January 5, 2023

We have a new paper in the Journal of the American Chemical Society!

“Synthesis and Characterization of a Bridging Cerium(IV) Nitride Complex.” Wilson, H. H.; Yu, X.; Cheisson, T.; Smith, P. W.; Pandey, P.; Carroll, P. J.; Minasian, S. G.; Autschbach, J.; Schelter, E. J.  J. Am. Chem. Soc. 2023. In print. Read it here ->

December 15, 2022

We have a new paper in Inorganic Chemistry!

“Metalating 5-Methyl-2-[(2-nitrophenyl)amino]-3-thiophenecarbonitrile (ROY): Understanding the Denticity and Speciation of Complexes of the ROY Anion” Kumar, A.; Pandey, P.; Gau, M. R.; Carroll, P. J.; Schelter, E. J. Inorg. Chem. 2022, 61 (51), 20785-20792. Read it here ->

November 3, 2022

We have a new paper in Organometallics!

“Synthesis, Electrochemical, and Computational Studies of Organocerium(III) Complexes with Ce–Aryl Sigma Bonds” Pandey, P.; Yu, X.; Panetti, G. B.; Lapsheva, E.; Gau, M. R.; Carroll, P. J.; Autschbach, J.; Schelter, E. J. Organometallics 2022. In print. Link

9.19.22 – We have a new paper in Journal of the American Chemical Society!

“Actinide–Oxygen Multiple Bonds from Air: Synthesis and Characterization of a Thorium Oxo Supported by Redox-Active Ligands” Rupasinghe, D. M. R. Y. P.; Baxter, M. R.; Gupta, H.; Poore, A. T.; Higgins, R. F.; Zeller, M.; Tian, S.; Schelter, E. J.; Bart, S. C. J. Am. Chem. Soc. 2022, 144 (38), 17423-17431. Link

8.30.22 – We have a new paper in Accounts of Chemical Research!

“Coordination Chemistry-Driven Approaches to Rare Earth Element Separations” Higgins, R. F.; Ruoff, K. P.; Kumar, A.; Schelter, E. J. Acc. Chem. Res. 2022, 55 (18), 2616-2627. Link

Paper Accepted

03.21.22 – We have a new paper in Organic Chemistry Frontiers!

“Light-Mediated Aerobic Oxidation of C(sp3)−H Bonds by a Ce(IV) Hexachloride Complex” Wang, Y-H.; Yang, Q.; Walsh, P.; Schelter, E. J. Org. Chem. Front. 2022, 9, 2612-2620. Link

Paper Accepted

03.21.22 – We have a new paper in Chem Catalysis!

“Discovery and mechanistic investigation of photoinduced sp³ C–H activation of hydrocarbons by the simple anion hexachlorotitanate” Panetti, G. B.; Yang, Q.; Gau, M. R.; Carrol, P. J.; Walsh, P. J.;  Schelter, E. J. Chem Catalysis 2022, 2, 1-14. Link

Paper Accepted

1.25.22 – We have a new paper in Chemical Science!

“Electronic structure studies reveal 4f/5d mixing and its effect on bonding characteristics in Ce-imido and -oxo complexes” Moreau, L. M.; Lapsheva, E.; Amaro-Estrada, J. I.; Gau, M. R.; Carroll, P. J.; Manor, B. C.; Qiao, Y.; Yang, Q.; Lukens, W. W.; Sokaras, D.; Schelter, E. J.; Maron, L.; Booth, C. H. Chem. Sci. 2022, In Press. Link

Paper Accepted

12.20.21 – We have a new paper in Inorganic Chemistry!

“Selective Reduction of Niobium(V) Species to Promote Molecular Niobium/Tantalum Separation” Furigay, M. H.; Chaudhuri, S.; Deresh, S. M.; Weberg, A. B.; Pandey, P.; Carroll, P. J.; Schatz, G. C.;  Schelter, E. J. Inorg. Chem. 2022, 61, 23-27. Link

Paper Accepted

11.15.21 – We have a new paper in Journal of the American Chemical Society!

“A Metal-Free, Photocatalytic Method for Aerobic Alkane Iodonation” Hirscher, N. A.; Ohri, N.; Yang, Q.; Zhou, J.; Anna, J. M.; ; Schelter, E. J.; Goldberg, K. I. J. Am. Chem. Soc. 2021, 143, 19232-19267. Link

Paper Accepted

5.21.21 – We have a new paper in Science!

“Photocatalytic C–H activation and the subtle role of chlorine radical complexation in reactivity” Yang, Q.; Wang, Y.-H.; Qiao, Y.; Gau, M.; Carroll, P. J.; Walsh, P. J.; Schelter, E. J. Science 2021, 372, 847–852. Link

New Group Members

01.04.21 – We have two new group members in the lab. Welcome Brett Vincenzini and Christian Uruburo!

Paper Accepted

08.04.20 – We have a new paper in Inorganic Chemistry Frontiers!

“A Hydrolytically Stable Ce(IV) Complex of Glutarimide-dioxime” Yang, Q.; Qiao, Y.; McSkimming, A.; Moreau, L. M.; Cheisson, T.; Booth, C. H.; Lapsheva, E.; Carrol, P.J.; Schelter, E. J. Inorg. Chem. Front. 2020, Accepted. Link

Paper Accepted

08.25.20 – We have a new paper in ACS Sustainable Chemistry and Engineering!

“Understanding Molecular Factors That Determine Performance in the Rare Earth (TriNOx) Separations System” Cole, B.E, Cheisson, T.; Nelson, J. J. M.; Higgins, R. F.; Gau, M. R.; Carroll, P.J.; Schelter, E. J. ACS Sustainable Chem. Eng. 2020, 8, 14786. Link