2024
Insertion of Molecular Oxygen into a Gold(III)–Hydride Bond
Phearman, A. S.; Ardon, Y.; Goldberg, K. I. J. Am. Chem. Soc. 2024, 146, 4045–4059.
2023
Ethanol Upgrading to n-Butanol Using Transition-Metal-Incorporated Poly(triazine)imide Frameworks
Cypher, S. M.; Pauly, M.; Castro, L. G.; Donley, C. L.; Maggard, P. A.; Goldberg, K. I. ACS Appl. Mater. Interfaces 2023, 15, 36384-36393.
Lewis Acids and Electron-Withdrawing Ligands Accelerate CO Coordination to Dinuclear CuI Compounds
Johnsen, W. D.; Deegbey, M.; Grills, D. C.; Polyansky, D. E.; Goldberg, K. I.; Jakubikova, E.; Mallouk, T. E. Inorg. Chem. 2023, 62, 9146-9157.
2022
Comparing Square–Planar RhI and IrI: Metal–Ligand Proton Tautomerism, Fluxionality, and Reactivity
Jain, A. K.; Gau, M. R.; Carroll, P. J.; Goldberg, K. I. Organometallics 2022, 41, 3341-3348.
Metal–Ligand–Anion Cooperation in C–H Bond Formation at Platinum(II)
Zeitler, H. E.; Phearman, A. S.; Gau, M. R.; Carroll, P. J.; Cundari, T. R.; Goldberg, K.I. J. Am. Chem. Soc. 2022, 144, 14446-14451.
The underappreciated influence of ancillary halide on metal-ligand proton tautomerism
Jain, A. K.; Gau, M. R.; Carroll, P. J.; Goldberg, K. I. Chem. Sci. 2022, 13, 7837-7845.
2021
A Metal-Free, Photocatalytic Method for Aerobic Alkane Iodination
Hirscher, N. A.; Ohri, N.; Yang, Q.; Zhou, J.; Anna, J. M.; Schelter, E. J.; Goldberg, K.I. J. Am. Chem. Soc. 2021, 143, 19262-19267.
Mono- and Dinuclear Binding Modes of the 2,5-Bis(α-pyridyl)pyrrolate Ligand in Platinum(II) Complexes.
Newman, D. C.; Gau, M. R.; Carroll, P. J.; Goldberg, K. I. Organometallics 2021, 40, 1806-1810.
Lowering the Barrier to C–H Activation at IrIII through Pincer Ligand Design.
Rubashkin, S. B.; Chu, W. -Y.; Goldberg, K. I. Organometallics 2021, 40, 1296-1302.
(Hexamethylbenzne)Ru Catalysts for the Aldehyde-Water Shift Reaction.
Phearman, A. S.; Moore, J. M.; Bhagwandin, D. D.; Goldberg, J. M.; Heinekey, D. M.; Goldberg, K. I. Green Chem. 2021, 23, 1609-1615.
2020
Metal/Ligand Proton Tautomerism Facilitates Dinuclear H2 Reductive Elimination.
Kuo, J. L.; Goldberg, K. I. J. Am. Chem. Soc. 2020, 142, 21439-21449.
Preparation and Reactivity of Bimetallic (pincer)Ir Complexes.
Goldberg, J. M.; Guard, L. M.; Wong, G. W.; Brayton, D. F.; Kaminsky, W.; Goldberg, K. I.; Heinekey, D. M. Organometallics, 2020, 39, 3323-3334.
Synthesis and Reactivity of PtII Methyl Complexes Supported by Pyrazolate Pincer Ligands.
Zahora, B. A.; Gau, M. R.; Goldberg, K. I. Organometallics 2020, 39, 1230-1237.
2019
Acid-Assisted Hydrogenation of CO2 to Methanol in a Homogeneous Catalytic Cascade System.
Chu, W. -Y.; Culakova, Z.; Wang, B. T.; Goldberg, K. I. ACS Catal. 2019, 9, 9317-9326.
Experimental and Computational Investigation of the Aerobic Oxidation of a Late Transition Metal-Hydride.
Wright, A. M.; Pahls, D. R.; Gary, J. B.; Warner, T.; Williams, J. Z.; Knapp, S. M. M.; Allen, K. E.; Landis, C. R.; Cundari, T. R.; Goldberg, K. I. J. Am. Chem. Soc. 2019, 141, 10830-10843.
Hydrogenolysis of dinuclear PCNR ligated PdII μ‐hydroxides and their mononuclear PdII hydroxide analogues.
Bailey, W. D.; Phearman, A. S.; Luconi,L.; Rossin, A.; Yakhvarov, D.; D’Accolti, L.; Flowers, S. E.; Kaminsky, W.; Kemp, R. A.; Giambastiani, G.; Goldberg, K. I. Chem. Eur. J. 2019, 25, 9920-9929.
Electrophilic Organoiridium(III) Pincer Complexes on Sulfated Zirconia for Hydrocarbon Activation and Functionalization.
Syed, Z.; Kaphan, D.; Perras, F. A.; Pruski, M.; Ferrandon, M. S.; Wegener, E. C.; Celik, G.; Wen, J.; Liu, C.; Dogan, F.; Goldberg, K. I.; Delferro, M. J. Am. Chem. Soc. 2019, 141, 6325–6337.
2018
Insertion of Molecular Oxygen into the Metal–Methyl Bonds of Platinum(II) and Palladium(II) 1,3-Bis(2-pyridylimino)isoindolate Complexes.
Zeitler, H. E.; Kaminsky, W. A.; Goldberg, K. I. Organometallics 2018, 37, 3644-3648.
The Key Role of the Hemiaminal Intermediate in the Iron-catalyzed Deaminative Hydrogenation of Amides.
Artús Suàrez, L.; Culakova, Z.; Balcells, D.; Bernskoetter, W. H.; Eisenstein, O.; Goldberg, K. I.; Hazari, N.; Tilset, M.; Nova, A. ACS Catal. 2018, 8, 8751-8762.
2017
Bond Activation by Metal Complexes: Special Issue in Honor of the 2017 Wolf Prize Laureate in Chemistry, Professor Robert G. Bergman.
Goldberg, K. I.; Milstein, D. Isr. J. Chem. 2017, 57, 915-915.
Detection of an Iridium-Dihydrogen Complex: A Proposed Intermediate in Ionic Hydrogenation.
Goldberg, J. M.; Goldberg, K. I.; Heinekey, D. M.; Burgess, S. A.; Lao, D. B.; Linehan, J. C. J. Am. Chem. Soc. 2017, 139, 12638-12646.
Direct Formation of Carbon(sp3)-Heteroatom Bonds from RhIII to Produce Methyl Iodide, Thioethers, and Alkylamines.
Stevens, T. E.; Smoll, K. A.; Goldberg, K. I. J. Am. Chem. Soc. 2017, 139, 7725-7728.
Photolysis of Pincer-Ligated PdII-Me Complexes in the Presence of Molecular Oxygen.
Smoll, K. A.; Kaminsky, W.; Goldberg, K. I. Organometallics 2017, 36, 1213-1216.
Oxidative addition of iodine to (tBu)4 (POCOP)Ir(CO) complexes.
Goldberg, J. M.; Berman, J. L.; Kaminsky, W.; Goldberg, K. I.; Heinekey, D. M. J. Organomet. Chem. 2017, 845, 171-176.
The Effect of the cis-donor in pincer ligands on hydrogenolysis of Pd-OH: A DFT study.
Parkes, M. V.; Bailey, W. D.; Goldberg, K. I.; Kemp, R. A. J. Organomet. Chem. 2017, 845, 165-170.
β-Hydride elimination and C-H activation by an iridium acetate complex, catalyzed by Lewis acids. Alkane dehydrogenation cocatalyzed by Lewis acids and [2,6-Bis(4,4-dimethyloxazolinyl)-3,5-dimethylphenyl]iridium.
Gao, Y.; Guan, C.; Zhou, M.; Kumar, A.; Emge, T. J.; Wright, A. M.; Goldberg, K. I.; Krogh-Jespersen, K.; Goldman, A. S. J. Am. Chem. Soc. 2017, 139, 6338-6350.
Large-Scale Selective Functionalization of Alkanes.
Goldberg, K. I.; Goldman, A. S. Acc. Chem. Res. 2017, 50, 620-626.
2016
Hydrogen Addition to (pincer)IrI(CO) Complexes: The Importance of Steric and Electronic Factors.
Goldberg, J. M.; Cherry, S. D. T.; Guard, L. M.; Kaminsky, W.; Goldberg, K. I.; Heinekey, D. M. Organometallics 2016, 35, 3546-3556.
High Catalytic Efficiency Combined with High Selectivity for the Aldehyde-Water Shift Reaction using (para-cymene)Ruthenium Precatalysts.
Brewster, T. P.; Goldberg, J. M.; Tran, J. C.; Heinekey, D. Michael; Goldberg, K. I. ACS Catal., 2016, 6, 6302-6305.
Base-Free Iridium-Catalyzed Hydrogenation of Esters and Lactones.
Brewster, T. P.; Rezayee, N. M.; Culakova, Z.; Sanford, M. S.; Goldberg, K. I. ACS Catal. 2016, 6, 3113-3117.
2015
The Importance of Steric Factors in Iridium Pincer Complexes.
Goldberg, J. M.; Wong, G. W.; Brastow, K. E.; Kaminsky, W.; Goldberg, K. I.; Heinekey, D. M. Organometallics 2015, 34, 753-762.
Pyrazole-Based PCN Pincer Complexes of Palladium(II): Mono- and Dinuclear Hydroxide Complexes and Ligand Rollover C–H Activation.
Bailey, W. D.; Luconi, L.; Rossin, A.; Yakhvarov, D.; Flowers, S. E.; Kaminsky, W.; Kemp, R. A.; Giambastiani, G.; Goldberg, K. I. Organometallics 2015, 34, 3998-4010.
2014
Bailey, W. D. Parkes, M. V.; Kemp, R. A.; and Goldberg, K. I., Reactions of Square-Planar d8 Pincer Complexes with Oxygen and Hydrogen. In Pincer and Pincer-Type Complexes: Applications in Organic Synthesis and Catalysis, Szabo, K., J. and Wendt, Ola F., Ed. Wiley-VCH 2014; pp 281-298.
Organometallics Roundtable 2013–2014
Gladysz, J. A.; Bedford, R. B.; Fujita, M.; Gabbaı̈, F. P.; Goldberg, K. I.; Holland, P. L.; Kiplinger, J. L.; Krische, M. J.; Louie, J.; Lu, C. C.; Norton, J. R.; Petrukhina, M. A.; Ren, T.; Stahl, S. S.; Tilley, T. D.; Webster, C. E.; White, M. C.; Whiteker, G. T Organometallics 2014, 33, 1505-1527.
Platinum(II) Olefin Hydroarylation Catalysts: Tuning Selectivity for the anti-Markovnikov Product.
Clement, M. L.; Grice, K. A.; Luedtke, A. T.; Kaminsky, W.; Goldberg, K. I. Chemistry- A European Journal 2014, 20, 17287-17291.
Understanding the Effect of Ancillary Ligands on Concerted Metalation-Deprotonation by (dmPhebox)Ir(OAc)2(H2O) Complexes: A DFT Study.
Pahls, D. R.; Allen, K. E.; Goldberg, K. I.; Cundari, T. R. Organometallics 2014, 33, 6413-6419.
Reactions of Pd and Pt Complexes with Molecular Oxygen.
Scheuermann, M. L.; Goldberg K. I. Chemistry- A European Journal 2014, 20, 14556-14568.
Iridium, Rhodium, and Ruthenium Catalysts for the “Aldehyde-Water Shift” Reaction.
Brewster, T. P.; Ou, W. C.; Tran, J. C.; Goldberg, K. I.; Hanson, S. K.; Cundari, T. R.; Heinekey, D. M. ACS Catalysis 2014, 4, 3034-3038.
Hemilability of P(X)N-type ligands (X = O, N-H): rollover cyclometalation and benzene C-H activation from (P(X)N)PtMe2 complexes.
Scheuermann, M. L.; Grice, K. A.; Ruppel, M. J.; Rossello-Merino, M.; Kaminsky W.; Goldberg, K. I. Dalton Trans. 2014, 43, 12018-12025.
Methylplatinum(II) and Molecular Oxygen: Oxidation to Methylplatinum(IV) in Competition with Methyl Group Transfer to Form Dimethylplatinum(IV).
Prantner, J. D.; Kaminsky, W.; Goldberg, K. I. Organometallics 2014, 33, 3227-3230.
Oxygen-Promoted C-H Bond Activation at Palladium.
Scheuermann, M. L..; Boyce, D. W.; Grice, K. A.; Kaminsky, W.; Stoll, S.; Tolman, W. B.; Swang, O.; Goldberg, K. I. Angew. Chem. Int. Ed. 2014, 53, 6492-6495.
Synthesis and Characterization of Anionic, Neutral, and Cationic PNP Pincer Pd(II) and Pt(II) Hydrides.
Bailey, W. D.; Kaminsky W.; Kemp, R. A.; Goldberg, K. I. Organometallics 2014, 33, 2503-2509.
Regeneration of an Iridium(III) Complex Active for Alkane Dehydrogenation Using Molecular Oxygen.
Allen, K. E.; Heinekey, D. M.; Goldman, A. S.; Goldberg, K. I. Organometallics 2014, 33, 1337-1340.
Arene Activation at Iridium Facilitates C-O Bond Cleavage of Aryl Ethers.
Miller, A. J. M.; Kaminsky, W.; Goldberg, K. I. Organometallics 2014, 33, 1245-1252.
2013
Hydrogenation of Carboxylic Acids Catalyzed by Half-Sandwich Complexes of Iridium and Rhodium.
Brewster, T. P.; Miller, A. J. M.; Heinekey, D. M.; Goldberg, K. I. J. Am. Chem. Soc. 2013, 135, 16022-16025.
Partial Deoxygenation of Glycerol Catalyzed by Iridium Pincer Complexes.
Lao, D. B.; Owens, A. C. E.; Heinekey, D. M.; Goldberg, K. I. ACS Catalysis 2013, 3, 2391-2396.
Reactions of Five-Coordinate Platinum(IV) Complexes with Molecular Oxygen.
Scheuermann, M. L; Luedtke, A. T.; Hanson, S. K.; Fekl, U.; Kaminsky, W.; Goldberg, K. I. Organometallics 2013, 32, 4752-4758.
Synthesis and Characterization of Iridium(I) and Iridium(III) Complexes Containing Dialkylbiphenylphosphines.
O’Connor, A. R.; Kaminsky, W.; Chan, B. C.; Heinekey, D. M.; Goldberg, K. I. Organometallics 2013, 32, 4016-4019.
Catalytic Disproportionation of Formic Acid to Generate Methanol.
Miller, A. J. M.; Heinekey, D. M.; Mayer, J. M.; Goldberg, K. I. Angew. Chem. Int. Ed. 2013, 52, 3981-3984.
Alkane Dehydrogenation by C-H Activation at Iridium(III).
Allen, K. E.; Heinekey, D. M.; Goldman, A. S.; Goldberg, K. I. Organometallics 2013, 32, 1579-1582.
Generation and Structural Characterization of a Gold(III) Alkene Complex.
Langseth, E.; Scheuermann, M. L.; Balcells, D.; Kaminsky, W.; Goldberg, K. I.; Eisenstein, O.; Heyn, R. H.; Tilset, M. Angew. Chem. Int. Ed. 2013, 52, 1660-1663.
Pincer Complexes as Catalysts for Amine Borane Dehydrogenation.
St. John, A.; Goldberg, K. I.; Heinekey, D. M. Top. Organomet. Chem. 2013, 40, 271.
2012
Reactions of Late Transition Metal Complexes with Molecular Oxygen
Boisvert. L; Goldberg, K. I. Accounts of Chemical Research 2012, 45, 899.
A Soluble Copper-bipyridine Water-oxidation Electrocatalyst
Barnett, S. M.; Goldberg, K. I.; Mayer, J. M. Nature Chem. 2012, 4, 498.
Partial Deoxygenation of 1,2-Propanediol Catalyzed by Iridium Pincer Complexes
Ahmed Foskey, T. J.; Heinekey, D. M.; Goldberg, K. I. ACS Catalysis 2012, 2, 1285.
η6 Tetramethylfulvene and μ-η3:η3-Benzene Complexes of Iridium
Meredith, J. M.; Goldberg, K. I.; Kaminsky, W. Heinekey, D. M. Organometallics 2012, 31, 8459-8462.
Catalytic Arene H/D Exchange with Novel Rhodium and Iridium Complexes
Rhinehart, J. L.; Manbeck, K. A.; Buzak, S. K.; Lippa G. M.; Brennessel, W. W.; Goldberg, K. I.; Jones, W. D. Organometallics 2012, 31, 1943.
C-H Bond Activation by Cationic Iridium(III) NHC Complexes: A Combined Experimental and Computational Study
Meredith, J. M.; Robinson, R.; Goldberg, K. I.; Kaminsky, W.; Heinekey, D. M. Organometallics 2012, 31, 1879.
2011
Hydrogenolysis of Palladium(II) Hydroxide, Phenoxide, and Alkoxide Complexes
Fulmer, G. R.; Herndon, A. N.; Kaminsky, W.; Kemp, R. A.; Goldberg, K. I. J. Am. Chem. Soc. 2011, 133, 17713.
Syntheses and Characterization of Palladium Complexes with a Hemilabile “PCO” Pincer Ligand
Fulmer, G. R.; Kaminsky, W.; Kemp, R. A.; Goldberg, K. I. Organometallics 2011, 30, 1627.
Five-Coordinate Platinum(IV) Complexes
Grice, K. A.; Scheuermann, M. L.; Goldberg, K. I. Top. Organomet. Chem. 2011, 503, 1.
Preparation of a Dihydrogen Complex of Cobalt
Hebden, T. J.; St. John, A. J.; Gusev, D. G.; Kaminsky, W.; Goldberg, K. I.; Heinekey, D. M. Angew. Chem. Int. Ed. 2011, 50, 1873.
C–H Activation of Benzene by Platinum(II) Complexes with Cyclometalated Phosphine Ligands
Grice, K. A.; Kaminsky, W.; Goldberg, K. I. Inorg. Chim. Acta 2011, 369, 76.
2010
Metal-Ligand Cooperativity in O2 Activation: Observation of a “Pt-O-O-C” Peroxo Intermediate
Scheuermann, M. L.; Fekl, U.; Kaminsky, W.; Goldberg, K. I. Organometallics 2010, 29, 4749.
NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in DeuteratedSolvents Relevant to the Organometallic Chemist
Fulmer, G. R.; Miller, A. J. M.; Sherden, N. H.; Gottlieb, H. E.; Nudelman, A.; Stoltz, B. M.; Bercaw, J. E.; Goldberg, K. I. Organometallics 2010, 29, 2176.
2009
Characterization of a Rhodium(I) σ-Methane Complex in Solution
Bernskoetter, W. H.; Schauer, C. K.; Goldberg, K. I.; Brookhart, M. Science 2009, 553.
Insertion of Molecular Oxygen into a Palladium(II) Methyl Bond: A Radical Chain Mechanism Involving Palladium(III) Intermediates
Boisvert, L.; Denney, M. C.; Hanson, S. K.; Goldberg, K. I. J. Am. Chem. Soc. 2009, 131, 15802.
Investigations of Iridium-Mediated Reversible C-H Bond Cleavage: Characterization of a 16-Electron Iridium(III) Methyl Hydride Complex
Bernskoetter, W. H.; Kloek-Hanson, S. ; Buzak, S. K.; Davis, Z.; White, P. S.; Swartz, R.; Goldberg, K. I.; Brookhart, M. J. Am. Chem. Soc. 2009, 131, 8603.
Synthesis, Characterization, and Reactivity of Nickel Hydride Complexes Containing 2,6-C6H3(CH2PR2)2 (R = tBu, cHex, and iPr) Pincer Ligands
Boro, B. J.; Duesler, E. N.; Goldberg, K. I.; Kemp, R. A. Inorg. Chem. 2009, 48, 5081.
Dinuclear Iridium Complexes Containing Cp* and Carbonyl Ligands: Synthesis, Structure, and Reactivity
Meredith, J. M.; Goldberg, K. I.; Kaminsky, W. ;Heinekey, D. M. Organometallics 2009, 28, 3546.
Insertion of Dioxygen into a Platinum(II)−Methyl Bond To Form a Platinum(II) Methylperoxo Complex
Grice, K. A.; Goldberg, K. I. Organometallics 2009, 28, 953.
Autoxidation of Platinum(IV) Hydrocarbyl Hydride Complexes To Form Platinum(IV) Hydrocarbyl Hydroperoxide Complexes
Look, J. L.; Wick, D. D.; Mayer, J. M.; Goldberg, K. I. Inorg. Chem. 2009, 48, 1356.
Hydrogenolysis of Palladium(II) Hydroxide and Methoxide Pincer Complexes
Fulmer, G. R.; Muller, R. P.; Kemp, R. A.; Goldberg, K. I. J. Am. Chem. Soc. 2009, 131, 1346.
Reductive Elimination and Dissociative β-Hydride Abstraction from Pt(IV) Hydroxide and Methoxide Complexes
Smythe, N. A.; Grice, K. A.; Williams, B. S.; Goldberg, K. I. Organometallics 2009, 28, 277.
2008
An Unprecedented Bonding Mode for Potassium within a PCP-Pincer Palladium Hydride-K-Selectride® Complex
Boro, B. J.; Duesler, E. N.; Goldberg, K. I.; Kemp, R. A. Inorg. Chem. Commun. 2008, 11, 1426.
Iridium-Catalyzed Dehydrogenation of Substituted Amine Boranes: Kinetics, Thermodynamics, and Implications for Hydrogen Storage
Dietrich, B. L.; Goldberg, K. I.; Heinekey, D. M.; Autrey, T.; Linehan, J. C. Inorg. Chem. 2008, 47, 8583.
Intermolecular Hydroarylation of Unactivated Olefins Catalyzed by Homogeneous Platinum Complexes
Luedtke A. T.; Goldberg, K. I. Angew. Chem. Int. Ed. 2008, 47, 7694.
σ-Borane Complexes of Iridium: Synthesis and Structural Characterization
Hebden, T. J.; Denney, M. C.; Pons, V.; Piccoli, P. M. B.; Koetzle, T. F.; Schultz, A. J.; Kaminsky, W.; Goldberg, K. I.; Heinekey, D. M. J. Am. Chem. Soc. 2008, 130, 10812.
C-H Bond Activation by Rhodium(I) Phenoxide and Acetate Complexes: Mechanism of H-D Exchange between Arenes and Water
Kloek-Hanson, S. M.; Heinekey, D. M.; Goldberg, K. I. Organometallics 2008, 27, 1454.
Reactions of Iridium Hydride Pincer Complexes with Dioxygen: New Peroxo Complexes and Reversible O2 Binding
Williams, D. B.; Kaminsky, W.; Mayer, J. M.; Goldberg, K. I. Chem. Commun. 2008, 35, 4195.
2007
Reductive Elimination of Ethane from Five-Coordinate Platinum(IV) Alkyl Complexes
Luedtke, A. T.; Goldberg, K. I. Inorg. Chem. 2007, 46, 8496.
Alkyl Carbon-Nitrogen Reductive Elimination from Platinum(IV)-Sulfonamide Complexes
Pawlikowski, A. V.; Getty, A. D.; Goldberg, K. I. J. Am. Chem. Soc. 2007, 129, 10382.
C-H bond Activation by Rhodium(I) Hydroxide and Phenoxide Complexes
Kloek, S. M.; Heinekey, D. M.; Goldberg, K. I. Angew. Chem. Int. Ed. 2007, 46, 4736.
Competitive C-H Bond Activation and β-Hydride Elimination at Platinum(II)
Kloek, S. M.; Goldberg, K. I. J. Am. Chem. Soc. 2007, 129, 3460.
2006
Mechanism of Direct Molecular Oxygen Insertion in a Palladium(II)-Hydride Bond
Keith, J. M.; Muller, R. P.; Kemp, R. A.; Goldberg, K. I.; Goddard, W. A.; Oxgaard, J. Inorg. Chem. 2006, 45, 9631.
Efficient Catalysis of Ammonia Borane Dehydrogenation
Denney, M. C.; Pons, V.; Hebden, T. J.; Heinekey, D. M.; Goldberg, K. I. J. Am. Chem. Soc. 2006, 128, 12048.
Stereoselective Decarbonylation of Methanol to Form a Stable Iridium(III) trans-Dihydride Complex
Kloek, S. M.; Heinekey, D. M.; Goldberg, K. I. Organometallics 2006, 25, 3007.
Insertion of Molecular Oxygen into a Palladium(II) Hydride Bond
Denney, M. C.; Smythe, N. A.; Cetto, K. L.; Kemp, R. A.; Goldberg, K. I. J. Am. Chem. Soc. 2006, 128, 2508.
2005
Mechanistic Information on the Reductive Elimination from Cationic Trimethylplatinum(IV) Complexes to Form Carbon-Carbon Bonds
Procelewska, J.; Zahl, A.; Liehr, G.; van Eldik, R.; Smythe, N. A.; Williams, B. S.; Goldberg, K. I. Inorg. Chem. 2005, 44, 7732.
The gem-Dialkyl Effect as a Test for Preliminary Diphosphine Chelate Opening in a Reductive Elimination Reaction
Arthur, K. L.; Wang, Q. L.; Bregel, D. M.; Smythe, N. A.; O’Neill, B. A.; Goldberg, K. I.; Moloy K. G. Organometallics 2005, 24, 4624.
2003
β-Diiminate Platinum Complexes for Alkane Dehydrogenation
Fekl, U.; Kaminsky, W.; Goldberg, K. I. J. Am. Chem. Soc. 2003, 125, 15286.
Reductive Elimination/Oxidative Addition of Carbon-Hydrogen Bonds at Pt(IV)/Pt(II) Centers: Mechanistic Studies of the Solution Thermolyses of TpMe2Pt(CH3)2H
Jenson, M. P.; Wick, D. D.; Reinartz, S.; White, P. S.; Templeton, J, L.; Goldberg, K. I. J. Am. Chem. Soc. 2003, 125, 8610.
Homogeneous Hydrocarbon C-H Bond Activation and Functionalixation with Platinum
Fekl, U.; Goldberg, K. I. Adv. Inorg. Chem. 2003, 54, 259.
Mechanisms of C-C and C-H Alkane Reductive Eliminations from Octahedral Pt(IV): Reaction via Five-Coordinate Intermediates or Direct Elimination?
Crumpton-Bregel, D. M.; Goldberg, K. I. J. Am. Chem. Soc. 2003, 125, 9442.
2002
Five-Coordinate Platinum(IV) Complex as a Precursor to a Novel Pt(II) Olefin Hydride Complex for Alkane Activation
Fekl, U.; Goldberg, K. I. J. Am. Chem. Soc. 2002, 124, 6804.
2001
Stable Five-Coordinate Platinum(IV) Alkyl Complex
Fekl, U.; Kaminsky, W.; Goldberg, K. I. J. Am. Chem. Soc. 2001, 123, 6423.
Reaction of a Palladium(II) Complex Chelated by a Tridentate PNC Ligand with Water to Produce a [(PN)Pd(-OH)]22+ Dimer: A Rare Observation of a Well-Defined Hydrolysis of a Pd(II)-Aryl Compound
Getty, A. D.; Goldberg, K. I. Organometallics 2001, 20, 2545.
Computational Study of Reductive Elimination Reactions to Form C-H Bonds from Platinum(II) and Platinum(IV) Centers with Strongly Coordinating Trimethylphosphine Ligands
Bartlett, K.L.; Goldberg, K. I.; Borden, W. T. Organometallics 2001, 20, 2669.
Studies of Reductive Elimination Reactions To Form Carbon-Oxygen Bonds from Pt(IV) Complexes
Williams, B. S.; Goldberg, K. I. J. Am. Chem. Soc. 2001, 123, 2576.
2000
Five-Coordinate Intermediates in Carbon-Carbon Reductive Elimination Reactions from Pt(IV)
Crumpton, D. M.; Goldberg, K. I. J. Am. Chem. Soc. 2000, 122, 962.
A Computational Study of Reductive Elimination Reactions to Form C-H Bonds from Pt(II) and Pt(IV) Centers. Why Does Ligand Loss Precede Elimination from Six-Coodinate but Not Four-Coodinate Platinum?
Bartlett, K. L.; Goldberg, K. I.; Borden, W. T. J. Am. Chem. Soc. 2000, 122, 1456.
1999
Direct Observation of C-O Reductive Elimination from Pt(IV)
Williams, B. S.; Holland, A. W.; Goldberg, K. I. J. Am. Chem. Soc. 1999, 121, 252.
Insertion of Dioxygen into a Platinum-Hydride Bond to Form a Novel Dialkylhydroperoxo Pt(IV) Complex
Wick, D. D.; Goldberg, K. I. J. Am. Chem. Soc. 1999, 121, 11900.
1997
C-H Activation at Pt(II) To Form Stable Pt(IV) Alkyl Hydrides
Wick, D. D.; Goldberg, K. I. J. Am . Chem. Soc. 1997, 119, 10235.