Refereed Publications from the University of Pennsylvania

2022


167. “Tantalum, easy as Pi: understanding differences in metal-imido bonding towards improving Ta/Nb separations” Weberg, A. B.; Chaudhuri, S.; Cheisson, T.; Uruburo, C.; Lapsheva, E.; Pandey, P.; Gau, M. R.; Carroll, P. J.; Schatz, G. C.; Schelter, E. J. Chem. Sci. 2022, in press. Link

 

166. “Light-Mediated Aerobic Oxidation of C(sp3)−H Bonds by a Ce(IV) Hexachloride Complex” Wang, Y-H.; Yang, Q.; Walsh, P.; Schelter, E. J. Org. Chem. Front. 2022, 9, 2612-2620. Link

165. “Discovery and mechanistic investigation of photoinduced sp3 C–H activation of hydrocarbons by the simple anion hexachlorotitanate” Panetti, G. B.; Yang, Q.; Gau, M. R.; Carrol, P. J.; Walsh, P. J.;  Schelter, E. J. Chem Catalysis 20222, 853-866. Link

 

164. “Electronic structure studies reveal 4f/5d mixing and its effect on bonding characteristics in Ce-imido and -oxo complexes” Moreau, L. M.; Lapsheva, E.; Amaro-Estrada, J. I.; Gau, M. R.; Carroll, P. J.; Manor, B. C.; Qiao, Y.; Yang, Q.; Lukens, W. W.; Sokaras, D.; Schelter, E. J.; Maron, L.; Booth, C. H. Chem. Sci. 2022, 13, 1759-1773. Link

163. “Selective Reduction of Niobium(V) Species to Promote Molecular Niobium/Tantalum Separation” Furigay, M. H.; Chaudhuri, S.; Deresh, S. M.; Weberg, A. B.; Pandey, P.; Carroll, P. J.; Schatz, G. C.;  Schelter, E. J. Inorg. Chem. 202261, 23-27. Link

 

2021


162. “A Metal-Free, Photocatalytic Method for Aerobic Alkane Iodination” Hirscher, N. A.; Ohri, N.; Yang, Q.; Zhou, J.; Anna, J. M.; Schelter, E. J.; Goldberg, E. I. J. Am. Chem. Soc. 2021, 143, 19262-19267. Link

161. “Photocatalytic CH Activation and the Subtle Role of Chlorine Radical Complexation in Reactivity” Schelter, E.  J.;, Walsh, P. J.; Yang, Q.; Wang, Y.-H.; Qiao, Y. Synthesis 2021, 53, A166-A169. Link

160. “Using Redox-Active Ligands to Generate Actinide Ligand Radical Species” Galley, S. S.; Pattenaude, S. A.; Ray, D.; Gaggioli, C. A.; Whitefoot, M. A.; Qiao, Y.; Higgins, R. F.; Nelson, W. L.; Baumbach, R.; Sperling, J. M.; Zeller, M.; Collins, T. A.; Schelter, E. J.; Gagliardi, L.; Albrecht-Schönzart, T. E.; Bart, S. C. Inorg. Chem. 2021, 60, 15242–15252. Link

159. “Elucidation of Thorium Redox-Active Ligand Complexes: Evidence for a Thorium-Tri(radical) Species” Rupasinghe, D. M. R. Y. P.; Gupta, H.; Baxter, M. R.; Higgins, R. F.; Zeller, M.; Schelter, E. J.; Bart, S. C. Inorg. Chem. 2021, 60, 14302–14309. Link

158. “Complexation and redox chemistry of neptunium, plutonium and americium with a hydroxylaminato ligand” Su, J.; Cheisson, T.; McSkimming, A.; Goodwin, C. A. P.; DiMucci, I. M.; Albrech-Schönzart, T.; Scott, B. L.; Batista, E. R.; Gaunt, A. J.; Kozimor, S. A.; Yang, P.; Schelter, E. J. Chem. Sci. 2021, 12, 13343-13359. Link

157. “Photocatalytic C–H activation and the subtle role of chlorine radical complexation in reactivity” Yang, Q.; Wang, Y.-H.; Qiao, Y.; Gau, M.; Carroll, P. J.; Walsh, P. J.; Schelter, E. J. Science 2021, 372, 847–852. Link

 

156. “Expanding the Rare-Earth Metal BINOLate Catalytic Multitool beyond Enantioselective Organic Synthesis” Panetti, G. B.; Robinson, J. R.; Schelter, E. J.; Walsh, P. Acc. Chem. Res. 2021, 54, 2637–2648Link

155. “Isolation and characterization of a covalent CeIV-Aryl complex with an anomalous 13C chemical shift” Panetti, G. B.; Sergentu, D.-C.; Gau, M. R.; Carroll, P. J.; Autschbach, J.; Walsh, P. J.;  Schelter, E. J. Nat. Commun. 2021, 12, 1713. Link

 

154. Knasin, A. and Schelter, E. J. Synthetic modeling of the structure and function of the rare-earth dependent methanol dehydrogenase cofactor. In Methods in Enzymology. Joseph A. Cotruvo Jr., Ed.; Academic Press (Elsevier): Cambridge, MA, 2021; pp 19-55.

153. “Synthesis of an elusive, stable 2-azaallyl radical guided by electrochemical and reactivity studies of 2-azaallyl anions” Panetti, G. B.; Carrol, P. J.; Gau, M. R.; Manor, B. C.; Schelter, E. J.; Walsh, P. Chem. Sci. 202121, 4405-4410. Link

152. “Cerium(IV) Complexes with Guanidinate Ligands: Intense Colors and Anomalous Electronic Structures” Qiao, Y.; Yin, H.; Moreau, L. M.; Feng, R.; Higgins, R. F.; Manor, B. C.; Carroll, P. J.; Booth, C. H.; Autschbach, J.;  Schelter, E. J. Chem. Sci., 2021,12, 3558-3567. Link

 

2020


151. “A Hydrolytically Stable Ce(IV) Complex of Glutarimide-dioxime” Yang, Q.; Qiao, Y.; McSkimming, A.; Moreau, L. M.; Cheisson, T.; Booth, C. H.; Lapsheva, E.; Carroll, P.J.; Schelter, E. J. Inorg. Chem. Front. 2020, 8, 934 – 939. Link

150. “Understanding Molecular Factors That Determine Performance in the Rare Earth (TriNOx) Separations System” Cole, B.E, Cheisson, T.; Nelson, J. J. M.; Higgins, R. F.; Gau, M. R.; Carroll, P.J.; Schelter, E. J. ACS Sustainable Chem. Eng. 20208, 14786. Link

 

149. “Proton affinities of pertechnetate (TcO4) andvperrhenate (ReO4)” Jian, J.; Barathan, E.; Cheisson, T.; Jian, T.; Lukens, W. W.; Davis, R. L.; Schelter, E. J.; Schreckenbach, G.; Gibson, J. K. Chem. Phys. Phys. Chem. 202022, 12403-10411. Link

148. “Reactivity of Ce(IV) Imido Compounds with Heteroallenes” Lapsheva, E.; Cheisson, T.; Lamsfus, C. A.; Carroll, P. J.; Gau, M. R.; Maron, L.; Schelter, E. J. Chem. Commun. 2020, 54, 4781. Link

147. “Correlating Mechanical Sensitivity with Spin Transition in the Explosive Spin Crossover Complex [Fe(Htrz)3]n[ClO4]2n” Nguyen, T.-A. D.; Veauthier, J. M.; Angles-Tamayo, G. F.; Chavez, D. E.; Lapsheva, E.; Myers, T. W.; Nelson, T. R.; Schelter, E. J.; Bertke, J. A. J. Am. Chem. Soc. 2020142, 4842-4851. Link

146. “Mononuclear to Polynuclear U(IV) Structural Units: Effects of Reaction Conditions on U-Furoate Phase Formation” Knope, K. E.; Vanagas, N. A.; Higgins, R. F.; Wacker, J. N.; Asuigui, D. R. C.; Warzecha, E.; Kozimor, S. A.; Stoll, S. L.; Schelter, E. J.; Bertke, J. A. Chem. Eur. J. 202026, 5872-5886. Link

 

145. “High-throughput screening for discovery of benchtop separations systems for selected rare earth elements” Nelson, J. J. M.; Cheisson, T.; Rugh, H. J.; Gau, M. R.; Carroll, P. J.; Schelter, E. J. Commun. Chem. 20203, 7. Link

 

2019


144. “Screening of molecular lanthanide corrosion inhibitors by a high-throughput method” Zabula, A. V.; Dey, S.; Robinson, J. R.; Cheisson, T.; Higgins, R. F.; Bhargava, G.; Nahas, R. C.; Cinoman, D.; Kerins Jr., M.; Schelter, E. J. Corros. Sci. 2019165, 108377. Link

143. “Magnetic Field Directed Rare-Earth Separations” Higgins, R. F.; Cheisson, T.; Cole, B. E.; Manor, B. C.; Carroll, P. J.; Schelter, E. J. Angew. Chem. Int. Ed. 202059, 1851-1856. Link

 

142. “Halide anion discrimination by a tripodal hydroxylamine ligand in gas and condensed phases” Cheisson, T.; Jian, J.; Eaton, T. M.; Gau, M. R.; Carroll, P. J.; Batista, E. R.; Yang, P.; Gibson, J. K.; Schelter, E. J. Phys. Chem. Chem. Phys. 201921, 19868-19878. Link

141. “Redox-Driven Chelation and Kinetic Separation of Select Rare Earths Using a Tripodal Nitroxide Proligand” Cole, B. E.; Cheisson, T.; Higgins, R. F.; Nakamaru-Ogiso, E.; Manor, B. C.; Carroll, P. J.; Schelter, E. J. Inorg. Chem. 2020, 59, 172-178. Link

 

140. “Multiple Bonding in Lanthanides and Actinides: Direct Comparison of Covalency in Thorium(IV)- and Cerium(IV)-Imido Complexes” Cheisson, T.; Kersey, K. D.; Mahieu, N.; McSkimming, A.; Gau, M. R.; Carroll, P. J.; Schelter, E. J. J. Am. Chem. Soc. 2019141, 9185-9190. Link

139. “A reduction series of neodymium supported by pyridine(diimine) ligands” Galley, S. S.; Pattenaude, S. A.; Higgins, R. F.; Tatebe, C. J.; Stanley, D. A.; Fanwick, P. E.; Zeller, M.; Schelter, E. J.; Bart, S. C. Dalton Trans. 201948, 8021-8025. Link

138. An investigation of the binding of (S)-monothioBINOLate to rare earth metal cations” Panetti, G. B.; Varela, E. J.; Gau, M. R.; Schelter, E. J.; Walsh, P. J. Phosphorus, Sulfur, and Silicon and the Related Elements 2019, https://doi.org/10.1080/10426507.2019.1602773. Link

 

137. “A strategy to improve the performance of cerium(III) photocatalysts” Qiao, Y.; Cheisson, T.; Manor, B. C.; Carroll, P. J.; Schelter, E. J. Chem. Comm. 201955, 4067-4070. Link

136. “13C NMR Shifts as an Indicator of U-C Bond Covalency in Uranium(VI) Acetylide Complexes: An Experimental and Computational Study” Mullane, K. C.; Hrobárik, P.; Cheisson, T.; Manor, B. C.; Carroll, P. J.; Schelter, E. J. Inorg. Chem. 201958, 4152-4163. Link

 

135. “Synthesis and Characterization of Tris-chelate Complexes for Understanding f-Orbital Bonding in Later Actinides” Galley, S. S.; Pattenaude, S. A.; Gaggioli, C. A.; Qiao, Y.; Sperling, J. M.; Zeller, M.; Pakhira, S.; Mendoza-Cortes, J. L.; Schelter, E. J.; Albrecht-Schmitt, T. E.; Gagliardi, L.; Bart, S. C. J. Am. Chem. Soc. 2019141, 2356-2366. Link

134. “Rare earth elements: Mendeleev’s bane, modern marvels” Cheisson, T.; Schelter, E. J. Science 2019, 363, 489-493. Link

133. “Phosphoryl-Ligand Adducts of Rare Earth-TriNOx Complexes: Systematic Studies and Implications for Separations Chemistry” Cheisson, T.; Cole, B. E.; Manor, B. C.; Carroll, P. J.; Schelter, E. J. ACS Sustainable Chem. Eng. 20197, 4993-5001. Link

 

132. “Sustainable Inorganic Chemistry: Metal Separations for Recycling” Nelson, J. M.; Schelter, E. J. Inorg. Chem. 201958, 979-990. Link

2018


131. “Uranyl functionalization mediated by redox-active ligands: generation of O-C bonds via acylation” Coughlin, E. J.; Qiao, Y.; Lapsheva, E.; Zeller, M.; Schelter, E. J.; Bart, S. C. J. Am. Chem. Soc. 2019141, 1016-1026. Link

130. “Lanthanide photocatalysis” Qiao, Y.; Schelter, E. J. Acc. Chem. Res. 201851, 2926-2936. Link

 

129. “Frontiers in coordination chemistry and its applications” Shatruk, M.; Schelter, E. J.; Mindiola, D. J. Dalton Trans. 201847, 11736-11738. Link

*Organized in honor of Prof. Kim R. Dunbar on the occasion of her 60th birthday.

128. “Silyl Transfer Pathway to a Ce(IV) Imido Complex” Cheisson, T.; Solola, L. A.; Gau, M. R.; Carroll, P. J.; Schelter, E. J. Organometallics 201837, 4332-4335. Link 

*Selected for ACS Editors’ Choice.

127. “Exploration of the Solid- and Solution-State Structures and Electrochemical Properties of CeIV(atrane) Complexes” Solola, L. A.; Cheisson, T.; Yang, Q.; Carroll, P. J.; Schelter, E. J. Inorg. Chem. 201857, 10543-10547. Link

 

126. “Synthesis of novel copper-rare earth BINOLate frameworks from a hydrogen bonding DBU-H rare earth BINOLate complex” Panetti, G. B.; Robinson, J. R.; Carrol, P. J.; Gau, M. R.; Manor, B. C.; Walsh, P. J.; Schelter, E. J. Dalton Trans. 2018, 47, 14408-14410. Link

    *Invited Article as part of the themed collection: in celebration of Richard Andersen’s 75th birthday.

 

125. “A Molecular Basis to Rare Earth Separations for Recycling: Tuning TriNOx Ligand Properties for Improved Performance” Cole, B. E.; Falcones, I. B.; Cheisson, T.; Manor, B. C.; Carroll, P. J.; Schelter, E. J. Chem. Comm. 201854, 10276-10279. Link

 

124. “C-H Bond Addition Across a Transient Uranium Nitrido and Formation of a Parent Uranium Imido Complex” Mullane, K. C.; Ryu, H.; Cheisson, T.; Grant, L. N.; Park, J. Y.; Manor, B. C.; Carroll, P. J.; Baik, M.-H.; Mindiola, D. J.; Schelter, E. J. J. Am. Chem. Soc. 2018140, 11335-11340. Link

123. “Redox-enhanced hemilability of the tris(tert-butoxy)siloxy ligand at cerium” Friedrich, J.; Qiao, Y.; Maichle-moessmer, C.; Schelter, E. J.; Anwander, R. Dalton Trans. 201847, 10113-10123. Link

122. “Solution and Solid State Structural Chemistry of Th(IV) and U(IV) 4-hydroxybenzoates” Vanagas, N. A.; Wacker, J. N.; Rom, C. L.; Glass, E. N.; Colliard, I.; Qiao, Y.; Bertke, J. A.; Van Keuren, E.; Schelter, E. J.; Nyman, M.; Knope, K. E. Inorg. Chem. 201857, 7259-7269. Link

121. “Photoinduced Miyaura Borylation by a Rare Earth Photoreductant: the Hexachlorocerate(III) Anion” Qiao, Y.; Yang, Q.; Schelter, E. J. Angew. Chem. Int. Ed. 201857, 10999-11003. Link

 

120. “Redox-Active vs Redox-Innocent: A Comparison of Uranium Complexes Containing Diamine Ligands” Pattenaude, S. A.; Mullane, K. C.; Schelter, E. J.; Ferrier, M. G.; Stein, B. W.; Bone, S. E.; Lezama Pacheco, J. S.; Kozimor, S. A.; Fanwick, P. E.; Zeller, M.; Bart, S. C. Inorg. Chem. 201857, 6530-6539. Link

  1. “Coordination Chemistry of a Strongly-Donating Hydroxylamine with Early Actinides: An Investigation of Redox Properties and Electronic Structure” McSkimming, A.; Su, J.; Cheisson, T.; Gau, M. R.; Carroll, P. J.; Batista, E. R.; Yang, P.; Schelter, E. J. Inorg. Chem. 2018140, 4588-4595. Link

118. “Understanding and Controlling the Emission Brightness and Color of Molecular Cerium Luminophores” Qiao, Y.; Sergentu, D.-C.; Yin, H.; Zabula, A. V.; Cheisson, T.; McSkimming, A.; Carroll, P. J.; Anna, J. M.; Autschbach, J.; Schelter, E. J. J. Am. Chem. Soc. 2018, 140, 4588-4595. Link

 

  1. “Functional Synthetic Model for the Lanthanide-Dependent Quinoid Alcohol Dehydrogenase Active Site” McSkimming, A.; Cheisson, T.; Carroll, P. J.; Schelter, E. J. J. Am. Chem. Soc. 2018140, 1223-1226. Link
  1. “Cationic cerium(IV) complexes with multiple open coordination sites” Solola, L. A.; Carroll, P. J.; Schelter, E. J. J. Organomet. Chem. 2017, In Press Link

2017


  1. “The Vibrancy and Variety of Modern f-Element Organometallic Chemistry” Bart, S. C.; Schelter, E. J. Organometallics 201736, 4507-4510. Link
  1. “Reduction of Carbonyl Groups by Uranium(III) and Formation of a Stable Amide Radical Anion” Mullane, K. C.; Cheisson, T.; Nakamaru-Ogiso, E.; Manor, B. C.; Carroll, P. J.; Schelter, E. J.Chem. Eur. J. 2017AcceptedLink
  1. “Structure, Electronics and Reactivity of Ce(PNP) Complexes” Zabula, A. V.; Qiao, Y.; Kosanovich, A. J.; Cheisson; T.; Manor, B. C.; Carroll, P. J.; Ozerov, O. V.; Schelter, E. J. Chem. Eur. J. 2017, 23, 5748-5757. Link
  1. “Electro-kinetic Separation of Rare Earth Elements Using a Redox Active Ligand” Fang, H.; Cole, B. E.; Qiao, Y.; Bogart, J. A.; Cheisson, T.; Manor, B. C.; Carroll, P. J.; Schelter, E. J. Angew. Chem. Int. Ed. 2017, AcceptedLink
  1. “A 1,2-Addition Pathway for C(sp2)-H Activation at a Dinickel Imide” Powers, I. G.; Kiattisewee, C.; Mullane, K. C.; Schelter, E. J.; Uyeda, C. Chem. Eur. J. 2017, 56, 4852-4863. Link
  2. “Tuning the Fe(II/III) Redox Potential in Nonheme Fe(II)–Hydroxo Complexes through Primary and Secondary Coordination Sphere Modifications” Gordon, Z.; Drummond, M. J.; Matson, E. M.; Bogart, J. A.; Schelter, E. J.; Lord, R. L.; Fout, A. R.  Inorg. Chem. 2017, 56, 4852-4863. Link
  1. “Synthesis and Reduction of Uranium(V) Imido Complexes with Redox Active Substituents” Mullane, K. C.; Carroll, P. J.; Schelter, E. J. Chem. Eur. J. 2017, 23, 5748-5757. Link
  1. “Cerium(IV) Imido Complexes: Structural, Computational and Reactivity Studies” Solola, L. A.; Zabula, A. V.; Dorfner, W. L.; Manor, B. C.; Carroll, P. J.; Schelter, E. J. J. Am. Chem. Soc. 2017, 139, 2435-2442. Link

2016


  1. “Accomplishing simple, solubility-based separations of rare earth elements with complexes bearing size-sensitive molecular apertures” Bogart, J. A.; Cole, B. E.; Boreen, M. A.; Lippincott, C. A.; Manor, B. C.; Carroll, P. J. Schelter, E. J. Proc. Natl. Acad. Sci. U. S. A. 2016, 113, 14887-14892. Link
  1. “Density Functional Theory as a Predictive Tool for Cerium Redox Properties in Nonaqueous Solvents” Levin, J. R.; Dorfner, W. L.; Dai, A. X.; Carroll, P. J.; Schelter, E. J. Inorg. Chem. 2016, 55, 12651-12659. Link
  1. “The Hexachlorocerate(III) Anion: A Potent, Benchtop Stable and Readily Available UVA Photosensitizer for Aryl Chlorides” Yin, H.; Jin, Y.; Hertzog, J. E.; Mullane, K. C.; Carroll, P. J.; Manor, B. C.; Anna, J. M.; Schelter, E. J. J. Am. Chem. Soc. 2016, 138, 16266-16273. Link
  1. “Not Just Lewis Acids: Preface for the Forum on New Trends and Applications for Lanthanides” Murugesu, M.; Schelter, E. J.; Inorg. Chem. 2016, 55, 9951-9953. Link
  1. “Accessing relatively electron poor cerium(IV) hydrazido complexes by lithium cation promoted ligand reduction” Levin, J. R.; Cheisson, T.; Carroll, P. J.; Schelter, E. J. Dalton Trans. 2016, 45, 15249-15258. Link
  1. “Reactions of A Cerium(III) Amide with Heteroallenes: Insertion, Silyl-migration and De-insertion” Yin, H.; Carroll, P. J.; Schelter, E. J. Chem. Comm. 2016, 52, 9813-9816. Link
  1. “1,2-Addition or Enolization? Variable Reactivity of a Cerium Acetylide Complex toward Carbonyl Compounds” Kim, J. E.; Zabula, A. V.; Carroll, P. J.; Schelter, E. J. Organometallics 2016, 35, 2086-2091. Link
  1. “Cerium(III) and Uranium(IV) Complexes of the 2-Fluorophenyl Trimethylsilyl Amide Ligand: C‐F–>Ln/An Interactions that Modulate the Coordination Spheres of f-Block Elements” Yin, H.; Carroll, P. J.; Schelter, E. J. Inorg. Chem. 2016, 55, 5684-5692. Link
  1. “An Alkali Metal-Capped Cerium(IV) Imido Complex” Solola, L. A.; Zabula, A. V.; Dorfner, W. L.; Manor, B. C.; Carroll, P. J.; Schelter, E. J. J. Am. Chem. Soc. 2016, 138, 6928-6931. Link
  1. “Cerium Photosensitizers: Structure-Function Relationships and Applications in Photocatalytic Aryl Coupling Reactions” Yin, H.; Carroll, P. J.; Manor, B. C.; Anna, J. M.; Schelter, E. J. J. Am. Chem. Soc. 2016, 138, 5984-5993. Link
  1. “The Role of Dynamic Ligand Exchange in the Oxidation Chemistry of Cerium(III)” Robinson, J. R.; Qiao, Y.; Gu, J.; Carroll, P. J.; Schelter, E. J. Chem. Sci. 2016, 7, 4537-4547. Link
  1. “C-F–>Ln/An Interactions in Synthetic f-Element Chemistry” Yin, H.; Zabula, A. V.; Schelter, E. J. Dalton Trans. 2016, 45, 6313‐6323. Link
  1. “Rare Earth Metal Complexes of Bidentate Nitroxide Ligands: Synthesis and Electrochemistry; Kim, J. E.; Bogart, J. A.; Carroll, P. J.; Schelter, E. J. Inorg. Chem. 2016, 55, 775‐784. Link
  1. “Synthesis and Characterization of Aluminum Nitroxide Complexes” Herb, T. M.; Poitras, A. M.; Richardson, K. G.; Cole, B. E.; Bogart, J. A.; Carroll, P. J.; Schelter, E. J.; Graves, C. R. Polyhedron 2016, 114, 194-199. Link

2015


  1. “Spontaneous Partitioning of Californium from Curium: Curious Cases from the Crystallization of Curium Coordination Complexes” Cary, S. K.; Silver, M. A.; Liu, G.; Wang, J. C.; Bogart, J. A.; Stritzinger, J. T.; Arico, A. A.; Hanson, K.; Schelter, E. J.; Albrecht-Schmitt, T. E. Inorg. Chem. 2015, 54, 11399-11404. Link
  2. “Synthesis and Characterization of Redox-Active Aluminum-Pyridyl Nitroxide Complexes” Poitras, A.; Bogart, J. A.; Cole, B.; Carroll, P. J.; Schelter, E. J.; Graves, C. R. Inorg. Chem. 2015, 54, 10901-10908. Link
  1. “Controlled Redox Chemistry at Cerium within a Tripodal Nitroxide Ligand Framework” Bogart, J. A.; Lippincott, C. A.; Carroll, P. J.; Booth, C. H.; Schelter, E. J. Chem. Eur. J. 2015, 21, 17850‐17859. Link
  1. “Rearrangement in a Tripodal Nitroxide Ligand To Modulate the Reactivity of a Ti-F Bond” Boreen, M. A.; Bogart, J. A.; Carroll, P. J.; Schelter, E. J. Inorg. Chem. 2015, 54, 9588‐9593. Link
  1. “Bidentate Nitroxide Ligands Stable Toward Oxidative Redox Cycling and their Complexes with Cerium and Lanthanum” Kim, J. E.; Carroll, P. J.; Schelter, E. J. Chem. Comm. 2015, 51, 15047‐15050. Link
  1. “Control of Cerium Oxidation State through Metal Complex Secondary Structures” Levin, J. R.; Dorfner, W. L.; Carroll, P. J.; Schelter, E. J. Chem. Sci. 2015, 6, 6925‐6934. Link
  1. “Luminescent Ce(III) Complexes as Stoichiometric and Catalytic Photo-reductants for Halogen Atom Abstraction Reactions” Yin, H.; Carroll, P. J.; Anna, J. M.; Schelter, E. J. J. Am. Chem. Soc. 2015, 137, 9234-9237. Link
  1. “Investigation of Uranium Tris(imido) Complexes: Synthesis, Characterization, and Reduction Chemistry of [U(NDIPP)3(thf)3]” Anderson, N. H.; Yin, H.; Kiernicki, J. J.; Fanwick, P. E.; Schelter, E. J.; Bart, S. C. Angew. Chem. Int. Ed. 2015, 54, 9386-9389. Link
  2. “Spectroscopic and Structural Elucidation of Uranium Dioxophenoxazine Complexes” Pattenaude, S. A.; Kuehner, C. S.; Dorfner, W. L.; Schelter, E. J.; Fanwick, P. E.; Bart, S. C. Inorg. Chem. 2015, 54, 6520-6527. Link
  1. “An Operationally Simple Method for Separating the Rare-Earth Elements Neodymium and Dysprosium” Bogart, J. A.; Lippincott, C. A.; Carroll, P. J.; Schelter, E. J. Angew. Chem. Int. Ed. 2015, 54, 8222-8225. Link
  1. “Structural Variation in Cerium Aryloxide Complexes Templated by Hemilabile K+-Amine Interactions” Kim, J. E.; Carroll, P. J.; Schelter, E. J. New J. Chem. 2015, 39, 6076-6084. Link
  1. “Exchange Processes in Shibasaki’s Rare Earth Alkali Metal BINOLate (REMB) Frameworks and their Relevance in Multifunctional Asymmetric Catalysis” Robinson, J. R.; Gu, J.; Carroll, P. J.; Schelter, E. J.; Walsh, P. J. J. Am. Chem. Soc. 2015, 7135-7144. Link
  1. “Why is Uranyl Formohydroxamate Red?” Silver, M. A.; Dorfner, W. L.; Cary, S. K.; Cross, J. N.; Lin, J.; Schelter, E. J.; Albrecht-Schmitt, T. E. Inorg. Chem. 2015, 54, 5280-5284. *Selected for ACS Editors’ Choice Link
  1. “Investigation of the Electronic Ground States for a Reduced Pyridine(diimine) Uranium Series: Evidence for a Ligand Tetraanion Stabilized by a Uranium Dimer” Anderson, N. A.; Odoh, S. O.; Williams, U. J.; Lewis, A. J.; Wagner, G. L.; Pacheco, J. L.; Kozimor, S. A.; Gagliardi, L.; Schelter, E. J.; Bart, S. C. J. Am. Chem. Soc. 2015, 137, 4690-4700. Link
  1. “Substituted Quinoline Quinones as Surrogates for the PQQ Cofactor: An Electrochemical and Computational Study§” Dorfner, W. L.; Carroll, P. J.; Schelter, E. J. Org. Lett. 2015, 17, 1850-1853. Link
  1. “A Ligand Field Series for the 4f-Block from Experimental and DFT Computed Ce(IV/III) Electrochemical Potentials” Bogart, J. A.; Lewis, A. J.; Boreen, M. A.; Lee, H. B.; Medling, S. A.; Carroll, P. J.; Booth, C. H.; Schelter, E. J. Inorg. Chem. 2015, 54, 2830-2837. Link

2014


  1. “DFT Study of the Active Site of the XoxF-type Natural, Cerium-Dependent Methanol Dehydrogenase Enzyme” Bogart, J. A.; Lewis, A. J.; Schelter, E. J.Chem. Eur. J. 2014, 21, 1743-1748. Link
  1. “Synthesis, Structural Characterization, and Carbonyl Addition Reactivity of a Terminal Cerium(III) Acetylide Complex” Kim, J. E.; Weinberger, D. S.; Carroll, P. J.; Schelter, E. J.Organometallics 2014, 33, 5948-5951. Link
  1. “Stabilization of MIV = Ti, Zr, Hf, Ce, and Th using a selenium bis(phenolate) ligand” Behrle, A. C.; Levin, J. R.; Kim, J. E.; Drewett, J. M.; Barnes, C. L.; Schelter, E. J.; Walensky, J. R. Dalton Trans. 2014, 44, 2693-2702. Link
  2. “A New Class of Organocatalysts: Sulfenate Anions” Zhang, M.; Jia, T.; Yin, H.; Carroll, P. J.; Schelter, E. J.; Walsh, P. J. Angew. Chem. Int. Ed. 2014, 53, 10755-10758. Link
  1. “Anomalous One-Electron Processes in the Chemistry of Uranium Nitrogen Multiple Bonds” Mullane, K. C.; Lewis, A. J.; Yin, H.; Carroll, P. J.; Schelter, E. J. Inorg. Chem. 2014, 53, 9129-9139. Link
  1. “Variation of Electronic Transitions and Reduction Potentials of Cerium(IV) Complexes” Williams, U. J.; Schneider, D.; Dorfner, W. L.; Maichle-Moessmer, C.; Carroll, P. J.; Anwander, R.; Schelter, E. J. Dalton Trans. 2014, 43, 16197-16206. Link
  1. “Harnessing redox activity for the formation of uranium tris(imido) compounds” Anderson, N. H.; Odoh, S. O.; Yao, Y.; Williams, U. J.; Schaefer, B. A.; Kiernicki, J. J.; Lewis, A. J.; Goshert, M. D.; Fanwick, P. E.; Schelter, E. J.; Walensky, J. R.; Gagliardi, L.; Bart, S. C. Nat. Chem. 2014, 6, 919-926. Link
  1. “The Inverse Trans Influence in a Family of Pentavalent Uranium Complexes” Lewis, A. J.; Mullane, K. C.; Nakamaru-Ogiso, E.; Carroll, P. J.; Schelter, E. J. Inorg. Chem. 2014, 53, 6944-6953. Link
  1. “Synthesis and Analysis of a Family of Cerium(IV) Halide and Pseudohalide Compounds” Williams, U. J.; Carroll, P. J.; Schelter, E. J. Inorg. Chem. 2014, 53, 6338-6345. Link
  1. “Uranyl-Oxo Coordination Directed by Non-Covalent Interactions” Lewis, A. J.; Yin, H. L.; Carroll, P. J.; Schelter, E. J. Dalton Trans.2014, 43, 10844-10851. Link
  1. “Air- and Water-Tolerant Rare Earth Guanidinium BINOLate Complexes as Practical Precatalysts in Multifunctional Asymmetric Catalysis” Robinson, J. R.; Fan, X.; Yadav, J.; Carroll, P. J.; Wooten, A. J.; Pericàs, M. A.; Schelter, E. J.; Walsh, P. J. J. Am. Chem. Soc. 2014, 136, 8034-8041. Link
  1. “Asymmetric Allylation of Ketones and Subsequent Tandem Reactions Catalyzed by a Novel Polymer-Supported Titanium-BINOLate Complex” Yadav, J.; Stanton, G. R.; Fan, X.; Robinson, J. R.; Schelter, E. J.; Walsh, P. J.; Pericàs, M. A. Chem. Eur. J. 2014, 20, 7122-7127. Link
  2. “NiXantphos: A Deprotonatable Ligand for Room Temperature Palladium-Catalyzed Cross-Couplings of Aryl Chlorides” Zhang, J.; Bellomo, A.; Trongsiriwat, N.; Jia, T.; Carroll, P. J.; Dreher, S. D.; Tudge, M. T.; Yin, H.; Robinson, J. R.; Schelter, E. J.; Walsh, P. J. J. Am. Chem. Soc. 2014, 136, 6276-6287. Link
  1. “Non-Covalent Immobilization of Rare Earth Heterobimetallic Frameworks and their Reactivity in an Asymmetric Michael Addition” Robinson, J. R.; Yadav, J.; Fan, X.; Stanton, G. R.; Schelter, E. J.; Pericàs, M. A.; Walsh, P. J. Adv. Synth. Cat. 2014, 356, 1243-1254. Link Cover art
  1. “A Homoleptic η2 Hydroxylaminato CeIV Complex with S4Symmetry” Dorfner, W. L.; Carroll, P. J.; Schelter, E. J. Dalton Trans. 2014, 43, 6300-6303. Link
  1. “κ2-coordination of 18-crown-6 to Ce(III) cations: Solution dynamics and reactivity” Yin, H.; Robinson, J. R.; Carroll, P. J.; Walsh, P. J.; Schelter, E. J. Chem. Commun. 2014, 50, 3470-3472. Link
  1. “Structural and magnetic conformation of a cerocene [Ce(COT′′)2] exhibiting a uniconfigurational f1 ground state and slow-magnetic relaxation” Le Roy, J. J.; Korobkov, I.; Kim, J. E.; Schelter, E. J.; Murugesu, M. Dalton Trans. 2014, 43, 2737-2740. Link
  1. “Synthesis, Bonding, and Reactivity of a Cerium(IV) Fluoride Complex” Williams, U. J.; Robinson, J. R.; Lewis, A. J.; Carroll, P. J.; Walsh, P. J.; Schelter, E. J. Inorg. Chem. 2014, 53, 27-29. Link

2013


  1. “Synthesis and Catalytic Activity of Heterobimetallic Rare Earth-Zinc Ethyl BINOLate Analogues of Shibasaki’s Catalysts” Nieto, I.; Wooten, A. J.; Robinson, J. R.; Carroll, P. J.; Schelter, E. J.; Walsh, P. J. Organometallics 2013, 32, 7431-7439. Link
  1. “Tuning Reactivity and Electronic Properties through Ligand Reorganization within a Cerium Heterobimetallic Framework” Robinson, J. R.; Gordon, Z.; Booth, C. H.; Carroll, P. J.; Walsh, P. J.; Schelter, E. J. J. Am. Chem. Soc. 2013, 135, 19016-19024. Link
  1. “Synthesis and Characterization of a Cerium(IV) Hydroxamate Complex: Implications for the Beneficiation of Light Rare Earth Ores” Lee, H. B.; Bogart, J. A.; Carroll, P. J.; Schelter, E. J. Chem. Commun. 2014, 5361-5363. Link
  1. “Homoleptic Ce(III) and Ce(IV) Nitroxide Complexes: Significant Stabilization of the 4+ Oxidation State” Bogart, J. A.; Lewis, A. J.; Medling, S. A.; Piro, N. A.; Carroll, P. J.; Booth, C. H. Schelter, E. J. Inorg. Chem. 2013, 52, 11600-11607. Link
  1. “The Electrochemical Behavior of Cerium(III/IV) Complexes: Thermodynamics, Kinetics and Applications in Synthesis” Piro, N. A.; Robinson, J. R.; Walsh, P. J.; Schelter, E. J. Coord. Chem. Rev. 2014, 260, 21-36. Link
  1. “Stable Uranium(VI) Methyl and Acetylide Complexes and the Elucidation of an Inverse Trans Influence Ligand Series” Lewis, A. J.; Carroll, P. J.; Schelter, E. J. J. Am. Chem. Soc. 2013, 135, 13185-13192. Link
  1. “Electrophilic Ln(III) Cations Protected by C-F→Ln Interactions and their Coordination Chemistry with Weak Sigma- and Pi-Donors” Yin, H.; Lewis, A. J.; Carroll, P. J.; Schelter, E. J. Inorg. Chem. 2013, 52, 8234-8243. Link
  1. “Tetrakis(bis(trimethylsilyl)amido)uranium(IV): Synthesis and Reactivity” Lewis, A. J.; Williams, U. J.; Carroll, P. J.; Schelter, E. J. Inorg. Chem. 2013, 52, 7326-7328. Link
  1. “Fine-tuning the Oxidative Ability of Persistent Radicals: Electrochemical and Computational Studies of Substituted 2-Pyridyl Hydroxylamines” Bogart, J. A.; Lee, H. B.; Boreen, M. A.; Jun, M.; Schelter, E. J. J. Org. Chem 2013, 78, 6344-6349. Link
  1. “Synthesis, Electrochemistry, and Reactivity of Cerium(III/IV) Methylene-Bis-Phenolate Complexes” Mahoney, B. D.; Piro, N. A.; Carroll, P. J.; Schelter, E. J. Inorg. Chem. 2013, 52, 5970-5977. Link
  1. “Single Crystal to Single Crystal Transformation and Hydrogen Atom Transfer upon Oxidation of a Cerium Coordination Compound” Williams, U. J.; Mahoney, B. D.; Lewis, A. J.; DeGregorio, P. T.; Carroll, P. J.; Schelter, E. J. Inorg. Chem. 2013, 52, 4142-4144. Link
  1. “Cerium under the lens” Schelter, E. J. Nat. Chem. 2013, 5, 348. Link
  1. “Dimeric Rare-Earth BINOLate Complexes: Activation of 1,4-Benzoquinone through Lewis Acid Promoted Potential Shifts” Robinson, J. R.; Booth, C. H.; Carroll, P. J.; Walsh, P. J.; Schelter, E. J. Chem. Eur. J. 2013, 19, 5996-6004. Link
  1. “Uranium(IV) BINOLate Heterobimetallics: Synthesis and Reactivity in an Asymmetric Diels-Alder Reaction” Robinson, J. R.; Carroll, P. J.; Walsh, P. J.; Schelter, E. J.Organometallics 2013, 32, 1493-1499. Link
  1. “Reductive Cleavage of Nitrite to form Terminal Uranium Mono-Oxo Complexes” Lewis, A. J.; Carroll, P. J.; Schelter, E. J. J. Am. Chem. Soc. 2013, 135, 511-518. Link
  1. “Fluorinated Diarylamides Complexes of Uranium(III, IV) Incorporating Ancillary Fluorine-to-Uranium Dative Interactions” Yin, H.; Lewis, A. J.; Williams, U. J.; Carroll, P. J.; Schelter, E. J. Chem. Sci. 2013, 4 798-805. Link

2012


  1. “The Impact of Ligand Reorganization on CeIII Oxidation Chemistry” Robinson, J. R.; Carroll, P. J.; Walsh, P. J.; Schelter, E. J. Angew. Chem. Int. Ed. 2012, 51, 10159-10163. Link
  1. “Electrochemistry of Kinetically Inert Cerium Aryloxide Complexes Supported by Inter-ligand Hydrogen Bonds” Levin, J. R. and Schelter, E. J. CIM Proceedings of the Annual Conference of Metallurgists, 2012, Accepted.
  1. “Lanthanide(III) 2-Naphthoxide Complexes Stabilized by Interligand Non-Covalent Interactions” Levin, J. R.; Gu, J.; Carroll, P. J.; Schelter, E. J. Dalton Trans. 2012, 41, 7870-7872. Link
  1. “A Comparison of the Effects of Symmetry and Magnetoanisotropy on Paramagnetic Relaxation in Related Dysprosium Single Ion Magnets” Williams, U. J.; Mahoney, B. D.; DeGregorio, P. T.; Carroll, P. J.; Nakamaru-Ogiso, E.; Kikkawa, J. M.; Schelter, E. J.Chem. Commun. 2012, 48, 5593-5595. Link
  1. “Pentavalent Uranium Trans-Dihalides and -Pseudohalides” Lewis, A. J.; Nakamaru-Ogiso, E.; Kikkawa, J. M.; Carroll, P. J.; Schelter, E. J.Chem. Commun., 2012, 48, 4977-4979. Link
  1. “Uranium Pyrrolylamine Complexes Featuring a Trigonal Binding Pocket and Interligand Noncovalent Interactions” Lewis, A. J.; Williams, U. J.; Kikkawa, J. M.; Carroll, P. J.; Schelter, E. J. Inorg. Chem. 2012, 51, 37-39. Link

2011


  1. “Synthesis, Characterization and Multi-Electron Reduction Chemistry of Uranium Supported by Redox-Active alpha-Diimine Ligands” Kraft, S. J.; Williams, U. J.; Daly, S. R.; Schelter, E. J.; Kozimor, S. A.; Boland, K. S.; Kikkawa, J. M.; Forrest, W. P.; Christensen, C. N.; Schwarz, D. E.; Fanwick, P. E.; Clark, D. L.; Conradson, S. D.; Bart, S. C. Inorg. Chem. 2011, 50, 9838-9848. Link
  2. “A General and Modular Synthesis of Monoimido Uranium(IV) Dihalides,” Jilek, R. E.; Spencer, L. P.; Kuiper, D. L.; Scott, B. L.; Williams, U. J.; Kikkawa, J. M.; Schelter, E. J.; Boncella, J. M. Inorg. Chem. 2011, 50, 4235-4237. Link