Refereed Publications from Postdoctoral Studies (Los Alamos National Laboratory)

  1. "Comparative Study of f-Element Electronic Structure across a Series of Multimetallic Actinide and Lanthanoid-Actinide Complexes Possessing Redox-Active Bridging Ligands," Schelter, E. J.; Wu, R.; Veauthier, J. M.; Bauer, E. D.; Booth, C. H.; Thomson, R. K.; Graves, C. R.; John, K. D.; Scott, B. L.; Thompson, J. D.; Morris, D. E.; Kiplinger, J. L. Inorg. Chem. 2010, 49, 1995-2007.
  2. "Actinide Redox-Active Ligand Complexes: Reversible Intramolecular Electron-Transfer in U(dpp-BIAN)2/U(dpp-BIAN)2(THF)," Schelter, E. J.; Wu, R.; Scott, B. L.; Thompson, J. D.; Batista, E.; Morris, D. E.; Kiplinger, J. L. Inorg. Chem. 2010, 49, 924-933.
  3. "Cation-Cation Interactions, Magnetic Communication, and Reactivity of the Pentavalent Uranium Ion [U(NtBu)2]+," Spencer, L. P.; Schelter, E. J.; Yang, P.; Gdula, R. L.; Scott, B. L.; Thompson, J. D.; Kiplinger, J. L.; Batista, E. R.; Boncella, J. M. Angew. Chem. Int. Ed. 2009, 48, 3795-3798.
  4. "Probing the Chemistry, Electronic Structure and Redox Energetics in Organometallic Pentavalent Uranium Complexes," Graves, C. R.; Vaughn, A. E.; Schelter, E. J.; Scott, B. L.; Thompson, J. D.; Morris, D. E.; Kiplinger, J. L. Inorg. Chem. 2008, 47, 11879-11891.
  5. "Evidence for the Involvement of 5f-Orbitals in the Bonding and Reactivity of Organometallic Actinide Compounds: Thorium(IV) and Uranium(IV) Bis(hydrazonato) Complexes," Cantat, T.; Graves, C. R.; Jantunen, K. C.; Burns, C. J.; Scott, B. L.; Schelter, E. J.; Morris, D. E.; Hay, P. J.; Kiplinger, J. L. J. Am. Chem. Soc. 2008, 130, 17537-17551.
  6. "A Mild Protocol to Generate Uranium(IV) Mixed-Ligand Metallocene Complexes Using Cu(I) Iodide," Graves, C. R.; Schelter, E. J.; Cantat, T.; Scott, B. L.; Kiplinger, J. L. Organometallics 2008, 27, 5371-5378.
  7. "Ultrafast Spectroscopy of the Uranium(IV) and Thorium(IV) Bis(ketimide) Complexes (C5Me5)2An[-N=C(Ph)(CH2Ph)]2(An = Th, U)," Hilton, D. J.; Prasankumar, R. P.; Schelter, E. J.; Thorsmølle, V. K.; Trugman, S. A.; Shreve, A. P.; Kiplinger, J. L.; Morris, D. E.; Taylor, A. J. J. Phys. Chem. 2008, 112, 7840-7847.
  8. "1,4-Dicyanobenzene as a Scaffold for the Preparation of Bimetallic Actinide Complexes Exhibiting Metal-Metal Communication," Schelter, E. J.; Veauthier, J. M.; Graves, C. R.; John, K. D.; Scott, B. L.; Thompson, J. D.; Pool-Davis-Tournear, J. A.; Morris, D. E.; Kiplinger, J. L. Chem. — Eur. J. 2008, 14, 7782-7790. (Cover Article)
  9. "Direct Comparison of the Magnetic and Electronic Properties of Samarocene and Ytterbocene Terpyridine Complexes," Veauthier, J. M.; Schelter, E. J.; Carlson, C. N.; Scott, B. L.; Da Re, R. E.; Thompson, J. D.; Kiplinger, J. L.; Morris, D. E.; John, K. D. Inorg. Chem. 2008, 47, 5841-5849.
  10. "Organometallic Uranium(V)-Imido Halide Complexes: From Synthesis to Electronic Structure and Bonding," Graves, C. R.; Yang, P.; Kozimor, S. A.; Vaughn, A. E.; Clark, D. L.; Conradson, S. D.; Schelter, E. J.; Scott, B. L.; Thompson, J. D.; Hay, P. J.; Morris, D. E.; Kiplinger, J. L. J. Am. Chem. Soc. 2008, 130, 5272-5285.
  11. "Mixed-Valency in Uranium Multimetallic Complexes," Schelter, E. J.; Wu, R.; Scott, B. L.; Thompson, J. D.; Morris, D. E.; Kiplinger, J. L. Angew. Chem. Int. Ed. 2008, 47, 2993-2996.
  12. "sp3 versus sp2 C-H Bond Activation Chemistry of 2-picoline by Th(IV) and U(IV) Metallocene Complexes," Kiplinger, J. L.; Scott, B. L.; Schelter, E. J.; Pool Davis Tournear, J. A. Alloys Compd. 2007, 444-445, 477-482.
  13. "Systematic Studies of Actinide-Ketimide Bonding: Uranium Fluoroketimides," Schelter, E. J.; Yang, P.; Martin, R. L.; Scott, B. L.; Thompson, J. D.; Jantunen, K. C.; Hay, P. J.; Morris, D. E.; Kiplinger, J. L. Inorg. Chem. 2007, 46, 7477-7488.
  14. "Toward Actinide Molecular Magnetic Materials: Coordination Polymers of U(IV) and the Organic Acceptors TCNQ and TCNE," Schelter, E. J.; Morris, D. E.; Scott, B. L.; Thompson, J. D.; Kiplinger, J. L. Inorg. Chem. 2007, 46, 5528-5536. (Starred Author)
  15. "Systematic Studies of Actinide-Ketimide Bonding.  Part I: Thorium Fluoroketimides," Schelter, E. J.; Yang, P.; Martin, R. L.; Hay, P. J.; Scott, B. L.; Jantunen, K. C.; Morris, D. E.; Kiplinger, J. L. J. Am. Chem. Soc. 2007, 129, 5139-5152.
  16. "Actinide-Mediated Coupling of 4-Fluorobenzonitrile: Synthesis of an Eight-Membered Thorium(IV) Tetraazametallacycle," Schelter, E. J.; Morris, D. E.; Scott, B. L.; Kiplinger, J. L. Chem. Commun. 2007, 1029-1031.
  17. "Ytterbocene Charge-Transfer Molecular Wire Complexes," Carlson, C. N.; Kuehl, C. J.; Da Re, R. E.; Veauthier, J. M.; Schelter, E. J.; Milligan, A. E.; Scott, B. L.; Bauer, E. D.; Thompson, J. D.; Morris, D. E.; John, K. D. J. Am. Chem. Soc.2006, 128, 7230-7241.
  18. "4f/5f Heterotrimetallic Complexes Exhibiting Electrochemical and Magnetic Communication," Schelter, E. J.; Veauthier, J. M.; John, K. D.; Scott, B. L.; Thompson, J. D.; Morris, D. E.; Kiplinger, J. L. J. Am. Chem. Soc. 2006, 128, 2198-2199. (Featured in C&E News Science and Technology Concentrate)
  19. "Actinide-Mediated Cyclization of 1,2,4,5-Tetracyanobenzene: Synthesis and Characterization of Self-Assembled Trinuclear Thorium and Uranium Macrocycles," Kiplinger, J. L.; Pool, J. A.; Schelter, E. J.; Morris, D. E.; Thompson, J. D.; Scott, B. L. Angew. Chem. Int. Ed. 2006, 45, 2036-2041. (Frontispiece Article)
  20. "A Ligand Substituent Effect Observed for Ytterbocene 4’-Cyano-2,2’:6’,2” Terpyridine," Veauthier, J. M.; Schelter, E. J.; Kuehl, C. J.; Clark, A. E.; Scott, B. L.; Morris, D. E.; Martin, R. L.; Thompson, J. D.; Kiplinger, J. L.; John, K. D. Inorg. Chem. 2005, 44, 5911-5920.

Refereed Publications from Graduate Studies (Texas A&M University, Dunbar Group)

  1. “A Family of Cyanide-Bridged Molecular Squares: Structural and Magnetic Properties of [{MIICl2}2{CoII(triphos)(CN)2}2]·xCH2Cl2, M = Mn, Fe, Co, Ni, Zn,” Karadas, F.; Schelter, E. J.; Shatruk, M.; Prosvirin, A. V.; Bacsa, J.; Smirnov, D.; Ozarowski, A.; Krzystek, J.; Telser, J.; Dunbar, K. R. Inorg. Chem. 2008, 47, 2074-2082.
  2. “Magnetic Anisotropy in the Octanuclear ReII4MnII4 Cluster Exhibiting Single-Molecule Magnet Behavior: Quantum-Spin and Classical-Spin Approaches,” Palii, A. V.; Ostrovsky, S. M.; Klokishner, S. I.; Tsukerblat, B. S.; Schelter, E. J.; Prosvirin, A. V.; Dunbar, K. R. Inorg. Chim. Acta 2007, 360, 3915-3924.
  3. “A Family of Metal-Cyanide Cubes with Alternating Octahedral and Tetrahedral Corners Exhibiting a Variety of Magnetic Behaviors Including Single Molecule Magnetism,” Schelter, E. J.; Prosvirin, A. V.; Karadas, F.; Bacsa, J.; Dunbar, K. R., J. Am. Chem. Soc. 2007, 129, 8139-8149.
  4. “Synthesis and Reactivity Studies of Solvated Dirhenium Complexes,” Bera, J. K.; Schelter, E. J.; Patra, S. K.; Bacsa, J.; Dunbar, K. R. Dalton 2006, 4011-4019.
  5. “Unexpected Conversion of a Hexacyanometallate to a Homoleptic Nitrile Complex with Triphenylborane Substituents,” Schelter, E. J.; Heinz, R. A.; Galán-Mascarós, J. R.; Dunbar, K. R. Chem. Commun.2005, 1417-1419.
  6. “A High Spin Molecular Square Based on Square Pyramidal CoII and Tetrahedral MnII Centers: [{MnIICl2}2{CoII(triphos)(CN)2}2],” Karadas, F.; Schelter, E. J.; Prosvirin, A. V.; Basca, J.; Dunbar, K. R. Chem. Commun. 2005, 1414-1416.
  7. “Molecular Cube of ReII and MnII That Exhibits Single-Molecule Magnetism,” Schelter, E. J.; Prosvirin, A. V.; Dunbar, K. R. J. Am. Chem. Soc. 2004, 126, 15004-15005. (Highlighted in C&E News Article.)
  8. “Unusual Magnetic Metal-Cyanide Cubes of ReII with Alternating Octahedral and Tetrahedral Corners,” Schelter, E. J.; Prosvirin, A. V.; Reiff, W. M.; Dunbar, K. R., Angew. Chem., Int. Ed. 2004, 43, 4912-4915.
  9. “Structural Characterization, Magnetic Properties and Electrospray Mass Spectrometry of Two Jahn-Teller Isomers of the Single Molecule Magnet Mn12O12(CF3COO)16(H2O)4,” Zhao, H.; Berlinguette, C. P.; Bacsa, J.; Prosvirin, A. V.; Bera, J. K.; Tichy, S. E.; Schelter, E. J.; Dunbar K. R. Inorg. Chem. 2003, 43, 1359-1369.
  10. “Unusual Magnetic Behavior of Six-Coordinate, Mixed-Ligand Re(II) Complexes: Origin of a Strong Temperature Independent Paramagnetism,” Dunbar, K. R.; Schelter, E. J.; Palii, A. V.; Ostrovsky, S. M.; Mirovitskii, V. Y.; Klokishner, S. I.; Tsukerblat, B. S. J. Phys. Chem. A. 2003, 107, 11102-11111.
  11. “Magnetic Properties of a Low-Symmetry d5 Complex-Adiabatic Pseudo Jahn-Teller Problem,” Dunbar, K. R.; Schelter, E. J.; Tsukerblat, B. S.; Palii, A. V.; Ostrovsky, S. M.; Mirovitskii, V. Y.; Klokishner, S. I. Adv. Quantum Chem. 2003, 44, 414-428.
  12. “Magnetic Properties of Complex d1 and d5 Ions: Crystal Field Model, and Jahn-Teller Effect,” Dunbar, K. R.; Schelter, E. J.; Tsukerblat, B. S.; Ostrovsky, S. M.; Mirovitsky, V. Y.; Palii, A. V. Polyhedron 2003, 22, 2545-2556. (Invited Article – Special Issue on Molecule-Based Magnetic Materials.)
  13. “New Paramagnetic Re(II) Compounds with Nitrile and Cyanide Ligands Prepared by Homolytic Scission of Dirhenium Complexes,” Schelter, E. J.; Bera, J. K.; Bacsa, J.; Galán-Mascarós, J. R.; Dunbar, K. R. Inorg. Chem. 2003, 42, 4256-4258.

Refereed Publications from Undergraduate Studies (MTU, Luck Group)

  1. “Synthesis and Characterization of ReCl(H2)(AsMePh2)4, a Classical Hydride Complex; Reexamination of ReCl(H2)(PMePh2)4 and Theoretical Calculations on Model Compounds,” Bayse C. A.; Luck R. L.; Schelter E. J. Inorg. Chem.2001, 40, 3463-3467.
  2. “Potassium Borohydride,” Luck, R. L.; Schelter, E. J. Acta Cryst. 1999, C55, IUC9900151.