Layered and Porous Materials

498. J. D. Dillenburger, L. Schulte, M. Suleiman, C. J. Sheehan, and T. E. Mallouk, “Selective covalent basal plane modification as a probe of hydroxide ion conduction pathways in magnesium aluminum layered double hydroxides,” ChemSusChem, in press.

494. J. D. Dillenburger, L. Schulte, P. Mahale, M. Suleiman, and T. E. Mallouk, “Anion-dependent structure, dehydration, and hydroxide ion conductivity of magnesium aluminum layered double hydroxides,” Chem. Mater. 35, 6437–6446 (2023) https://doi.org/10.1021/acs.chemmater.3c01161

486. R. Uppuluri, S. Hwang, S. Maheshwari, P. Zhao, J. Gray, A. Rosas, H. Yennawar, X. Fan, M. J. Janik, and T. E. Mallouk, “Stabilization of dinuclear rhodium and iridium clusters on layered titanate and niobate supports,” Inorg. Chem., 62,1113–1121 (2023). https://doi.org/10.1021/acs.inorgchem.2c03225.

485. L. R. De Jesús Baez, A. S. Rosas, P. Mahale, and T. E. Mallouk, “A chelation-based route to aluminum free layered transition metal carbides (MXenes),” ACS Omega, in press.

482. J. D. Dillenburger, M. A. T. Nguyen, P. Xu, J. R. Shallenberger, and T. E. Mallouk, “Basal plane functionalization of niobium disulfide nanosheets with cyclopentadienylmanganese(I) dicarbonyl,” Inorg. Chem., 61,14824–14832 (2022). https://doi.org/10.1021/acs.inorgchem.2c02366

478. P. Mahale, B. Lee, H.Y. Cheng, M. Segad, and T. E. Mallouk, “Small-Angle X-Ray Scattering Analysis of Colloidal Crystals and Replica Materials Made From L-Arginine Stabilized Silica Nanoparticles,” ACS-AMI, 14, 9398-9407 (2022). https://doi.org/10.1021/acsami.1c19193

474. J. Knobloch, B., McBennett, C. Bevis, S. Yazdi, T. Frazer, A. Adak, E. Nelson, J. Hernandez-Charpak, H. Cheng, A. Grede, P. Mahale, N. N. Nova, N. Giebink, T. E. Mallouk, J. V. Badding, H. Kapteyn, B. Abad Mayor, and M. Murnane, “Structural and Elastic Properties of Empty-Pore Metalattices Extracted Via Nondestructive Coherent Extreme UV Scatterometry and Electron Tomography,” ACS-AMI, 14, 41316–41327 (2022). https://doi.org/10.1021/acsami.2c09360

471. A. Rana, C.-T. Liao, E. Iacocca, J. Zou, M. Pham, E.-E.C. Subramanian, Y. H. Lo, S. A. Ryan, X. Lu, C. S. Bevis, R. M. Karl, Jr., A. J. Glaod, Y.-S. Yu, P. Mahale, D. A. Shapiro, S. Yazdi, T. E. Mallouk, S. J. Osher, H. C. Kapteyn, V. H. Crespi, J. V. Badding, Y. Tserkovnyak, M. M. Murnane, and J. Miao, “Creation and observation of magnetic monopoles and their interactions in a ferromagnetic superlattice,” Nature Nanotechnol., 18, 227–232 (2023). https://www.nature.com/articles/s41565-022-01311-0.

469.  P. Moradifar, L. Kang, Y. Liu, A. Glaid, P. Mahale, P. Batson, T. E. Mallouk, J. V. Badding, D. H. Werner, and N. Alem, “Plasmonic Metalattices: A Correlated Monochromated Electron Energy Loss Study and Theoretical Calculations,” Microsc. Microanal., 25, 678-679 (2021). https://doi.org/10.1017/S1431927619004124

462.  A. Fajardo Peralta, M. A. T. Nguyen, J. Valenzuela-Benavides, A. Brodie, R. Nunes Gontijo, A. L. Elias, N. Perea Lopez, T. E. Mallouk, and M. Terrones, “Evolution of spectroscopy features in layered MoSxSe(2-x) solid solutions,” Materials Research Express, 9, 046301 (2022). https://doi.org/10.1088/2053-1591/ac5ef3

461. P. Mahale, P. Moradifar, H. Y. Cheng, N. Nabi Nova, A. J. Grede, B. Lee, L. R. De Jesus, M. Wetherington, N. C. Giebink, J. V. Badding, and T. E. Mallouk, “An oxide-free 3-dimensional germanium/silicon core-shell metalattice made by high pressure confined chemical vapor deposition,” ACS Nano, 14, 10, 12810-12818, (2020) PDF.

459. W. Zhang, R. Uppuluri, T. E. Mallouk, and C. T. Campbell, “Silver Adsorption on Calcium Niobate(001) Nanosheets: Calorimetric Energies Explain Sinter-Resistant Support,” J. Am. Chem. Soc., 142, 15751−15763 (2020) PDF.

457. B. Abad-Mayor, J. Knobloch, T. Frazer, J. Hernandez-Charpak, H. Cheng, A. Grede, N. C. Giebink, T. E. Mallouk, P. Mahale, N. Nova, A. Tomaschke, V. Ferguson, V. H. Crespi, V. Gopalan, H. Kapteyn, J. V. Badding, and M. Murnane, “Nondestructive measurements of the mechanical and structural properties of nanostructured metalattices,” Nano Lett., (2020) PDF.

455. Y. Gao, D. Wang, Y. K. Shin, Z. Yan, Z. Han, J. Hossain, S. Shen, A. AlZahrani, A. C. T. van Duin, T. E. Mallouk, and D. Wang, “Stable metal anodes enabled by a labile organic molecule bonded to a reduced graphene oxide aerogel,” PNAS, 117, 48, 30135-30141 (2020) PDF.

449. W. Chen, D. Taljreja, D. Eichfeld, P. Mahale, N. Nabi Nova, H. Y. Cheng, J. L. Russell, S.-Y. Yu, N. C. Giebink, N. Poilvert, G. D. Mahan, S. E. Mohney, V. H. Crespi, T. E. Mallouk, J. V. Badding, B. Foley, V. Gopalan, and I. Dabo,”Achieving minimal heat conductivity by ballistic confinement in phononic metalattices,” ACS Nano, 14, 4235-4243 (2020) PDF.

445. R. Uppuluri, H. Akamatsu, A. Sen Gupta, H. Wang, C. M. Brown, K. E. Agueda Lopez, N. Alem, V. Gopalan, and T. E. Mallouk,”Competing polar and antipolar structures in the Ruddlesden-Popper layered perovskite Li2SrNb2O7,” Chem. Mater. 31, 4418-4425 (2019). PDF

442. Y. Chen, Y. Liu, P. Moradifar, A. J. Glaid, J. L. Russell, P. Mahale, S.-Y. Yu, T. E. Culp, M. Kumar, E. D. Gomez, S. E. Mohney, T. E. Mallouk, N. Alem, J. V. Badding, and Y. Liu,”Quantum transport in three-dimensional metalattices of platinum featuring an unprecedentedly large surface area to volume ratio,” Phys. Rev. Mater. 4, 035201 (2020) PDF.

440. J. L. Russell, N.-L. Tran, and T. E. Mallouk , “Adaptive shape ripening and interparticle bridging of L-arginine-stabilized silica nanoparticles during evaporative colloidal crystal assembly,” ACS Adv. Mater. Interf., 11, 4568-4577 (2019).PDF

439. K. Maeda and T. E. Mallouk, “Two-Dimensional Metal Oxide Nanosheets as Building Blocks for Artificial Photosynthetic Assemblies,” Bull. Chem. Soc. Japan, 92, 38-54 (2019). PDF

435. Y. Gao, D. Wang, Y. C. Li, Z. Yu, T. E. Mallouk, and D. Wang, “Salt-based organic-inorganic nanocomposites: towards a stable lithium metal/Li10GeP2S12 solid electrolyte interface,” Angew. Chem., in press. e-article link

434. Y. Gao, Z. Yan, J. L. Gray, X. He, T. Chen, Q. Huang, Y. C. Li, H. Wang, S. H. Kim, T. E. Mallouk, and D. Wang “Polymer–inorganic solid–electrolyte interphase for stable lithium metal batteries under lean electrolyte conditions,” Nature Mater. 18, 384-389 (2019). PDF

431. M. A. T. Nguyen, A. Sen Gupta, J. Shevrin, H. Akamatsu, P. Xu, Z. Lin, K. Wang, J. Zhu, V. Gopalan, M. Terrones and T. E. Mallouk, “Random anion distribution in MSxSe2-x(M=Mo, W) crystals and nanosheets,” RSC Adv. 8, 9871 – 9878 (2018). PDF

429. G. F. Mancini, R. M. Karl, Jr., E. R. Shanblatt, C. S. Bevis, D. F. Gardner, M. D. Tanksalvaia, J. L. Russell, D. E. Adams, H. C. Kapteyn, J. V. Badding, T. E. Mallouk, and M. M. Murnane, “Colloidal Crystal Order and Structure Revealed by Tabletop Extreme Ultraviolet Scattering and Coherent Diffractive Imaging,” Optics Express 26, 321043 (2018). PDF

428. R. Uppuluri, A. Sen Gupta, A. S. Rosas, and T. E. Mallouk, “Soft Chemistry of Ion-Exchangeable Layered Metal Oxides,” Chem. Soc. Rev. 47, 2401-2430 (2018). PDF

425. Y. Liu, S. Kempinger, R. He, T. P. Day, P. Moradifar, S.-Y. Yu, J. L. Russell, V. M. Torres, P. Xu, T. E. Mallouk, S. E. Mohney, N. Alem, N. Samarth, and J. V. Badding, “Confined chemical fluid deposition of ferromagnetic metalattices,” Nano Lett. 18, 546-552 (2018). PDF

424. D. Xu, P. Xu, Y. Zhu, W. Peng, Y. Li, G. Zhang, F. Zhang, T. E. Mallouk, and X. Fan, High yield exfoliation of WS2 crystals into 1-2 layer semiconducting nanosheets and efficient photocatalytic hydrogen evolution from WS2-CdS nanorod composites, ACS Appl. Mater. Interf., 10, 2810-2818 (2018). PDF

422. J. L. Russell and T. E. Mallouk, “Double replication of silica colloidal crystal films,” ACS Appl. Mater. Interf., 9, 42075-42083 (2017). PDF

418. Y. Gao, R. Yi, Y. C. Li, J. Song, S. Chen, Q. Huang, T. E. Mallouk, and D. Wang, “General Method of Manipulating Formation, Composition, and Morphology of Solid-Electrolyte Interphases for Stable Li-Alloy Anodes,” J. Am. Chem. Soc. 139, 17359-17367 (2017). PDF

417. T. M. F. Marques, M. E. Strayer, A. Silva, A. Ghosh, O. P. Ferreira, K. Fujisawa, J. R. Alves da Cunha, G. J. P. Abreu, M. Terrones, T. E. Mallouk, and B. C. Viana, “Homogeneously dispersed CeO2 nanoparticles on exfoliated hexaniobate nanosheets,” J. Phys. Chem. Solids, 111, 335-342 (2017). PDF

414. J. L. Russell, G. H. Noel, J. Warren, N.-L. Tran, and T. E. Mallouk,”Binary colloidal crystal films grown by vertical evaporation of silica nanoparticle suspensions,” Langmuir, 33, 10366-10373 (2017). PDF

413. N. I. Kovtyukhova, N. Perea-Lopez, M. Terrones, and T. E. Mallouk, “Atomically thin layers of graphene and hexagonal boron nitride made by solvent exfoliation of their phosphoric acid intercalation compounds,” ACS Nano, 11, 6746-6754 (2017). PDF

408. A. Sen Gupta, H. Akamatsu, F. G. Brown, M.A.T. Nguyen, M. E. Strayer, P. Lapidus, S. Yoshida, K. Fujita, K. Tanaka, A. Togo, I. Tanaka, T. E. Mallouk, and V. Gopalan, “Competing structural instabilities in the Ruddlesden-Popper derivatives HRTiO4 (R = rare earths): oxygen octahedral rotations including noncentrosymmetriciity and layer sliding retaining centrosymmetricity,” Chem. Mater., 29, 656 – 665 (2017). PDF

404. P. Xu, T. J. Milstein, and T. E. Mallouk, “Flat-band potentials of molecularly thin metal oxide nanosheets,” ACS Appl. Mater. 8, 11539-11547 (2016). PDF

401. X. Fan, P. Xu, Y. C. Li, D. Zhou, Y. Sun, M. A. T. Nguyen, M. Terrones, and T. E. Mallouk, “Controlled exfoliation of MoS2 crystals into trilayer nanosheets,” J. Am. Chem. Soc., 138, 5143-5149 (2016). PDF

399. M. E. Strayer, T. P. Senftle, J. P. Winterstein, N. M. Vargas-Barbosa, R. Sharma, R. M. Rioux, M. J. Janik, and T. E. Mallouk, “Charge transfer stabilization of late transition metal oxide nanoparticles on a layered niobate support,” J. Am. Chem. Soc. 137, 16216-16224 (2015). PDF

397. A. McCreary, A. Berkdemir, J. Wang, M. A. Nguyen, A. L. Elias, N. Perea-Lopez, K. Fujisawa, B. Kabius, V. Carozo, D. A. Cullen, T. E. Mallouk, J. Zhu, and M. Terrones, “Distinct photoluminescence and Raman spectroscopy signatures for identifying highly crystalline WS2 monolayers produced by different growth methods,” J. Mater. Res. 31, 931-944 (2016). e-article link

396. M. E. Strayer, A. Sen Gupta, H. Akamatsu, S. Lei, N. A. Benedek, V. Gopalan, and T. E. Mallouk, “Emergent non-centrosymmetry and piezoelectricity driven by oxygen octahedral rotations in n = 2 Dion-Jacobson phase layer perovskites,” Adv. Func. Mater., DOI: 10.1002/adfm.201504046 (2016). e-article link

392. N. Lu, C. Zhang, C.-H. Lee, J. P. Oviedo, M. A. T. Nguyen, X. Peng, R. M. Wallace, T. E. Mallouk, J. A. Robinson, J. Wang, K. Cho, and M. J. Kim, “Atomic and electronic structures of WTe2 probed by electron microscopy and ab initio calculations,” J. Phys. Chem. C, 120, 8364-8369 (2016). PDF

391. A. Sen Gupta, H. Akamatsu, M. E. Strayer, S. Lei, T. Kuge, K. Fujita, C. dela Cruz, A. Togo, I. Tanaka, K. Tanaka, T. E. Mallouk, and V. Gopalan, “Improper inversion symmetry breaking and piezoelectricity through oxygen octahedral rotations in layered perovskite family, LiRTiO4 (R= rare earths),” Adv. Elec. Mater., 2: 1500196 (2015). e-article link

390. X. Fan, P. Xu, D. Zhou, Y. Sun, Y. C. Li, M. A. T. Nguyen, M. Terrones, and T. E. Mallouk, “Fast and efficient preparation of exfoliated 2H MoS2 nanosheets by sonication-assisted lithium intercalation and infrared laser-induced 1T to 2H phase reversion,” Nano Lett., 15, 5956-5960 (2015). PDF

388. C.-H. Lee, E. Cruz Silva, L. Calderin, M. A. T. Nguyen, M. J. Hollander, B. Bersch, T. E. Mallouk, and J. A. Robinson , “Tungsten ditelluride: a layered semimetal,” Scientific Reports, 5, 10013 (2015). PDF

384. A. Kondo, A. S. Hall, T. E. Mallouk, and K. Maeda, “A new synthetic route to microporous silica with well-defined pores by replication of a metal-organic framework,” Chem. Eur. J., 21, 12148-52 (2015). e-article link

383. J. Wang, D. Rhodes, S. Feng, M. A. T. Nguyen, K. Watanabe, T. Taniguchi, T. E. Mallouk, M. Terrones, L. Balicas, and J. Zhu, “Gate-modulated conductance of few-layer WSe2 field-effect transistors in the subgap regime: schottky barrier transistor and subgap impurity states,” Appl. Phys. Lett., 106, 152104 (2015). PDF

377. R. Lv, J. A. Robinson, R. E. Schaak, D. Sun, Y. Sun, T. E. Mallouk, and M. Terrones, “Transition metal dichalcogenides and beyond: synthesis, properties, and applications of single- and few-layer nanosheets,” Acc. Chem. Res., 48, 56-64 (2015). PDF

374. E. del Corro, H. Terrones, A. L. Elias, C. Fantini, S. Feng, M. A. Nguyen, T. E. Mallouk, M. Terrones, and M. A. Pimenta, “Excited excitonic states in 1L, 2L, 3L and bulk WSe2observed by resonant Raman spectroscopy,” ACS Nano, 8, 9629-9635 (2014). PDF

368. M. E. Strayer, J. M. Binz, M. Tanase, R. Sharma, R. M. Rioux, and T. E. Mallouk, “Interfacial bonding stabilizes rhodium and rhodium oxide nanoparticles on layered Nb- and Ta-oxide supports,” J. Am. Chem. Soc., 136, 5687-5696 (2014). PDF

367. H. Terrones, E. Del Corro-Garcia, S. Feng, J. M. Poumirol, D. Rhodes, D. Smirnov, N. R. Pradhan, Z. Lin, M. A. T. Nguyen, A. L. Elias, T. E. Mallouk, L. Balicas, M. A. Pimenta, and M. Terrones, “New first-order Raman-active modes in few layered transition metal dichalcogenides,” Scientific Reports, 4, 4215 (2014). PDF

366. N. I. Kovtyukhova, Y. Wang, A. Berkdemir, R. Cruz-Silva, M. Terrones, V. H. Crespi and T. E. Mallouk, “Non-oxidative intercalation and exfoliation of graphite by Bronsted acids,” Nature Chem., 6, 957-963 (2014). PDF

365. A. Winchester, S. Ghosh, S. Feng, A. L. Elias, T. Mallouk, M. Terrones, S. Talapatra, “Electrochemical characterization of liquid-phase exfoliated molybdenum disulfide,” ACS Adv. Mater. Interf., 6, 2125-2130 (2014). PDF

361. T. I. Draskovic, T.-H. Wang, C. N. Henderson, and T. E. Mallouk, “Protonic and electronic conductivity of the layered perovskite oxides HCa2Nb3O10 and Ca4Nb6O19,” Int. J. Hydrogen Energy, 39, 4576-4580 (2014). PDF

360. T.-H. Wang, T. I. Draskovic, C. N. Henderson, and T. E. Mallouk, “Synthesis, exfoliation, and electronic/protonic conductivity of the Dion-Jacobson phase layer perovskite HLa2Ti2TaO10.nH2O,” Chem. Mater., 26, 898-906 (2014). PDF Correction

356. A. S. Hall, A. Kondo, K. Maeda, and T. E. Mallouk, “Microporous brookite-phase titania made by replication of a metal-organic framework” J. Am. Chem. Soc., 135, 16276-16279 (2013). PDF

352. A. L. Elias, N. Perea-Lopez, A. Castro-Beltran, Y. Berkdemir, R. Lv, S. Feng, A. Long, T. Hayashi, Y. A. Kim, M. Endo, H. Gutierrez, N. Pradhan, L. Balicas, T. Mallouk, F. Lopez-Urias, H. Terrones, and M. Terrones, “Controlled synthesis and transfer of large area WS2 sheets: from single-layer to few-layers,” ACS Nano, 7, 5235-5242 (2013). PDF

351. N. I. Kovtyukhova, Y. Wang, R. Lv, M. Terrones, V. H. Crespi, and T. E. Mallouk, “Reversible intercalation of hexagonal boron nitride with Bronsted acids,” J. Am. Chem. Soc., 135, 8372-8381 (2013). PDF

340. J. W. Lee, A. S. Hall, J.-D. Kim, and T. E. Mallouk, “A facile and template-free hydrothermal synthesis of Mn3O4 nanorods on graphene sheets for supercapacitor electrodes with long cycle stability,” Chem. Mater. 24, 6, 1158-1164 (2012). PDF

321. E. C. Sklute, M. Eguchi, M. S. Angelone, H. P. Yennawar, and T. E. Mallouk, “Orientation of diamagnetic layered transition metal oxide particles in 1-Tesla magnetic fields,” J. Am. Chem. Soc., 133, 1824-1831 (2011). PDF

308. Y. Kobayashi, M. Tian, M. Eguchi, and T. E. Mallouk, “Ion-exchangeable, electronically conducting layered perovskite oxyfluorides,” J. Am. Chem. Soc., 131, 9849-9855 (2009). PDF

306. K. Maeda, M. Eguchi, W. J. Youngblood, and T. E. Mallouk, “Calcium niobate nanosheets prepared by the polymerized complex method as catalytic materials for photochemical hydrogen evolution,” Chem. Mater., 21, 3611-3617 (2009). PDF

305. K. Maeda and T. E. Mallouk, “Comparison of two- and three-layer restacked Dion-Jacobson niobate nanosheets as catalysts for photochemical hydrogen evolution,” J. Mater. Chem., 19, 4813-4818 (2009). PDF

301. K. Maeda, M. Eguchi, S.-H. A. Lee, W. J. Youngblood, H. Hata, and T. E. Mallouk, “Photocatalytic hydrogen evolution from hexaniobate nanoscrolls and calcium niobate nanosheets sensitized by ruthenium(ii) bipyridyl complexes,” J. Phys. Chem. C, 113, 7962-7969 (2009). PDF