids to Alkyl Ketones.” Amani, J.; Molander, G. A. Org. Lett., 2017, 19, 3612..

“Azaborininones: Synthesis and Structural Analysis of a Carbonyl-Containing Class of Azaborines.” Davies, G. H. M.; Mukhtar, A.; Saeednia, B.; Sherafat, F.; Kelly, C. B.; Molander, G. A. J. Org. Chem., 2017, 82, 5380..

“O-Benzyl Xanthate Esters under Ni/Photoredox Dual Catalysis: Selective Radical Generation and Csp3–Csp2 Cross-Coupling.” Vara, B. A.; Patel, N. R.; Molander, G. A. ACS Catal., 2017, 7, 3955..

“Synergistic Visible-Light Photoredox/Nickel-Catalyzed Synthesis of Aliphatic Ketones via N–C Cleavage of Imides.” Amani, J.; Alam, R.; Badir, S.; Molander, G. A. Org. Lett., 2017, 19, 2426..

“Photoredox-Mediated Routes to Radicals: The Value of Catalytic Radical Generation in Synthetic Methods Development.” Matsui, J. K.; Lang, S. B.; Heitz, D. R.; Molander, G. A. ACS Catal., 2017, 7, 2563..

“Metal-free C–H alkylation of heteroarenes with alkyltrifluoroborates: a general protocol for 1°, 2° and 3° alkylation.” Matsui, J. K.; Primer, D. N.; Molander, G. A. Chem. Sci., 2017, 8, 3512..

“Mild, Redox-Neutral Alkylation of Imines Enabled by an Organic Photocatalyst.” Patel, N. P.; Kelly, C. B.; Siegenfeld, A. P.; Molander, G. A. ACS Catal., 2017, 7, 1766. .

“Organocatalyzed, Photoredox Heteroarylation of 2-Trifluoroboratochromanones via C–H Functionalization.” Matsui, J. K.; Molander, G. A. Org. Lett., 2017, 19, 950..

“Preparation of visible-light-activated metal complexes and their use in photoredox/nickel dual catalysis.” Kelly, C. B.; Patel, N. P.; Primer, D. P.; Jouffroy, M.; Tellis, J. C.; Molander, G. A. Nat. Protoc., 2017, 12, 472..

“Preparation of Diisopropylammonium Bis(catecholato)cyclohexylsilicate.” Lin, K.; Kelly, C. B.; Jouffroy, M.; Molander, G. A. Org. Synth., 2017, 94, 16..

“Synergistic Photoredox/Nickel Coupling of Acyl Chlorides with Secondary Alkyltrifluoroborates: Dialkyl Ketone Synthesis.” Amani, J.; Molander, G. A. J. Org. Chem., 2017, 82, 1856.

“Direct α-Arylation/Heteroarylation of 2-Trifluoroboratochromanones via Photoredox/Nickel Dual Catalysis.” Matsui, J. K.; Molander, G. A. Org. Lett., 2017, 19, 436.

“C(sp3)–C(sp2) cross-coupling of alkylsilicates with borylated aryl bromides – an iterative platform to alkylated aryl- and heteroaryl boronates.” Vara, B. A.; Jouffroy, M.; Molander, G. A. Chem. Sci., 2017, 8, 530.

“Method for Accessing Nitrogen-Containing, B-Heteroaryl-Substituted 2,1-Borazaronaphthalenes.” Davies, G. H. M.; Zhou, Z.-Z.; Jouffroy, M.; Molander, G. A. J. Org. Chem., 2016, 82, 549..

“1,4-Dihydropyridines as Alkyl Radical Precursors: Introducing the Aldehyde Feedstock to Nickel/Photoredox Dual Catalysis.” Gutiérrez-Bonet, A.; Tellis, J. C.; Matsui, J. K.; Vara, B. A.; Molander, G. A ACS Catal., 2016, 6, 8004.

“Photochemical Nickel-Catalyzed C–H Arylation: Synthetic Scope and Mechanistic Investigations.” Heitz, D. R.; Tellis, J. C.; Molander, G. A. J. Am. Chem. Soc., 2016, 138, 12715.

“Single-Electron Transmetalation via Photoredox/Nickel Dual Catalysis: Unlocking a New Paradigm for sp3-sp2 Cross-Coupling.” Tellis, J. C.; Kelly, C. B.; Primer, D. N.; Jouffroy, M.; Patel, N. R.; Molander, G. A. Acc. Chem. Res., 2016, 49, 1429.

“Visible-Light-Mediated Alkenylation, Allylation, and Cyanation of Potassium Alkyltrifluoroborates with Organic Photoredox Catalysts.” Heitz, D. R.; Rizwan, K.; Molander, G. A. J. Org. Chem., 2016, 81 7308.

“Phenol Derivatives as Coupling Partners with Alkylsilicates in Photoredox/Nickel Dual Catalysis.” Patel, N. R.; Molander, G. A. J. Org. Chem., 2016, 81 7271.

“Single-Electron Transmetalation: Photoredox/Nickel Dual Catalytic Cross-Coupling of Secondary Alkyl β-Trifluoroboratoketones and -esters with Aryl Bromides.” Tellis, J. C.; Amani, J.; Molander, G. A. Org. Lett., 2016, 18 2572.

“Single-Electron Transmetalation: Protecting-Group-Independent Synthesis of Secondary Benzylic Alcohol Derivatives via Photoredox/Nickel Dual Catalysis.” Karimi-Nami, R.; Tellis, J. C.; Molander, G. A. Org. Lett., 2016, 18 2572.

“Synthesis of Functionalized 1,3,2-Benzodiazaborole Cores Using Bench-Stable Components.” Davies, G. H. M.; Molander, G. A. J. Org. Chem., 2016, 81 3771.

“Accessing Elaborated 2,1-Borazaronaphthalene Cores Using Photoredox/Nickel Dual-Catalytic Functionalization.” Jouffroy, M.; Davies, G. H. M.; Molander, G. A. Org. Lett., 2016, 18 1606.

“Thioetherification via Photoredox/Nickel Dual Catalysis.” Jouffroy, M.; Kelly, C. B.; Molander, G. A. Org. Lett., 2016, 18 876.

“Engaging Alkenyl Halides with Alkylsilicates via Photoredox Dual Catalysis.” Patel, N. R.; Kelly, C. B.; Jouffroy, M.; Molander, G. A. Org. Lett., 2016, 18 746.

“Visible Light Photoredox Cross-Coupling of Acyl Chlorides with Potassium Alkoxymethyltrifluoroborates: Synthesis of α-Alkoxyketones.” Amani, J.; Sodagar, E.; Molander, G. A. Org. Lett., 2016, ASAP .

“Base-Free Photoredox/Nickel Dual-Catalytic Cross-Coupling of Ammonium Alkylsilicates.” Jouffroy, M.; Primer, D. N.; Molander, G. A. J. Am. Chem. Soc., 2016, 138, 475.

“Single-Electron Transmetalation: Synthesis of 1,1-Diaryl-2,2,2-trifluoroethanes by Photoredox/Nickel Dual Catalytic Cross-Coupling.” Ryu, D.; Primer, D. N.; Tellis, J. C.; Molander, G. A. Chem. Eur. J. , 2016, 22, 120.

“α-Arylation/Heteroarylation of Chiral α-Aminomethyltrifluoro-borates by Synergistic Iridium Photoredox/Nickel Cross-Coupling Catalysis.” El Khatib, M.; Serafim, R. A. M.; Molander, G. A. Angew. Chem. Int. Ed., 2016, 55, 254 .

“A modified procedure for the palladium catalyzed borylation/Suzuki-Miyaura cross-coupling of aryl and heteroaryl halides utilizing bis-boronic acid.” Molander, G. A.; Trice, S. L. J.; Tschaen, B. Tetrahedron, 2015, 71, 5758 .

“Copper-mediated N-arylation of methyl 2-aminothiophene-3-carboxylate with organoboron reagents.” Rizwan, K.; Karakaya, I.; Heitz, D.; Zubair, M.; Rasool, N.; Molander, G. A.Tetrahedron Lett., 2015, 56, 6839.

“Protecting group-free, selective cross-coupling of alkyltrifluoroborates with borylated aryl bromides via photoredox/nickel dual catalysis.” Yamashita, Y. Tellis, J. C.; Molander, G. A. Proc. Natl. Acad. Sci. U. S. A., 2015, 112, 12026.

“Organotrifluoroborates: Another Branch of the Mighty Oak.” Molander, G. A. J. Org. Chem., 2015, 80, 7837 .

“Toward Efficient Nucleophilic Azaborine Building Blocks for the Synthesis of B–N Naphthyl (Hetero)arylmethane Isosteres.” Amani, J.; Molander, G. A. Org. Lett., 2015, 17, 3624.

“Photoredox Cross-Coupling: Ir/Ni Dual Catalysis for the Synthesis of Benzylic Ethers.” Karakaya, I.; Primer, D. N.; Molander, G. A. Org. Lett., 2015, 17, 3294 .

“Nickel-Catalyzed Cross-Coupling of Photoredox-Generated Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed Cross-Couplings.” Gutierrez, O.; Tellis, J. C.; Primer, D. N.; Molander, G. A.; Kozlowski, M. C. J. Am. Chem. Soc., 2015, 137, 4896 .

“Engaging Nonaromatic, Heterocyclic Tosylates in Reductive Cross-Coupling with Aryl and Heteroaryl Bromides.” Molander, G. A.; Traister, K. M.; O’Neill, B. T. J. Org. Chem., 2015, 80, 2907 .

“Single-Electron Transmetalation: An Enabling Technology for Secondary Alkylboron Cross-Coupling.” Primer, D. N.; Karakaya, I.; Tellis, J. C.; Molander, G. A. J. Am. Chem. Soc., 2015, 137, 2195 .

“Reductive Cross-Coupling of 3-Bromo-2,1-borazaronaphthalenes with Alkyl Iodides.” Molander, G. A.; Wisniewski, S. R.; Traister, K. M. Org. Lett., 2014, 16, 3692.

“Accessing 2-(Hetero)arylmethyl-, -allyl-, and -propargyl-2,1-borazaronaphthalenes: Palladium-Catalyzed Cross-Couplings of 2-(Chloromethyl)-2,1-borazaronaphthalenes.” Molander, G. A.; Amani, J.; Wisniewski, S. R. Org. Lett., 2014, 16, 6024.

“Suzuki–Miyaura Cross-Coupling of Brominated 2,1-Borazaronaphthalenes with Potassium Alkenyltrifluoroborates.” Molander, G. A.; Wisniewski, S. R.; Etemadi-Davan, E. J. Org. Chem., 2014, 79, 11199.

“Diastereoselective Synthesis of Vicinally Di-trifluoromethylated Alkylboron Compounds via Successive Insertions of 2,2,2-Trifluorodiazoethane.” Molander, G. A.; Ryu, D. Angew. Chem. Int. Ed., 2014, 53, 14181.

“Accessing an Azaborine Building Block: Synthesis and Substitution Reactions of 2-Chloromethyl-2,1-borazaronaphthalene.” Molander, G. A.; Wisniewski, S. R.; Amani, J. Org. Lett., 2014, 16, 5636.

“Copper(II)-Mediated O-Arylation of Protected Serines and Threonines.” El Khatib, M.; Molander, G. A. Org. Lett., 2014, 16, 4944.

“Accessing 2,1-Borazaronaphthols: Self-Arylation of 1-Alkyl-2-aryl-3-bromo-2,1-borazaronaphthalenes.” Molander, G. A.; Wisniewski, S. R. J. Org. Chem., 2014, 79, 8339 .

“Arylation and Heteroarylation of Thienylsulfonamides with Organotrifluoroborates.” Noreen, M.; Rasool, N.; El Khatib, M.; Molander, G. A. J. Org. Chem., 2014, 79, 8339.

“Accessing Molecularly Complex Azaborines: Palladium-Catalyzed Suzuki–Miyaura Cross-Couplings of Brominated 2,1-Borazaronaphthalenes and Potassium Organotrifluoroborates.” Molander, G. A.; Wisniewski, S. R. J. Org. Chem., 2014, 79, 6663.

“Reductive Cross-Coupling of Nonaromatic, Heterocyclic Bromides with Aryl and Heteroaryl Bromides.” Molander, G. A.; Traister, K. M.; O’Neill, B. T. J. Org. Chem., 2014, 79, 5771.

“Single-electron Transmetalation in Organoboron Cross-coupling by Photoredox/Nickel Dual Catalysis.” Tellis, J. C.; Primer, D. N.; Molander, G. A. Science, 2014, 345, 433.

“Stereospecific Ni-Catalyzed Cross-Coupling of Potassium Alkenyltrifluoroborates with Alkyl Halides.” Molander, G. A.; Argintaru, O. A. Org. Lett., 2014, 16, 1904.

“Carbonylative Suzuki Couplings of Aryl Bromides with Boronic Acid Derivatives under Base-Free Conditions.” Bjerglund, K. M.; Skrydstrup, T.; Molander, G. A. Org. Lett., 2014, 16, 1888.

“A Convergent, Modular Approach to Functionalized 2,1-Borazaronaphthalenes from 2-Aminostyrenes and Potassium Organotrifluoroborates.” Wisniewski, S. R.; Guenther, C. L.; Argintaru, O. A.; Molander, G. A. J. Org. Chem., 2014, 79, 365.

“Copper-Mediated Radical Trifluoromethylation of Unsaturated Potassium Organotrifluoroborates.” Presset, M.; Oehlrich, D.; Rombouts, F.; Molander, G. A. J. Org. Chem., 2013, 78, 12837.

“Synthesis and Applications of α-Trifluoromethylated Alkylboron Compounds.” Argintaru, O. A.; Ryu, D.; Aron, I.; Molander, G. A.Angew. Chem. Int. Ed., 2013, 52, 13656.

“Synthesis and Suzuki–Miyaura Cross-Coupling of Enantioenriched Secondary Potassium β-Trifluoroboratoamides: Catalytic, Asymmetric Conjugate Addition of Bisboronic Acid and Tetrakis(dimethylamino)diboron to α,β-Unsaturated Carbonyl Compounds.” Molander, G. A.; Wisniewski, S. R.; Hosseini-Sarvari, M. Adv. Synth. Catal., 2013, 355, 3037.

“Pd-Catalyzed Alkynylation of 2-Chloroacetates and 2-Chloroacetamides with Potassium Alkynyltrifluoroborates.” Molander, G. A.; Traister, K. M. Org. Lett., 2013, 15, 5052.

“Suzuki–Miyaura Cross-Coupling of Potassium Trifluoro(N-Methylheteroaryl)borates with Aryl and Heteroaryl Halides.” Molander, G. A.; Ryu, D.; Hosseini-Sarvari, M.; Devulapally, R.; Seapy, D. G.J. Org. Chem., 2013, 78, 6648.

“Nickel-Catalyzed Borylation of Halides and Pseudohalides with Tetrahydroxydiboron [B2(OH)4].” Molander, G. A.; Cavalcanti, L. N.; García-García, C.J. Org. Chem., 2013, 78, 6427.

“Pd-Catalyzed Cross-Coupling of Potassium Alkenyltrifluoroborates with 2-Chloroacetates and 2-Chloroacetamides.” Molander, G. A.;Barcellos, T.; Traister, K. M.Org. Lett., 2013, 15, 3342.

“Synthesis of Trifluoromethylated Isoxazolidines: 1,3-Dipolar Cycloaddition of Nitrosoarenes, (Trifluoromethyl)diazomethane, and Alkenes.” Molander, G. A.; Cavalcanti, L. N.Org. Lett., 2013, 15, 3166.

“Pd-Catalyzed Suzuki–Miyaura Cross-Coupling Reactions between Sulfamates and Potassium Boc-Protected Aminomethyltrifluoroborates.” Molander, G. A.; Shin, I.Org. Lett., 2013, 15, 2534.

“Synthesis and Minisci Reactions of Organotrifluoroborato Building Blocks.” Presset, M.;Fleury-Brégeot, N.;Oehlrich, D.;Rombouts, F.; Molander, G. A.J. Org. Chem., 2013, 78, 4615.

“Palladium-Catalyzed α-Arylation of 2-Chloroacetates and 2-Chloroacetamides.” Molander, G. A.; Traister, K. M.; Barcellos, T. J. Org. Chem., 2013, 78, 4123.

“Complementary Regioselectivity in Rh(III)-Catalyzed Insertions of Potassium Vinyltrifluoroborate via C–H Activation: Preparation and Use of 4-Trifluoroboratotetrahydroisoquinolones.” Presset, M.; Oehlrich, D.; Rombouts, F.; Molander, G. A.Org. Lett., 2013, 15, 1528.

“Suzuki–Miyaura Cross-Coupling of Potassium Dioxolanylethyltrifluoroborate and Aryl/Heteroaryl Chlorides.” Fleury-Brégeot, N.; Oehlrich, D.; Rombouts, F.; Molander, G. A.Org. Lett., 2013, 15, 1536.

“Pd-Catalyzed Aldehyde to Ester Conversion: A Hydrogen Transfer Approach.” Tschaen, B.; Schmink, J.; Molander, G. A.Org. Lett., 2013, 15, 500.

“Synthesis of 1-Naphthol via Oxidation of Potassium 1-Naphthyltrifluoroborate.” Molander, G. A.; Siddiqui, S. Z.; Fleury-Brégeot, N. Org. Synth., 2013, 90, 153.

“Suzuki–Miyaura Cross-Coupling of Potassium Alkoxyethyltrifluoroborates: Access to Aryl/Heteroarylethyloxy Motifs.” Fleury-Brégeot, N; Presset, M.; Beaumard, F.; Colombel, V.; Oehlrich, D.; Rombouts, F.; Molander G. A.J. Org. Chem., 2012, 77, 10399.

“Stereospecific Cross-Coupling of Secondary Organotrifluoroborates: Potassium 1-(Benzyloxy)alkyltrifluoroborates.” Molander, G. A.; Wisniewski, S. R.J. Am. Chem. Soc., 2012, 134, 16856.

“Scope of the Two-Step, One-Pot Palladium-Catalyzed Borylation/Suzuki Cross-Coupling Reaction Utilizing Bis-Boronic Acid.” Molander, G. A.; Trice, S. L. J.; Kennedy, S. M.J. Org. Chem., 2012, 77, 8678.

“Palladium-Catalyzed Borylation of Aryl and Heteroaryl Halides Utilizing Tetrakis(dimethylamino)diboron: One Step Greener.” Molander, G. A.; Trice, S. L. J.; Kennedy, S. M.Org. Lett., 2012, 14, 4814.

“Potassium Boc-Protected Secondary Aminomethyltrifluoroborates: Synthesis and Suzuki–Miyaura Cross-Coupling Reactions.” Molander, G. A.; Shin, I. Org. Lett., 2012, 14, 4458.

“Oxidative Condensations To Form Benzimidazole-Substituted Potassium Organotrifluoroborates.” Molander, G. A.; Ajayi, K..Org. Lett., 2012, 14, 4242.

“Activation of Si–Si Bonds for Copper(I)-Catalyzed Conjugate Silylation.” Iannazzo, L.;Molander, G. A. Eur. J. Org. Chem., 2012, 4923.

“Scope of the Palladium-Catalyzed Aryl Borylation Utilizing Bis-Boronic Acid.” Molander, G. A.; Trice, S. L. J.; Kennedy, S. M.; Dreher, S. D.; Tudge, M. T. J. Am. Chem. Soc., 2012, 134, 11667.

“Rapid and Efficient Access to Secondary Arylmethylamines.” Fleury-Brégeot, N.; Raushel, J.; Sandrock, D. L.; Dreher, S. D.; Molander, G. A. Chem. Eur. J., 2012, 18, 9564.

“Suzuki–Miyaura Cross-Coupling Reactions of Potassium Boc-Protected Aminomethyltrifluoroborate with Aryl and Hetaryl Mesylates.” Molander, G. A.; Shin, I. Org. Lett., 2012, 14, 3138.

“Amide-Forming Ligation of Acyltrifluoroborates and Hydroxylamines in Water.” Dumas1, A. M.; Molander, G. M.; Bode, J. W. Angew. Chem. Int. Ed., 2012, 51, 5683.

“Nitrosation of Aryl and Heteroaryltrifluoroborates with Nitrosonium Tetrafluoroborate.” Molander, G. A.; Cavalcanti, L. N. J. Org. Chem., 2012, 77, 4402.

“Suzuki Coupling of Potassium Cyclopropyl- and Alkoxymethyltrifluoroborates with Benzyl Chlorides.” Colombel, V.; Rombouts, F.; Oehlrich, D.; Molander, G. A. J. Org. Chem., 2012, 77, 2966.

“Synthesis and Reactivity of Solid-Supported Organotrifluoroborates in Suzuki Cross-Coupling.” Colombel, V.; Presset, M.; Oehlrich, D.; Rombouts, F.; Molander, G. A. Org. Lett., 2012, 14, 1680.

“Synthesis and cross-coupling reactions of imidomethyltrifluoroborates with aryl chlorides.” Devulapally, R.; Fleury-Brégeot, N.; Molander, G. A.; Seapy, D. G. Tetrahedron Lett., 2012, 53, 1051.

“Palladium-Catalyzed Hiyama Cross-Coupling of Aryltrifluorosilanes with Aryl and Heteroaryl Chlorides.” Molander, G. A.; Iannazzo, L. J. Org. Chem., 2011, 76, 9182.

“Copper-Catalyzed β-Boration of α,β-Unsaturated Carbonyl Compounds with Tetrahydroxydiborane.” Molander, G. A.; McKee, S. A. Org. Lett., 2011, 13, 4684.

“Cross-Coupling of Mesylated Phenol Derivatives with Potassium Cyclopropyltrifluoroborate.” Molander, G. A.; Beaumard, F.; Niethamer, T. K. J. Org. Chem., 2011, 76, 8126.

“Metal-Free Chlorodeboronation of Organotrifluoroborates.” Molander, G. A.; Cavalcanti, L. J. Org. Chem., 2011, 76, 7195.

“Iridium-Catalyzed Allylic Amination Route to α-Aminoboronates: Illustration of the Decisive Role of Boron Substituents.” Touchet, S.; Carreaux, F.; Molander, G. A.; Carboni, B.; Bouillon, A. Adv. Synth. Catal., 2011, 353, 3391.

“Synthesis and Suzuki–Miyaura Cross-Coupling Reactions of Potassium Boc-Protected Aminomethyltrifluoroborate with Aryl and Hetaryl Halides.” Molander, G. A.; Shin, I. Org. Lett., 2011, 13, 3956.

“Direct Alkylation of Heteroaryls Using Potassium Alkyl- and Alkoxymethyltrifluoroborates.” Molander, G. A.; Colombel, V.; Braz, V. A. Org. Lett., 2011, 13, 1852.

“Synthesis and Cross-Coupling of Sulfonamidomethyltrifluoroborates.” Molander, G. A.; Fleury-Brégeot, N.; Hiebel, M.-A. Org. Lett., 2011, 13, 1694.

“Reinvestigation of Aminomethyltrifluoroborates and Their Application in Suzuki−Miyaura Cross-Coupling Reactions.” Raushel, J.; Sandrock, D. L.; Josyula, K. V.; Pakyz, D.; Molander, G. A. J. Org. Chem., 2011, 76, 2762.

“Cross-Coupling of Mesylated Phenol Derivatives with Potassium Ammonio- and Amidomethyltrifluoroborates.” Molander, G. A.; Beaumard, F. Org. Lett., 2011, 13, 1242.

“Oxidation of Organotrifluoroborates via Oxone.” Molander, G. A.; Cavalcanti, L. N. J. Org. Chem., 2011, 76, 623.

“Synthesis of the stereogenic triad of the halicyclamine A core.” Molander, G. A.; Cadoret, F. Tetrahedron Lett., 2011, 52, 2199.

“Nickel-Catalyzed Cross-Coupling of Potassium Aryl- and Heteroaryltrifluoroborates with Unactivated Alkyl Halides.” Molander, G. A.; Argintaru, O. A.; Aron , I.; Dreher, S. D. Org. Lett., 2010, 12, 5783.

“Palladium-Catalyzed, Direct Boronic Acid Synthesis from Aryl Chlorides: A Simplified Route to Diverse Boronate Ester Derivatives.” Molander, G. A.; Trice, S. L. J.; Dreher, S. D. J. Am. Chem. Soc., 2010, 132, 17701.

“Stereospecific Cross-Coupling of Secondary Alkyl β-Trifluoroboratoamides.” Sandrock, D. L.; Jean-Gérard, L.; Chen, C.-y., Dreher, S. D.; Molander, G. A. J. Am. Chem. Soc., 2010, 132, 17108.

“Synthesis of Amidomethyltrifluoroborates and Their Use in Cross-Coupling Reactions.” Molander, G. A.; Hiebel, M.-A. Org. Lett., 2010, 12, 4876.

“Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions of Enantiomerically Enriched Potassium β-Trifluoroboratoamides with Various Aryl- and Hetaryl Chlorides.” Molander, G. A.; Shin, I.; Jean-Gérard, L. Org. Lett., 2010, 12, 4384.

“Nickel-Catalyzed C−O Activation of Phenol Derivatives with Potassium Heteroaryltrifluoroborates.” Molander, G. A.; Beaumard, F. Org. Lett., 2010, 12, 4022.

“Synthesis of an Acyltrifluoroborate and Its Fusion with Azides To Form Amides.” Molander, G. A.; Raushel, J.; Ellis, N. M. J. Org. Chem., 2010, 75, 4304.