129. Bifunctional Ligands: Evaluating the Role of Acidic Protons in the Secondary Coordination Sphere

Anant Kumar Jain, Santanu Malakar, Austin T Cannon, Sophia Miranda M Gonzalez, Taylor M Keller, Patrick J Carroll, Michael R Gau, Jonathan L Kuo, and Karen I. Goldberg
Chemistry: A European Journal, 2024, e202304292.


128. Fast Outer-Sphere Electron Transfer and High Specific Capacitance at Covalently Modified Carbon Electrodes

Amy S. Metlay, Brandon Chyi, Colton J. Sheehan, Jeffrey R. Shallenberger, and Thomas E. Mallouk
Journal of the American Chemical Society, 2024, 146, in press.

127. Stabilizing Ti3C2Tx MXene Flakes in Air by Removing Confined Water

Hui Fang, Anupma Thakur, Amirhossein Zahmatkeshsaredorahi, Zhenyao Fang, Vahid Rad, Ahmad A. Shamsabadi, Claudia Pereyra, Masoud Soroush, Andrew M. Rappe, Xiaoji G. Xu, Babak Anasori, and Zahra Fakhraai
Proceedings of the National Academy of Sciences, 2024, 121, e2400084121.

126. Assembly of a Trapped Valent CeIII/IV–TCNQ Complex through Metal–ligand Redox Cooperativity

Himanshu Gupta, Brett D. Vincenzini, Alexandra M. Bacon, and Eric J. Schelter
Chemical Communications, 2024, 60, 6909-6912.

125. Hydrocarboxylation of C═C Bonds in Polycyclooctene: Progress Toward Valorization of Waste Polyolefins

Ikechukwu Martin Ogbu, Eli J. Fastow, Weihao Zhu, Lucille A. Wells, Roshni J. Chethalen, Vivek Nair, Zachary R. Hinton, Alex H. Balzer, Weiguo Hu, E. Bryan Coughlin, Karen I. Winey, and Marisa C. Kozlowski
Macromolecules, 2024, 57, 5860-5869.

124. Recent Developments in the Biosynthesis of Aziridines


Sabina J. Maurer, Joao Luiz Petrarca de Albuquerque, and Monica Erin McCallum
ChemBioChem, 2024, in press.

123. Vanadium Alkylidyne Initiated Cyclic Polymer Synthesis: The Importance of a Deprotiovanadacyclobutadiene Moiety

Mehrafshan G. Jafari, John B. Russell, Hanna Lee, Bimal Pudasaini, Digvijayee Pal, Zhihui Miao, Michael R. Gau, Patrick J. Carroll, Brent S. Sumerlin, Adam S. Veige, Mu-Hyun Baik, and Daniel J. Mindiola
Journal of the American Chemical Society, 2024, 146, 2997-3009.

122. Tunable Localized Charge Transfer Excitons in Nanoplatelet−2D Chalcogenide van der Waals Heterostructures

M. Rahaman, E. Marino, A.G. Joly, C.E. Stevens, S. Song, A. Alfieri, Z. Jiang, B.T. O’Callahan, D.J. Rosen, K. Jo, G. Kim, J.R. Hendrickson, P.Z. El-Khoury, C. Murray, and D. Jariwala
ACS Nano, 2024, 18, 15185-15193.

121. Discovery of Wurtzite Solid Solutions with Enhanced Piezoelectric Response using Machine Learning

Drew Behrendt, Sayan Banerjee, Jiahao Zhang, and Andrew M. Rappe
Physical Review Materials, 2024, 8, 055406.

120. Selective Covalent Basal Plane Modification as a Probe of Hydroxide Ion Conduction Pathways in Magnesium Aluminum Layered Double Hydroxides

Jarrett D. Dillenburger, Leanna Schulte, Mohammed Suleiman, Colton J. Sheehan, and Thomas E. Mallouk
Chemistry-Sustainability-Energy-Materials, 2024, in press.

119. Kubo-Anderson Theory of Polariton Line Shape

Clàudia Climent, Joseph E. Subotnik, and Abraham Nitzan
Physical Review A, 2024, 109, 052809.

118. Core/Shell-Like Localized Emission at Atomically Thin Semiconductor–Au Interface

Kiyoung Jo, Christopher E. Stevens, Bongjun Choi, Patrick Z. El-Khoury, Joshua R. Hendrickson, and Deep Jariwala
Nano Letters, 2024, 24, 4725-4723.

117. Realization of Organocerium-Based Fullerene Molecular Materials Showing Mott Insulator-Type Behavior

Pragati Pandey, Xiaoyu Wang, Himanshu Gupta, Patrick W. Smith, Ekaterina Lapsheva, Patrick J. Carroll, Alexandra M. Bacon, Corwin H. Booth, Stefan G. Minasian, Jochen Autschbach, Eva Zurek, and Eric J. Schelter
ACS Applied Materials & Interfaces, 2024, 16, 17857-17869.

116. Vanadacyclobuta-(2,3)-diene Rearrangement into a Vanadium Imido Monoazabutadieneallenyl Complex

John B. Russell, Sarah M. Smith, Michael R. Gau,and Daniel J. Mindiola
Polyhedron, 2024, 253, 116913.

115. Capillary Filling Dynamics of Polymer Melts in a Bicontinuous Nanoporous Scaffold

Weiwei Kong, Anastasia Neuman, Aria C. Zhang, Daeyeon Lee, Robert A. Riggleman, and Russell J. Composto
Journal of Chemical Physics, 2024, 160, 44904.

114. Thiol-ene Click Chemistry Incorporates Carboxylic Acid-terminated Alkane Pendants on Polycyclooctene to Tune Properties

Eli Fastow, Roshni John Chethalen, E. Bryan Coughlin, and Karen I. Winey
Giant, 2024, 17, 100231.

113. Metallacyclobuta-(2,3)-diene: A Bidentate Ligand for Stream-line Synthesis of First Row Transition Metal Catalysts for Cyclic Polymerization of Phenylacetylene

John B. Russell, Debabrata Konar, Taylor Keller, Michael R. Gau, Patrick J. Carroll, Joshua Telser, Daniel W. Lester, Adam S. Veige, Brent S. Sumerlin, and Daniel J. Mindiola
Angewandte Chemie International Edition, 2024, 63, e202318956.

112. Metal–Ligand Redox Cooperativity in Cerium Amine-/Amido-Phenolate-Type Complexes

Christian Uruburo, D. M. Ramitha Y. P. Rupasinghe, Himanshu Gupta, Rachael M. Knieser, Lauren M. Lopez, Maxwell H. Furigay, Robert F. Higgins, Pragati Pandey, Makayla R. Baxter, Patrick J. Carroll, Matthias Zeller, Suzanne C. Bart, and Eric J. Schelter
Inorganic Chemistry, 2024, 63, 9418–9426.

111. Revealing the Nature of Active Oxygen Species and Reaction Mechanism of Ethylene Epoxidation by Supported Ag/α-Al2O3 Catalysts

Tiancheng Pu, Adhika Setiawan, Alexandre C. Foucher, Mingyu Guo, Jih-Mirn Jehng, Minghui Zhu, Michael E. Ford, Eric A. Stach, Srinivas Rangarajan, and Israel E. Wachs
ACS Catalysis, 2024, 14, 406-217.


110. Two-Legged Molecular Walker and Curvature: Mechanochemical Ring Migration on Graphene

Sayan Banerjee, Nathaniel Hawthorne, James D. Batteas, and Andrew M. Rappe
The Journal of the American Chemical Society, 2023, 145, 26765-26773.

109. On the Circularly Polarized Luminescence of Individual Triplet Sublevels

Claudia Climent, Eric J. Schelter, David H. Waldeck, Sergei A. Vinograd, and Joseph E. Subotnik
The Journal of Chemical Physics, 2023, 159, 134304.

108. Large-Scaled and Solar-Reflective Kirigami-Based Building Envelopes for Shading and Occupants’ Thermal Comfort

Heesuk Jung, Miaomiao Hou, Byungsoo Kang, Zherui Wang, Hyojeong Choi, Hyeong Won Lee, Yongju Lee, Doh-Kwon Lee, Phillip Lee, Dorit Aviv, Hyeok Kim, and Shu Yang
Advanced Sustainable Systems, 2023, 7, 2300253.

107. Sulfonic-acid-based Lyotropic Bicontinuous Cubic Polymer Network for Molecular-size-selective Heterogeneous Catalysis

Keira E. Culley, Christopher Johnson and Douglas L. Gin
Chemical Communications, 2023, 59, 11105-11198.

106. Anion-Dependent Structure, Dehydration, and Hydroxide Ion Conductivity of Magnesium Aluminum Layered Double Hydroxides

Jarrett D. Dillenburger, Leanna Schulte, Pratibha Mahale, Mohammed Suleiman, and Thomas E. Mallouk
Chemistry of Materials, 2023, 35, 6437-6446.

105. Supported VPO Catalysts for Maleic Anhydride by Atomic Layer Deposition

Jian Chang, Raymond J. Gorte, and John M. Vohs
Catalysis Letters, 2023.

104. Lewis Acids and Electron-Withdrawing Ligands Accelerate CO Coordination to Dinuclear Cu(I) Compounds

Walter D. Johnsen, Mawuli Deegbey, David C. Grills, Dmitry E. Polyansky, Karen I. Goldberg, Elena Jakubikova, and Thomas E. Mallouk
Inorganic Chemistry, 2023, 62, 9146-9157.

103. A Practical Approach to Wave Function Propagation, Hopping Probabilities, and Time Steps in Surface Hopping Calculations

Tian Qiu, Clàudia Climent, and Joseph E. Subotnik
Journal of Chemical Theory and Computation, 2023, 19, 2744-2757.

102. Spin–Orbit versus Hyperfine Coupling-Mediated Intersystem Crossing in a Radical Pair

Sam R. May, Clàudia Climent, Zhen Tao, Sergei A. Vinogradov and Joseph E. Subotnik
Journal of Physical Chemistry A, 2023, 127, 3591–3597.

101. Surface Rearrangement and Sublimation Kinetics of Supported Gold Nanoparticle Catalysts

James P. Horwath, Colin Lehman-Chong, Aleksandra Vojvodic, and Eric A. Stach
ACS Nano, 2023, 17, 8098-8107.

100. Electrochemical Synthesis of Monodisperse PtCo Nanocrystals

Daniel J. Rosen, Duncan Zavanelli and Christopher B. Murray
Johnson Matthey Technology Review, 2023, 67, 349-356.

99. Relationship between the Surface Reconstruction of Nickel Phosphides and Their Activity toward the Hydrogen Evolution Reaction

Sayan Banerjee, Arvin Kakekhani, Robert B. Wexler, and Andrew M. Rappe
ACS Catalysis, 2023, 13, 4611-4621.

98. High-Throughput Computational Screening of Bioinspired Dual-Atom Alloys for CO2 Activation

Drew Behrendt, Sayan Banerjee, Cole Clark, and Andrew M. Rappe
Journal of the American Chemical Society, 2023, 145, 4730-4735.

97. Mechanochemical Molecular Motion Using Noncovalent Interactions on Graphene and Its Application to Tailoring the Adsorption Energetics

Sayan Banerjee and Andrew M. Rappe
ACS Materials Letters, 2023, 5, 574-579.

96. Thiol–ene Click Chemistry Incorporates Hydroxyl Functionality on Polycyclooctene to Tune Properties

Roshni John Chethalen, John Chethalen, Eli J. Fastow, E. Bryan Coughlin, and Karen I. Winey
ACS Macro Letters, 2023, 12, 107-112.

95. Above-Room-Temperature Ferromagnetism in Thin van der Waals Flakes of Cobalt-Substituted Fe5GeTe2

Hang Chen, Shahidul Asif, Kapildeb Dolui, Yang Wang, Jeyson Támara-Isaza, V. M. L. Durga Prasad Goli, Matthew Whalen, Xinhao Wang, Zhijie Chen, Huiqin Zhang, Kai Liu, Deep Jariwala, M. Benjamin Jungfleisch, Chitraleema Chakraborty, Andrew F. May, Michael A. McGuire, Branislav K. Nikolic, John Q. Xiao, and Mark J. H. Ku
ACS Applied Materials & Interfaces, 2023, 15, 3287-3296.


94. Resolving the Impact of Hydrogen Bonding on the Phylloquinone Cofactor through Two-Dimentional Infrared Spectroscopy

Phoebe G. Askelson, Stephen L. Meloni, Alexander M. Hoffnagle, and Jessica M. Anna
Journal of Physical Chemistry B, 2022, 48, 10120-10135.

93. High-Throughput Fluorescent Screening and Machine Learning for Feature Selection of Electrocatalysts for the Alkaline Hydrogen Oxidation Reaction

Jeremy L. Hitt, Dasol Yoon, Jeffrey R. Shallenberger, David A. Muller, and Thomas E. Mallouk
ACS Sustainable Chemistry & Engineering, 2022, 10, 16299-16312.

92. The Effects of Iron Oxide Overlayers on Pt for CO Oxidation

Siwon Lee, Seunghyun Kim, Taeho Kim, Chao Lin, Woo-Jae Lee. Sang-Joon Kim, Raymond J.Gorte, and WooChul Jung
Catalysis Communications, 2022, 172, 106549.

91. A Study of Support Effects for the Water-Gas-Shift Reaction over Cu

Jian Chang, Zhuoming Feng, John M. Vohs, and Raymond J. Gorte
Catalysts, 2022, 12, 1364.

90. Three-state Nematicity and Magneto-optical Kerr Effect in the Charge Density Waves in Kagome Superconductors

Yishuai Xu, Zhuoliang Ni, Yizhou Liu, Brenden R. Ortiz, Qinwen Deng, Stephen D. Wilson, Binghai Yan, Leon Balents, and Liang Wu
Nature Physics, 2022, 18, 1470-1475.

89. Studies of the Reactivity of Graphene Driven by Mechanical Distortions

Nathaniel Hawthorne, Sayan Banerjee, Quentarius Moore, Andrew M. Rappe, and James D. Batteas
Journal of Physical Chemistry C, 2022, 126, 17569-17578.

88. Comparing Square-Planar RhI and IrI: Metal–Ligand Proton Tautomerism, Fluxionality, and Reactivity

Anant Kumar Jain, Michael R. Gau, Patrick J. Carroll, and Karen I. Goldberg
Organometallics, 2022, 41, 3341-3348.

87. Photomechanochemical Control over Stereoselectivity in the [2+2] Photodimerization of Acenaphthylene

Sankarsan Biswas, Sayan Banerjee, Milan Shlain, Andrey Bardin, Rein Ulijn, Brent Lane Nanenga, Andrew Rappe and Adam Braunschweig
Faraday Discussions, 2022, 144, 14037-14041.

86. C–C σ-Bond Oxidative Addition and Hydrofunctionalization by a Macrocycle-Supported Diiron Complex

Tianchang Liu, Ryan P. Murphy, Patrick J. Carroll, Michael R. Gao, and Neil C. Tomson
Journal of the American Chemical Society, 2022, 144, 14037-14041.

85. A Study of How LaFeO3 and CaTiO3 Supports Affect the Oxidation, Hydrogenation, and Methane Steam Reforming Activity of Pt and Ni Catalysts

Siwon Lee, Matteo Monai, Kai Shen, Jian Chang, John M. Vohs, and Raymond J. Gorte
Journal of Physical Chemistry C, 2022, 126, 11619-11628

84. Interfacial Reaction and Diffusion at the One-Dimensional Interface of Two-Dimensional PtSe2

Pawan Kumar, Andrew C. Meng, Kiyoung Jo, Eric A. Stach, and Deep Jariwala
Nano Letters, 2022, 12, 4733-4740.

83. Dealloyed Air- and Water-Sensitive Nanoporous Metals and Metalloids for Emerging Energy Applications

Jintao Fu, Samuel S. Welborn, and Eric Detsi
ACS Applied Energy Materials, 2022, 5, 6516-6544.

82. High Density, Localized Quantum Emitters in Strained 2D Semiconductors

Gwangwoo Kim, Hyong Min Kim, Pawan Kumar, Mahfujur Rahaman, Christopher E. Stevens, Jonghyuk Jeon, Kiyoung Jo, Kwan-Ho Kim, Nicholas Trainor, Haoyue Zhu, Byeong-Hyeok Sohn, Eric A. Stach, Joshua R. Hendrickson, Nicholas R. Glavin, Joonki Suh, Joan M. Redwing, and Deep Jariwala
ACS Nano, 2022, 16, 9651-9659.

81. Electrospun Gold Nanoprism/Poly(vinyl alcohol) Nanofibers for Flexible and Free-Standing Surface-Enhanced Raman Scattering Substrates

Alei Dang, Yuchen Wang, Huiqin Zhang, Weerapha Panatdasirisuk, Yu Xia, Zongyu Wang, Deep Jariwala, Tiehu Li, and Shu Yang
ACS Applied Nano Materials, 2022, 5, 6650, 6658.

80. Not Dark Yet for Strong Light-matter Coupling to Accelerate Singlet Fission Dynamics

Claudia Climent, David Casanova, Johannes Feist, and Francisco J. Garcia-Vidal
Cell Reports Physical Science, 2022, 3, 100841.

79. Mechanochemical Molecular Migration on Graphene

Sayan Banerjee and Andrew Rappe
Journal of the American Chemical Society, 2022, 144, 7181-7188.

78. Observation of Giant Surface Second-Harmonic Generation Coupled to Nematic Orders in the van der Waals Antiferromagnet FePS3

Zhuoliang Ni, Nan Huang, Amanda V. Haglund, David G. Mandrus, and Liang Wu
Nano Letters, 2022, 22, 3283-3288.

77. Impact of the Gibbs−Thomson Effect on Lithium Solubility in Silver Used as an Alloy Lithium-Ion Battery Anode

John S. Corsi, Alexander K. Ng, Yewei, and Eric Detsi
ACS Applied Energy Materials, 2022, 5, 4547-4555.

76. Sacrificial Silver Recovery during Nanoporous Gold Formation by Electrolytic Dealloying of Gold-Silver Alloy

John S Corsi, Jintao Fu, Lin Wang, Samuel Welborn, Zeyu Wang, and Eric Detsi
Journal of the Electrochemical Society, 2022, 169, 63501.

75. Microwave Heating of Nanocrystals for Rapid, Low-Aggregation Intermetallic Phase Transformations

Daniel J. Rosen,Alexander C. Foucher, Jennifer D. Lee, Shengsong Yang, Emanuele Marino, Eric Stach and Christopher B. Murray
ACS Materials Letters, 2022, 4, 823.830.

74. Cavity-enhanced Linear Dichroism in a van der Waals Antiferromagnet

Huiqin Zhang, Zhuoliang Ni, Christopher E. Stevens, Aofeng Bai, Frank Peiris, Joshua R. Hendrickson, Liang Wu and Deep Jariwala
Nature Photonics, 2022, 16, 311-317.

73. Light-mediated Aerobic Oxidation of C(sp3)–H Bonds by a Ce(IV) Hexachloride Complex

Yu-Heng Wang, Qiaomu Yang, Patrick J. Walsh, and Eric J. Schelter
Organic Chemistry Frontiers, 2022, 9, 2612-2620.

72. Decoupled Cation Transport within Layered Assemblies in Sulfonated and Crystalline Telechelic Polyethylenes

Benjamin A. Paren, Manuel Häußler, Patrick Rathenow, Stefan Mecking, and Karen I. Winey
Macromolecules, 2022, 55, 2813-2820.

71. In Situ EXAFS-Based Nanothermometry of Heterodimer Nanocrystals under Induction Heating

Daniel J. Rosen, Shengsong Yang, Emanuele Marino, Zhiqiao Jiang, and Christopher B. Murray
Journal of Physical Chemistry C, 2022, 126, 3623-3634.

70. Three-Chamber Design for Aqueous Acid− Base Redox Flow Batteries

Amy S. Metlay, Brandon Chyi, Yein Yoon, Ryszard J. Wycisk, Peter N. Pintauro and Thomas E. Mallouk
ACS Energy Letters, 2022, 7, 908-913.

69. MXene-Based Molecular Sieving Membranes for Highly Efficient Gas Separation

Ahmad Arabi Shamsabadi, Zahra Fakhraai, and Masoud Soroush
Chapter 18 in Mxenes and their Composites: Synthesis, Properties and Potential Applications, A volume in Micro and Nano Technologies, 2022, Elsevier.

68. Light–Matter Coupling in Large-Area van der Waals Superlattices

Pawan Kumar, Jason Lynch, Baokun Song, Haonan Ling, Francisco Barrera, Kim Kisslinger, Huiqin Zhang, Surendra B. Anantharaman, Jagrit Digani, Haoyue Zhu, Tanushree H. Choudhury, Clifford McAleese, Xiaochen Wang, Ben R. Conran, Oliver Whear, Michael J. Motala, Michael Snure, Christopher Muratore, Joan M. Redwing, Nicholas R. Glavin, Eric A. Stach, Artur R. Davoyan, and Deep Jariwala
Nature Nanotechnology2022, 17, 182-189.


67. A Metal-Free, Photocatalytic Method for Aerobic Alkane Iodination

Nathanael A. Hirscher, Nidhi Ohri, Qiaomu Yang, Jiawang Zhou, Jessica M. Anna, Eric J. Schelter, and Karen I. Goldberg
Journal of the American Chemical Society, 2021143, 19262-19267.

66. Design of a Superpositively Charged Enzyme: Human Carbonic Anhydrase II Variant with Ferritin Encapsulation and Immobilization

Joshua A. Bulos, Rui Guo, Zhiheng Wang, Maegan A. DeLessio, Jeffery G. Savan, and Ivan J. Dmochowski
Biochemistry, 202160, 3596-3609.

65. The Effect of Fe Dopant Location in Co(Fe)OOHx Nanoparticles for the Oxygen Evolution Reaction

Zhaozung Sun, Anthony Curto, Johnathan Rodriguez-Fernandez, Zegao Wang, Ayush Parikh, Jakob Fester, Mingdong Dong, Aleksandra Vojvodic, and Jeppe V. Lauritsen
ACS Nano202115, 18226-18236.

64. Probing Ligand Effects on the Ultrafast Dynamics of Copper Complexes via Midinfrared Pump–Probe and 2DIR Spectroscopies

Wei Weng, Alexander B. Weberg, Rahul Gera, Neil C. Tomson, and Jessica M. Anna
Journal of Physical Chemistry B, 2021125, 12228-12241.

63. Direct Imaging of Antiferromagnetic Domains and Anomalous Layer-Dependent Mirror Symmetry Breaking in Atomically Thin MnPS3

Zhuoliang Ni, Huiqin Zhang, David A. Hopper, Amanda V. Haglund, Nan Huang, Deep Jariwala, Lee C. Bassett, David G. Mandrus, Eugene J. Mele, Charles L. Kane, and Liang Wu
Physical Review Letters, 2021127, 187201.

62. Sub-3-Nanometer Domain Spacings of Ultrahigh-χ Multiblock Copolymers with Pendant Ionic Groups

Jinseok Park, Anne Staiger, Stefan Mecking, and Karen I. Winey
ACS Nano202115, 16738-16747.

61. Effect of Nanoscale Confinement on Polymer-Infiltrated Scaffold Metal Composites

Shawn M. Maguire, Connor R. Bilchak, John S. Corsi, Samuel S. Welborn, Theresa Tsaggaris, Jamie Ford, Eric Detsi, Zahra Fakhraai, and Russell J. Composto
ACS Applied Materials & Interfaces, 2021, 13, 44893-44903.

60. Air-Stable Nanoporous Aluminum/Lithium Borohydride Fuel Pellets for Onboard Hydrogen Generation by Hydrolysis with Pure Water

Timothy Lee, John S. Corsi, Lin Wang, and Eric Detsi
ACS Applied Energy Materials, 2021, 4, 9742-9750.

59. Effects of Side Reactions on the Kinetics of Nanoporous Gold Formation Revealed by Real-time X-ray Scattering During Electrolytic Dealloying

Samuel S. Welborn, John S. Corsi, Lin Wang, Asaph Lee, Jintao Fu, and Eric Detsi
Journal of Materials Chemistry A, 2021, 9, 19994-20005.

58. Fluorine-Free Precise Polymer Electrolyte for Efficient Proton Transport: Experiments and Simulations

Benjamin A. Paren, Bryce A. Thurston, Arjun Kanthawar, William J. Neary, Aaron Kendrick, Manuel Maréchal, Justin G. Kennemur, Mark J. Stevens, Amalie L. Frischknecht, and Karen I. Winey
Chemistry of Materials, 2021, 33, 6041-6051.

57. Anisotropic Nanocrystal Shape and Ligand Design for Co-Assembly

Katherine C. Elbert, William Zygmunt, Corbin M. Vara, Daniel J. Rosen, Nadia M. Krook, Sharon C. Glotzer, and Christopher B. Murray
Science Advances, 2021, 7, eabf9402.

56. Photocatalytic C-H Activation and the Subtle Role of Chlorine Radical Complexation in Reactivity

Qiaomu Yang, Yu-Heng Wang, Yusen Qiao, Michael Gao, Patrick J. Carroll, Patrick J. Walsh, and Eric J. Schelter
Science, 2021, 372, 847-852.

55. Mono and Dinuclear Binding Modes of the 2,5-Bis(α2 pyridyl)pyrrolate Ligand in Platinum(II) Complexes

Drew C. Newman, Michael R. Gao, Patrick J. Caroll, and Karen I. Goldberg
Organometallics, 202140, 1806-1810.

54. Nanoscale Chemical and Structural Analysis during In Situ Scanning/Transmission Electron Microscopy in Liquids

Rui Serra-Maia, Pawan Kumar, Andrew C. Meng, Alexandre C. Foucher, Yijin Kang, Khim Karki, Deep Jariwala, and Eric A. Stach
ACS Nano, 2021, 15, 10228-10240.

53. Modified MAX Phase Synthesis for Environmentally Stable and Highly Conductive Ti3C2 MXene

Tyler S. Mathis, Kathleen Maleski, Adam Goad, Asia Sarycheva, Mark Anayee, Alexandre C. Foucher, Kanit Hantanasirisakul, Christopher E. Shuck, Eric A. Stach, and Yury Gogotsi
ACS Nano, 2021, 15, 6420-6429.

52. Tuning Metal–Metal Interactions for Cooperative Small Molecule Activation

Quiran Wang, Sam H. Brooks, Tianchang Liu, and Neil C. Tomson
Chemical Communications, 2021, 57, 2839-2853.

51. Using Internal Electrostatic Fields to Manipulate the Valence Manifolds of Copper Complexes

Alexander B. Weberg, Samuel P. McCollom, Laura M. Thierer, Michael R. Gao, Patrick J. Carroll, and Neil C. Tomson
Chemical Science, 2021, 12, 4395-4404.

50. Lowering the Barrier to C–H Activation at IrIII through Pincer Ligand Design

Sophie B. Rubashkin, Wan-Yi Chu, and Karen I. Goldberg
Organometallics, 2021, 40, 1296-1302.

49. Structure–Property Relationships in Single-Ion Conducting Multiblock Copolymers: A Phase Diagram and Ionic Conductivities

Jinseok Park, Anne Staiger, Stefan Mecking, and Karen I. Winey
Macromolecules, 2021, 54, 4269-4279.

48. Computer‐Free Autonomous Navigation and Power Generation Using Electro‐Chemotaxis

Min Wang, Yue Gao, and James H. Pikul
Advanced Intelligent Systems, 2021, 2000255.

47. A High Throughput Optical Method for Studying Compositional Effects in Electrocatalysts for CO2 Reduction

Jeremy L. Hitt, Yuguang C. Li, Songsheng Tao, Zhifei Yan, Yue Gao, Simon J. L. Billinge, and Thomas E. Mallouk
Nature Communications, 2021, 12, 1114.

46. Synthetic Modeling of the Structure and Function of the Rare-earth Dependent Methanol Dehydrogenase Cofactor

Alison L. Knasin and Eric J. Schelter
In Methods in Enzymology, Chapter 2 of volume “Rare-Earth Element Biochemistry: Methanol Dehydrogenases and Lanthanide Biology”, 2021, 50, 19-55.

45. Insights into the Degradation Mechanism of Nanoporous Alloy-Type Li-Ion Battery Anodes

John S. Corsi, Samuel S. Welborn, Eric A. Stach, and Eric Detsi
ACS Energy Letters, 2021, 6, 1749-1756.

44. Enhanced Carrier Transport in Strongly Coupled, Epitaxially Fused CdSe Nanocrystal Solids

Qinghua Zhao, Guillaume Gouget, Jiacen Guo, Shengsong Yang, Tianshuo Zhao, Daniel B. Straus, Chengyang Qian, Nuri Oh, Han Wang, Christopher B. Murray, and Cherie R. Kagan
Nano Letters, 2021, 21, 3318-3324.

43. Efficacy of Boron Nitride Encapsulation Against Plasma-processing of 2D Semiconductor Layers

Pawan Kumar, Kelotchi S. Figueroa, Alexandre C. Foucher, Kiyoung Jo, Natalia Acera, Eric A. Stach, and Deep Jariwala
Journal of Vacuum Science & Technology A, 2021, 39, 32201.

42. Using X-Ray Scattering to Elucidate the Microstructural Instability of 3D Bicontinuous Nanoporous Metal Scaffolds for Use in an Aperiodic 3D Tricontinuous Conductor–Insulator–Conductor Nanocapacitor

Samuel S. Welborn, Sven van der Meer, John S. Corsi, Jeff Th. M. de Hosson, and Eric Detsi
ACS Applied Materials & Interfaces, 2021, 13, 11721-11731.

41. Effect of Nanopore Geometry in the Conformation and Vibrational Dynamics of a Highly Confined Molecular Glass

Haonan Wang, Kenneth L. Kearns, Aixi Zhang, Ahmad Arabi Shamsabadi, Yi Jin, Aaron Bond, Steven M. Hurney, Carlos Morillo, and Zahra Fakhraai
Nano Letters, 2021, 21, 1778-1784.

40. Eco-friendly Synthesis of Nanoporous Magnesium by Air-Free Electrolytic Dealloying with Recovery of Sacrificial Elements for Energy Conversion and Storage Applications


Jintao Fu, John S. Corsi, Samuel S. Welborn, Victoria Basile, Lin Wang, Alexander K. Ng, and Eric Detsi
ACS Sustainable Chemistry & Engineering, 2021, 9, 2762-2769. (cover article)

39. Determination of Dielectric Functions and Exciton Oscillator Strength of Two-Dimensional Hybrid Perovskites

Baokun Song, Jin Hou, Haonan Wang, Siraj Sidhik, Jinshui Miao, Honggang Gu, Huiqin Zhang, Shiyuan Liu, Zahra Fakhraai, Jacky Even, Jean-Christophe Blancon, Aditya D. Mohite, and Deep Jariwala
ACS Materials Letters, 2021, 3, 148-159.


38. Gas Flow through Atomic-scale Apertures

Jothi Priyanka Thiruraman, Sidra Abbas Dar, Paul Masih Das, Nasim Hassani, Mehdi Neek-Amal, Ashok Keerthi, Marija Drndić, and Boya Radha
Science Advances, 2020, 6, eabc7927.

37. Tailoring Electronic and Optical Properties of MXenes through Forming Solid Solutions

Meikang Han, Kathleen Maleski, Christopher Eugene Shuck, Yizhou Yang, James T. Glazar, Alexandre C. Foucher, Kanit Hantanasirisakul, Asia Sarycheva, Nathan C. Frey, Steven J. May, Vivek B. Shenoy, Eric A. Stach, and Yury Gogotsi
Journal of the American Chemical Society, 2020, 142, 19110-19118.

36.  Impact of Hierarchical Nanoporous Architectures on Sodium Storage in Antimony-Based Sodium-Ion Battery Anodes

Manni Li, Tian Qiu, Alexandre C. Foucher, Jintao Fu, Zeyu Wang, Dongxing Zhang, Andrew M. Rappe, Eric A. Stach, and Eric Detsi
ACS Applied Energy Materials, 2020, 3, 11231-11241.

35.  Modeling Exsolution of Pt from ATiO3 Perovskites (A = Ca/Sr/Ba) Using First-Principles Methods

Abhinav S. Raman and Aleksandra Vojvodic
Chemistry of Materials, 2020, 32, 9642-9649.

34.  Percolated Ionic Aggregate Morphologies and Decoupled Ion Transport in Precise Sulfonated Polymers Synthesized by Ring-Opening Metathesis Polymerization

Benjamin A. Paren, Bryce A. Thurston, William J. Neary, Aaron Kendrick, Justin G. Kennemur, Mark J. Stevents, Amalie L. Frischkneckt, and Karen I. Winey
Macromolecules, 2020, 53, 8960-8973.

33.  Giant Gate-Tunability of Complex Refractive Index in Semiconduction Carbon Nanotubes

Baokun Song, Fang Liu, Haonan Wang, Jinshui Miao, Yueli Chen, Pawan Kumar, Huiqin Zhang, Xiwen Liu, Honggang Gu, Eric A. Stach, Xuelei Liang, Shiyuan Liu, Zahra Fakhraai, and Deep Jariwala
ACS Photonics, 2020, 7, 2896-2905.

32. Electron Transport in Dye-Sensitized TiO2 Nanowire Assays in Contact with Aqueous Electrolytes 

Langqiu Xiao, Yanan Yu, Emma L. Schultz, Eric A. Stach, and Thomas E. Mallouk
Journal of Physical Chemistry C, 2020, 124, 22003-22010.

31. Extracting the Frequency-Dependent Dynamic Stokes Shift from Two-Dimensional Electronic Spectra with Prominent Vibrational Coherences

Jiawei Lu, Yumin Lee, and Jessica M. Anna
Journal of Physical Chemistry B2020, 124, 8857-8867.

30. Cavity Molecular Dynamics Simulations of Liquid Water under Vibrational Ultrastrong Coupling

Tao E. Li, Joseph E. Subotnik, and Abraham Nitzan
Proceedings of the National Academy of Sciences, 2020, 117, 18324-18331.

29. Stochastic Ionic Transport in Single Atomic Zero-Dimensional Pores 

Jothi Priyanka Thiruraman, Paul Masih Dan, and Marija Drndić
ACS Nano2020, 14, 11831-11845.

28. On the Origin of Ground-State Vacuum-Field Catalysis: Equilibrium Consideration 

Tao E. Li, Abraham Nitzan, and Joseph E. Subotnik
Journal of Chemical Physics2020, 152, 234107.

27. General Approach for Reducing Continuous Translational Symmetry Errors in Finite Difference Real-Space Calculations 

Tian Qiu, Leeor Kronik, and Andrew M. Rappe
Journal of Chemical Theory and Computation2020, 16, 4327-4336.

26. Reviving Inert Oxides for Electrochemical Water Splitting by Subsurface Engineering

Liang Zhang, Abhinav S. Raman, and Aleksandra Vojvodic
Chemistry of Materials2020, 32, 5569-5578.

25. Direct Visualization of Out-of-Equilibrium Structural Transformations in Atomically Thin Chalcogenides

Pawan Kumar, James P. Horwath, Alexandre C. Foucher, Christopher C. Price, Natalia Acero, Vivek B. Shenoy, Eric A. Stach, and Deep Jariwala
npj 2D Materials and Applications2020, 4, 16.

24. Epitaxial and Strong Support Interations between Pt and LaFeO3 Films Stabilize Pt Dispersion

Xinyu Mao, Alexandre C. Foucher, Tiziano Montini, Eric A. Stach, Paolo Fornasiero, and Raymond J. Gorte
Journal of the American Chemical Society2020, 142, 10373-10382.

23. Quasiclassical Modeling of Cavity Quantum Electrodynamics

Tao E. Li, Hsing-Ta Chen, Abraham Nitzan, and Joseph E. Subotnik
Physical Review A2020, 101, 033831.

22. Activated Alumina as Value-Added Byproduct from the Hydrolysis of Hierarchical Nanoporous Aluminum with Pure Water to Generate Hydrogen Fuel

Timothy Lee, Jintao Fu, Victoria Basile, John S. Corsi, Zeyu Wang and Eric Detsi
Renewable Energy2020155, 189-196.

21. Surface Stability of Perovskite Oxides under OER Operating Conditions: A First Principles Approach

Abhinav S. Raman, Roshan Patel and Akelsandra Vojvodic
Faraday Discussions, 2021, 229, 75-88.

20. Diastereoselective Synthesis of Benzoxanthenones

William C. Neuhaus and Marisa C. Kozlowski
Chemistry An Asian Journal, 2020, 15, 1039-1043.

19. Total Synthesis of Pyrolaside B: Phenol Trimerization via Sequenced Oxidative C‐C and C‐O Coupling

Marisa C. Kozlowski and William C. Neuhaus
Angew. Chem., Int. Ed. Eng., 2020, 59, 7842-7847.

18. Perspective – Reversible Magnesium Storage in Silicon: An Ongoing Challenge

Dongyang Zhang, Jintao fu, Zeyu Wang, Lin Wang, John S. Corsi, and Eric Detsi
Journal of the Electrochemical Society, 2020, 167, 050514.

17. In Situ Electrochemical Dilatometry Study of (De)lithiation and Polysulfide Dissolution-Induced Dimensional Changes in Lithium-Sulfur Cathodes during Charging and Discharging

Manni Li, Zeyu Wang, and Eric Detsi
Journal of the Electrochemical Society, 2020, 167, 050505.

16. A Robust and Unified Solution for Choosing the Phases of Adiabatic States as a Function of Geometry: Extending Parallel Transport Concepts to the Cases of Trivial and Near-Trivial Crossings

Zeyu Zhou, Zuxin Jin, Tian Qiu, Andrew M. Rappe and Joseph Eli Subotnik
Journal of Chemical Theory and Computation, 2020, 16, 835-846.

15. Atomic-Scale Patterning in Two-Dimensional van der Waals Superlattices

Paul Masih Das, Jothi Priyanka Thiruraman, Meng-Qiang Zhao, Srinivas V. Mandyam, A. T. Charlie Johnson, and Marija Drndić
Nanotechnology, 2020, 31, 105302.

14. Three-dimensional Hierarchical Nanoporous Copper via Direct Ink Writing and Dealloying

Shahryar Mooraj, Samuel S. Welborn, Shuyang Jiang, Siyuan Peng, Jintao Fu, Sarah Baker, Eric B. Duoss, Cheng Zhu, Eric Detsi, and Wen Chen
Scripta Materialia, 2020, 177, 146-150.

13. Small-Angle X-Ray Scattering of Nanoporous Materials

Samuel S. Welborn and Eric Detsi
Nanoscale Horizons, 2020, 5, 12-24.


12. Chain and Ion Dynamics in Precise Polyethylene Ionomers

Amalie L. Frischknecht, Benjamin A. Paren, L. Robert Middleton, Jason P. Koski, Jacob D. Tarver, Madhusudan Tyagi, Christopher L. Soles and Karen I. Winey
Macromolecules, 2019, 52, 7939-7950.

11. High-rate and Long Cycle-Life Alloy-Type Magnesium-Ion Battery Anode Enabled through (De)magnesiation-Induced Near-Room-temperature Solid-liquid Phase Transformation

Lin Wang, Samuel S. Welborn, Hemant Kumar, Manni Li, Zeyu Wang, Vivek Shenoy, and Eric Detsi
Advanced Energy Materials, 2019, 9, 1902086.

10. Generalized Synthetic Strategy for Transition-Metal-Doped Brookite-Phase TiO2 Nanorods

We report a generalized wet-chemical methodology for the synthesis of transition-metal (M)-doped brookite-phase TiO2 nanorods (NRs) with unprecedented wide-range tunability in dopant composition (M = V, Cr, Mn, Fe, Co, Ni, Cu, Mo, etc.).







Zhiyong Zhang, Qiyuan Wu, Grayson Johnson, Yifan Ye, Xing Li, Na Li, Meiyang Cui, Jennifer D. Lee, Chang Liu, Shen Zhao, Shuang Li, Alexander Orlov, Christopher B. Murray, Xu Zhang, T. Brent Gunnoe, Dong Su, and Sen Zhang
Journal of the American Chemical Society, 2019, 141, 16548-16552.

9. Acid-Assisted Hydrogenation of CO2 to Methanol in a Homogeneous Catalytic Cascade System

A catalytic cascade system for CO2 hydrogenation to MeOH under acidic conditions is described. The reaction uses three catalysts which promote stepwise formation and conversion of formic acid and formate ester intermediates.







Wan-Yi Chu, Zuzana Culakova, Bernie T. Wang, and Karen I. Goldberg
ACS Catalysis, 2019, 9, 9317-9326.

8. Irradiation of Transition Metal Dichalcogenides Using a Focused Ion Beam: Controlled Single-Atom Defect Creation

Jothi Priyanka Thiruraman, Paul Masih Das, and Marija Drndić
Advanced Functional Materials, 2019, 1904668.

7. Impact of Building Block Structure on Ion Transport in Cyclopropenium-based Polymerized Ionic Liquids

Benjamin A. Paren,  Ramya Raghunathan, Isaac J. Knudson, Jessica L. Freyer, Luis M. Campos, and Karen I. Winey
Polymer Chemistry, 201910, 2832-2839.

6. Hierarchical Bulk Nanoporous Aluminum for On-Site Generation of Hydrogen by Hydrolysis in Pure Water and Catalytic Combustion of Solid Fuels

John S. Corsi, Jingtao Fu, Zeyu Wang, Timothy Lee, Alexander K. Ng, and Eric Detsi

ACS Sustainable Chemistry & Engineering2019, 7, 11194-11204.
Supporting Video 1      Supporting Video 2     Supporting Video 3

5. The Influence of Surface Platinum Deposits on the Photocatalytic Activity of Anatase TiO2 Nanocrystals

Paul A. Pepin, Jennifer D. Lee, Alexandre C. Foucher, Christopher B. Murray, Eric A. Stach, and John M. Vohs
The Journal of Physical Chemistry C, 2019, 123, 10477-10486.

4. Visible Light Plasmonic Heating-Enhanced Electrochemical Current in Nanoporous Gold Cathodes
(a) Illustration of the electrochemical cell configuration. (b) The curves represent the current densities measured in two different cells. In the absence of light, Al spontaneously dissolves in dilute sulfuric acid and electrons from this anodic oxidation reaction diffuse through the external circuit to the NP-Au cathode where H+ is reduced to H2 gas, resulting in a current in the cell on the order of −0.1 mA/cm2. When light is turned on, the absolute value of this current density increases from 0.1 mA/cm2 to 2 mA/cm2. When the light is turned off the absolute value of the current density decreases back to 0.1 mA/cm2. (c) Comparison of the photoelectrochemical current density generated by external heat only, and by both plasmonic and external heats.

Alexander Pröschel, Joel Chacko, Richard Whitaker, Mavis Athene U Chen and Eric Detsi
Journal of the Electrochemical Society, 2019, 156, H146-H150.

3. In situ Electrochemical Dilatometry Study of Capacity Fading in Nanoporous Ge-based Na-ion Battery Anodes

Manni Li, Zeyu Wang, Jintao Fu, Ke Ma, and Eric Detsi
Scripta Materialia, 2019, 164, 52-56.

2. Centimeter-Scale Nanoporous 2D Membranes and Ion Transport: Porous MoS2 Monolayers in a Few-Layer Matrix

Paul Masih Das, Jothi Priyanka Thiruraman, Yung-Chien Chou, Gopinath Danda, and Marija Drndić
Nano Letters, 2019, 19, 392-399.


1. Thermal and Photocatalytic Reactions of Methanol and Acetaldehyde on Pt-Modified Brookite TiO2 Nanorods

Paul A. Pepin, Jennifer D. Lee, Christopher B. Murray, and John M. Vohs
ACS Catalysis, 2018, 8, 11834-11846


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